BR112015026116A2 - método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetona - Google Patents
método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetonaInfo
- Publication number
- BR112015026116A2 BR112015026116A2 BR112015026116A BR112015026116A BR112015026116A2 BR 112015026116 A2 BR112015026116 A2 BR 112015026116A2 BR 112015026116 A BR112015026116 A BR 112015026116A BR 112015026116 A BR112015026116 A BR 112015026116A BR 112015026116 A2 BR112015026116 A2 BR 112015026116A2
- Authority
- BR
- Brazil
- Prior art keywords
- cycloalkane
- ketone
- mixture containing
- product mixture
- corresponding alcohol
- Prior art date
Links
- 150000001924 cycloalkanes Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 3
- 150000002576 ketones Chemical class 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000012015 metal triflimidate Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
Abstract
resumo método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetona a presente invenção diz respeito a um método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetona, compreendendo o referido método colocar um cicloalcano em contato com um agente oxidante na presença de uma quantidade catalítica eficaz de catalisadores de triflatos de metais ou triflimidatos de metais. 1/1
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNPCT/CN2013/074348 | 2013-04-18 | ||
CN2013074348 | 2013-04-18 | ||
PCT/EP2014/057855 WO2014170422A1 (en) | 2013-04-18 | 2014-04-17 | Cycloalkane oxidation catalysts and method to produce alcohols and ketones |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015026116A2 true BR112015026116A2 (pt) | 2017-07-25 |
BR112015026116B1 BR112015026116B1 (pt) | 2022-03-15 |
Family
ID=50543047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015026116-7A BR112015026116B1 (pt) | 2013-04-18 | 2014-04-17 | Método de oxidação de um cicloalcano para formar uma mistura de produtos contendo um correspondente álcool e cetona |
Country Status (10)
Country | Link |
---|---|
US (1) | US9745239B2 (pt) |
EP (1) | EP2986585B1 (pt) |
JP (2) | JP6527136B2 (pt) |
KR (1) | KR102162802B1 (pt) |
CN (1) | CN105339332B (pt) |
BR (1) | BR112015026116B1 (pt) |
RU (1) | RU2652794C2 (pt) |
SG (1) | SG11201507621QA (pt) |
UA (1) | UA115900C2 (pt) |
WO (1) | WO2014170422A1 (pt) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL3237365T3 (pl) * | 2014-12-22 | 2019-05-31 | Rhodia Operations | Katalizatory utleniania cykloalkanu i sposób wytwarzania alkoholi i ketonów |
JP2020063349A (ja) * | 2018-10-16 | 2020-04-23 | 国立大学法人京都大学 | セルロース及び/又はヘミセルロースの製造方法 |
CN112439452B (zh) * | 2019-09-04 | 2023-07-04 | 中国石油化工股份有限公司 | 用于环己烷直接氧化制己二酸的催化剂 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2087365A5 (pt) | 1970-05-15 | 1971-12-31 | Rhone Poulenc Sa | |
JPS5550930B2 (pt) * | 1972-12-20 | 1980-12-20 | ||
US3879467A (en) * | 1973-01-05 | 1975-04-22 | Atlantic Richfield Co | Catalytic oxidation of alkanes and alkenes with organic hydroperoxides |
FR2273789A2 (fr) * | 1974-06-06 | 1976-01-02 | Rhone Poulenc Ind | Procede pour la preparation de l'hexene-2 al |
US4465861A (en) | 1983-04-11 | 1984-08-14 | E. I. Du Pont De Nemours And Company | Process for producing a mixture containing cyclohexanol and cyclohexanone |
DE3601218A1 (de) | 1986-01-17 | 1987-07-23 | Basf Ag | Verfahren zur aufarbeitung von cyclohexylhydroperoxid, cyclohexanol und cyclohexanon enthaltenden reaktionsgemischen |
US4900871A (en) * | 1987-01-02 | 1990-02-13 | Sun Refining And Marketing Company | Hydrocarbon oxidations catalyzed by iron coordination complexes containing a halogenated ligand |
FR2628101B1 (fr) * | 1988-03-03 | 1990-07-20 | Rhone Poulenc Chimie | Procede d'oxydation catalytique d'alcanes en melanges d'alcools et de cetones |
BE1009662A3 (nl) * | 1995-10-13 | 1997-06-03 | Dsm Nv | Werkwijze voor het ontleden van cycloalkylhydroperoxide. |
EP1108701B1 (en) * | 1999-12-14 | 2003-04-23 | Sumitomo Chemical Company Limited | Process for preparing ketone, alcohol and hydroperoxide |
US6700022B2 (en) | 2002-06-05 | 2004-03-02 | E. I. Du Pont De Nemours And Company | High yield cyclohexyl hydroperoxide decompostition process |
JP4736368B2 (ja) | 2004-07-22 | 2011-07-27 | 住友化学株式会社 | シクロアルカノール及び/又はシクロアルカノンの製造方法 |
JP5197380B2 (ja) * | 2006-12-05 | 2013-05-15 | 株式会社ダイセル | シクロアルカンの酸化生成物の製造方法 |
JP2008189588A (ja) * | 2007-02-05 | 2008-08-21 | Sumitomo Chemical Co Ltd | シクロアルカノール及び/又はシクロアルカノンの製造方法 |
JP5136017B2 (ja) * | 2007-11-21 | 2013-02-06 | 住友化学株式会社 | シクロアルカノール及び/又はシクロアルカノンの製造方法 |
US9150971B2 (en) * | 2012-08-28 | 2015-10-06 | Oakland University | Aerobic oxidation of alkanes |
-
2014
- 2014-04-17 UA UAA201510042A patent/UA115900C2/uk unknown
- 2014-04-17 WO PCT/EP2014/057855 patent/WO2014170422A1/en active Application Filing
- 2014-04-17 RU RU2015149226A patent/RU2652794C2/ru active
- 2014-04-17 EP EP14718580.5A patent/EP2986585B1/en not_active Not-in-force
- 2014-04-17 KR KR1020157029222A patent/KR102162802B1/ko active IP Right Grant
- 2014-04-17 CN CN201480021847.6A patent/CN105339332B/zh active Active
- 2014-04-17 JP JP2016508170A patent/JP6527136B2/ja not_active Expired - Fee Related
- 2014-04-17 SG SG11201507621QA patent/SG11201507621QA/en unknown
- 2014-04-17 US US14/784,845 patent/US9745239B2/en active Active
- 2014-04-17 BR BR112015026116-7A patent/BR112015026116B1/pt not_active IP Right Cessation
-
2018
- 2018-12-26 JP JP2018242201A patent/JP2019073523A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2014170422A1 (en) | 2014-10-23 |
CN105339332B (zh) | 2018-04-10 |
US20160060199A1 (en) | 2016-03-03 |
SG11201507621QA (en) | 2015-11-27 |
CN105339332A (zh) | 2016-02-17 |
JP6527136B2 (ja) | 2019-06-05 |
EP2986585B1 (en) | 2017-06-21 |
JP2016520565A (ja) | 2016-07-14 |
RU2652794C2 (ru) | 2018-05-03 |
UA115900C2 (uk) | 2018-01-10 |
US9745239B2 (en) | 2017-08-29 |
KR102162802B1 (ko) | 2020-10-07 |
EP2986585A1 (en) | 2016-02-24 |
RU2015149226A (ru) | 2017-05-19 |
KR20150143489A (ko) | 2015-12-23 |
BR112015026116B1 (pt) | 2022-03-15 |
JP2019073523A (ja) | 2019-05-16 |
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Legal Events
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B25A | Requested transfer of rights approved |
Owner name: ECOLE NORMALE SUPERIEURE DE LYON (FR) ; PERFORMANCE POLYAMIDES, SAS (FR) |
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B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/04/2014, OBSERVADAS AS CONDICOES LEGAIS. |
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B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 10A ANUIDADE. |
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B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2771 DE 15-02-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |