BR112015008680A2 - catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio - Google Patents

catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio

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Publication number
BR112015008680A2
BR112015008680A2 BR112015008680A BR112015008680A BR112015008680A2 BR 112015008680 A2 BR112015008680 A2 BR 112015008680A2 BR 112015008680 A BR112015008680 A BR 112015008680A BR 112015008680 A BR112015008680 A BR 112015008680A BR 112015008680 A2 BR112015008680 A2 BR 112015008680A2
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Brazil
Prior art keywords
catalyst
stability
amine catalyst
halogen containing
improving
Prior art date
Application number
BR112015008680A
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English (en)
Other versions
BR112015008680B1 (pt
Inventor
Louise Vincent Jean
Jesus Burdeniuc Juan
J Miller Timothy
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Air Prod & Chem
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Publication date
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of BR112015008680A2 publication Critical patent/BR112015008680A2/pt
Publication of BR112015008680B1 publication Critical patent/BR112015008680B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1858—Catalysts containing secondary or tertiary amines or salts thereof having carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4027—Mixtures of compounds of group C08G18/54 with other macromolecular compounds
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    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/54—Polycondensates of aldehydes
    • C08G18/546—Oxyalkylated polycondensates of aldehydes
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
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    • C08G2110/0025—Foam properties rigid
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    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
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    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
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    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
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    • C08J2205/00—Foams characterised by their properties
    • C08J2205/10—Rigid foams
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2207/00—Foams characterised by their intended use
    • C08J2207/04—Aerosol, e.g. polyurethane foam spray
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

resumo patente de invenção: "catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio". a presente invenção refere-se a composições de catalisador úteis na produção de espuma isolante de poliuretano ou de poli-isocianurato. as composições de catalisador dão estabilidade aumentada de uma mistura do catalisador, um agente de expansão contendo halogênio e um poliol. estas composições de catalisador compreendem pelo menos 10% de uma tetra-alquilguanidina e pelo menos 10% de um catalisador de amina terciária com um grupo reativo de isocianato. estes catalisadores melhorados podem ser usados com qualquer agente de expansão halogenado, e fornece benefícios de estabilidade substanciais com o uso de hidrofluoro-olefinas e hidrofluorocloro-olefinas. em uma modalidade exemplar, um processo inclui fornecer uma pré-mistura compreendendo um agente de expansão de hidro-halo-olefina, pelo menos um poliol, água, e um catalisador compreendendo 10-50% de tetrametilguanidina e 10-90% de um ou mais de um catalisador de amina contendo um grupo reativo de isocianato.
BR112015008680-2A 2012-10-24 2013-10-24 Composição de pré-mistura de poliol, método para fazer espuma, espuma, método para melhorar a estabilidade de uma pré-mistura de poliol e uso de tetra-alquilguanidina para melhorar a estabilidade de uma composição de pré-mistura de poliol BR112015008680B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261717690P 2012-10-24 2012-10-24
US61/717,690 2012-10-24
US13/951,958 US10023681B2 (en) 2012-10-24 2013-07-26 Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents
US13/951,958 2013-07-26
PCT/US2013/066541 WO2014066596A1 (en) 2012-10-24 2013-10-24 Amine catalyst for improving the stability of polyurethane systems having halogen containing blowing agents

Publications (2)

Publication Number Publication Date
BR112015008680A2 true BR112015008680A2 (pt) 2017-07-04
BR112015008680B1 BR112015008680B1 (pt) 2021-03-23

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Application Number Title Priority Date Filing Date
BR112015008680-2A BR112015008680B1 (pt) 2012-10-24 2013-10-24 Composição de pré-mistura de poliol, método para fazer espuma, espuma, método para melhorar a estabilidade de uma pré-mistura de poliol e uso de tetra-alquilguanidina para melhorar a estabilidade de uma composição de pré-mistura de poliol

Country Status (11)

Country Link
US (2) US10023681B2 (pt)
EP (3) EP2725047B1 (pt)
JP (3) JP5869546B2 (pt)
KR (1) KR101792793B1 (pt)
CN (3) CN106810661A (pt)
BR (1) BR112015008680B1 (pt)
CA (2) CA2830692C (pt)
ES (3) ES2846768T3 (pt)
MX (1) MX355844B (pt)
PL (2) PL2725047T3 (pt)
WO (1) WO2014066596A1 (pt)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9968919B2 (en) * 2011-06-29 2018-05-15 Evonik Degussa Gmbh Reducing emissions in polyurethane foam
US20160145374A1 (en) * 2013-07-24 2016-05-26 Kao Corporation Polyol mixture for producing rigid polyurethane foam
BR112016019644B1 (pt) * 2014-02-26 2022-07-12 Evonik Operations Gmbh Método para preparação de uma espuma de poli-isocianurato/poliuretano
JP6626674B2 (ja) * 2014-10-08 2019-12-25 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
CN107371366B (zh) * 2015-04-07 2020-10-23 科思创德国股份有限公司 用于硬质聚氨酯泡沫塑料的多元醇预混物组合物
KR102410082B1 (ko) 2015-06-18 2022-06-16 에보닉 오퍼레이션스 게엠베하 이소시아네이트 반응성기를 갖는 3차 아민과 입체 장애 염으로부터의 삼량체화 촉매
EP4269483A3 (en) 2015-09-18 2024-01-03 Arkema Inc. Polyol pre-mixes having improved shelf life
WO2017061806A1 (en) 2015-10-06 2017-04-13 Institute For Basic Science Method for producing whole plants from protoplasts
JP6951012B2 (ja) * 2016-05-16 2021-10-20 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
US20190169351A1 (en) * 2016-05-17 2019-06-06 Tosoh Corporation Amine catalyst composition for producing haloalkene foamed polyurethane
JP6696984B2 (ja) * 2016-05-26 2020-05-20 積水化学工業株式会社 ポリウレタン組成物
US11021561B2 (en) * 2016-07-11 2021-06-01 Evonik Operations Gmbh Amine composition useful for making polyurethane foam
JP7017575B2 (ja) * 2016-10-25 2022-02-08 エル・コーポレイション 低粘度リン酸ポリオール
EP3553102A4 (en) * 2016-12-08 2020-08-05 Sekisui Chemical Co., Ltd. COMPOSITION OF URETHANE RESIN
EP3576921A1 (de) * 2017-01-31 2019-12-11 Covestro Deutschland AG Verfahren und system zur herstellung von schaum-verbundelementen
PL3596148T3 (pl) * 2017-03-16 2021-11-22 Basf Se Sposób wytwarzania butów poliuretanowych
MX2019014811A (es) * 2017-06-13 2020-02-10 Honeywell Int Inc Formulacion mejorada de espuma.
JP6753614B2 (ja) * 2017-07-25 2020-09-09 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、硬質ポリウレタンフォーム用組成物、および硬質ポリウレタンフォームの製造方法
WO2019055441A1 (en) * 2017-09-14 2019-03-21 Huntsman International Llc POLYURETHANE ISOLATION FOAM COMPOSITION COMPRISING HALOGENATED OLEFINS AND TERTIARY AMINE COMPOUND
CN111093825A (zh) * 2017-09-14 2020-05-01 亨斯迈国际有限责任公司 含卤代烯烃的就地倾注聚氨酯隔热泡沫组合物
US20210061938A1 (en) * 2017-09-14 2021-03-04 Huntsman International Llc Polyurethane insulation foam composition comprising halogenated olefins
US11046850B2 (en) 2017-09-27 2021-06-29 Evonik Operations Gmbh Mixed metal catalyst compositions and methods for making polyurethane foam
US11440286B2 (en) * 2017-12-25 2022-09-13 Inoac Corporation Laminate and skin material for vehicle interior member
KR20210046668A (ko) * 2018-08-21 2021-04-28 헌트스만 인터내셔날, 엘엘씨 Pir/pur 발포체 제조를 위한 촉매
CA3112573A1 (en) 2018-09-13 2020-03-19 Huntsman International Llc Polyurethane insulation foam composition comprising a stabilizing compound
CN113891903A (zh) * 2019-05-24 2022-01-04 陶氏环球技术有限责任公司 用于制备阻燃硬质聚氨酯泡沫的储存稳定的含hfo或hcfo的多元醇组合物
ES2837489B2 (es) * 2019-12-31 2022-02-28 Primalchit Solutions S L Mezcla de componentes organicos no polimericos con capacidad retardante de llama, metodo de preparacion y uso
WO2021194766A1 (en) 2020-03-27 2021-09-30 Huntsman Petrochemical Llc Acid-blocked alkylaminopyridine catalysts for polyurethane foam
WO2024038025A1 (de) 2022-08-16 2024-02-22 Basf Se Neue polyurethan-schaumkatalysatoren mit verbesserter lagerstabilität

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2932621A (en) 1956-02-07 1960-04-12 Pittsburgh Plate Glass Co Preparation of polyurethane foam utilizing a salt of dimethylethanol amine and a dicarboxylic acid as a catalyst
US3238154A (en) 1961-08-10 1966-03-01 Pittsburgh Plate Glass Co Preparation of a polyurethane resin using a tetraalkyl guanidine as a catalyst
NL122821C (pt) 1963-09-18
US3391113A (en) 1966-10-14 1968-07-02 Dow Chemical Co Rapid curing epoxy resin compositions
US3663258A (en) 1970-11-16 1972-05-16 Minnesota Mining & Mfg Heat-sensitive copy-sheet
US3772221A (en) 1972-01-12 1973-11-13 Quaker Oats Co Preparation of polyurethane foams and microcellular elastomers with integral skins using a combination of tetraalkylguanidine and an organomercury compound
US3892687A (en) 1973-07-09 1975-07-01 Air Prod & Chem Quaternary hydroxyalkyl tertiary amine bases as poluyrethane catalysts
LU68552A1 (pt) 1973-10-03 1975-06-16
US3896052A (en) * 1974-01-30 1975-07-22 Upjohn Co Cocatalyst system for trimerizing polyisocyanates
DE2524834C3 (de) * 1975-06-04 1981-04-23 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Polyurethanschaumstoffen mit geschlossener Außenhaut
US4394491A (en) 1980-10-08 1983-07-19 The Dow Chemical Company Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate
US4464488A (en) 1983-08-11 1984-08-07 Texaco Inc. Polyurethanes using monocarboxylic acid salts of bis(aminoethyl)ether derivatives as catalysts
US5688834A (en) 1991-08-30 1997-11-18 Alliedsignal, Inc. Catalysts which stabilize hydrohalocarbon blowing agent in polyurethane foam formulations
US4711910A (en) * 1986-10-24 1987-12-08 Atlantic Richfield Company Preparation of fire retardant flexible polyester based polyurethane foams having reduced discoloration and scorch
US4758605A (en) 1987-03-12 1988-07-19 The Dow Chemical Company Stabilization of reactivity of polyester polyol based polyurethane foam components
GB8712363D0 (en) * 1987-05-26 1987-07-01 Ici Plc Polyisocyanurate rigid foams
DE3730221A1 (de) 1987-09-09 1989-03-30 Kali Chemie Ag Stabilisierung von chlorfluoralkanen
DE3934955A1 (de) 1989-10-20 1991-04-25 Bayer Ag Verfahren zur herstellung von formkoerpern aus polyurethanschaumstoffen und die nach diesem verfahren erhaltenen formkoerper
WO1998020058A1 (en) * 1996-11-04 1998-05-14 Imperial Chemical Industries Plc Rigid polyurethane foams
JP4147637B2 (ja) 1998-09-21 2008-09-10 東ソー株式会社 ポリウレタン製造用の触媒
WO2001058976A1 (en) 2000-02-10 2001-08-16 Dow Global Technologies Inc. Low emission polyurethane polymers made with autocatalytic polyols
US6387972B1 (en) 2001-02-15 2002-05-14 Crompton Corporation Process to enhance polyurethane foam performance
TWI315730B (en) 2001-08-15 2009-10-11 Dow Global Technologies Inc Process to manufacture polyurethane products
TW592813B (en) 2001-08-15 2004-06-21 Dow Global Technologies Inc Process to manufacture polyurethane products
US6562932B1 (en) 2001-10-12 2003-05-13 Bayer Corporation Light stable one-shot urethane-urea elastomers
US20060217516A1 (en) 2001-12-21 2006-09-28 Casati Francois M Tertiary amine modified polyurethane products made therefrom
WO2004060956A1 (en) 2002-12-17 2004-07-22 Dow Global Technologies Inc. Amine-epoxy autocatalytic polymers and polyurethane products made therefrom
US6825238B2 (en) 2003-01-29 2004-11-30 Air Products And Chemicals, Inc. Low acid organometallic catalyst for the production of flexible, semi-flexible and rigid polyurethane foams
KR20070053708A (ko) * 2004-08-04 2007-05-25 포움 서플라이즈 인코포레이션 폴리우레탄 폼에서의 반응도 변동 및 촉매 분해
US7691914B2 (en) 2005-04-25 2010-04-06 Cargill, Incorporated Polyurethane foams comprising oligomeric polyols
US8729146B2 (en) * 2005-06-14 2014-05-20 Momentive Performance Materials Inc. Catalyst composition and process using same
US20110152392A1 (en) 2009-12-17 2011-06-23 Honeywell International Inc. Catalysts For Polyurethane Foam Polyol Premixes Containing Halogenated Olefin Blowing Agents
US7666919B2 (en) 2006-03-14 2010-02-23 Air Products And Chemicals, Inc. Aromatic diacid ester diols and substituted carbamates thereof for minimizing deterioration of polyurethane foams
US8552077B2 (en) 2006-05-04 2013-10-08 Air Products And Chemicals, Inc. Trimer catalyst additives for improving foam processability
WO2008108250A1 (ja) * 2007-02-27 2008-09-12 Tosoh Corporation 軟質ポリウレタンフォーム製造用の触媒組成物
JP2009013247A (ja) 2007-07-03 2009-01-22 Central Glass Co Ltd 安定化された硬質ポリウレタンフォーム用プレミックス
US9550854B2 (en) 2007-10-12 2017-01-24 Honeywell International Inc. Amine catalysts for polyurethane foams
US9453115B2 (en) 2007-10-12 2016-09-27 Honeywell International Inc. Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents
JP5560553B2 (ja) 2008-10-31 2014-07-30 東ソー株式会社 ポリウレタン樹脂製造用のアミン触媒組成物及びそれを用いたポリウレタン樹脂の製造方法
US8778246B2 (en) 2008-10-31 2014-07-15 Ppg Industries Ohio, Inc Method for preparing polyurethane urea-containing films
BRPI0922975A2 (pt) 2008-12-17 2016-01-26 Dystar Colours Deutschland corantes para coloração de polímero, sua preparação e seu uso
WO2011038081A1 (en) 2009-09-25 2011-03-31 Arkema Inc. Biodegradable foams with improved dimensional stability
US20110144216A1 (en) 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
BR112013021214B1 (pt) 2011-02-21 2021-09-28 Honeywell International Inc Composição de pré-mistura de poliol
US9556303B2 (en) 2011-02-21 2017-01-31 Honeywell International Inc. Catalysts for polyurethane foam polyol premixes containing halogenated olefin blowing agents
US9051442B2 (en) 2011-02-21 2015-06-09 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
US20120313035A1 (en) 2011-06-08 2012-12-13 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
US10106638B2 (en) 2011-07-29 2018-10-23 Evonik Degussa Gmbh Reduced emissions low density spray polyurethane foam
JP5561261B2 (ja) 2011-09-20 2014-07-30 東ソー株式会社 ポリウレタン樹脂製造用の触媒組成物及びポリウレタン樹脂の製造方法
US9765009B2 (en) 2011-11-17 2017-09-19 Evonik Degussa Gmbh Processes, products, and compositions having tetraalkylguanidine salt of aromatic carboxylic acid
CN106397708A (zh) 2012-02-02 2017-02-15 阿科玛股份有限公司 通过包封活性组分改善的含有卤代烯烃的多元醇共混物的保质期
WO2014030654A1 (ja) 2012-08-21 2014-02-27 東ソー株式会社 ポリウレタンフォーム製造用の原料配合組成物及びポリウレタンフォーム又はイソシアヌレート変性ポリウレタンフォームの製造方法

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