BR112015004274A2 - formação de [2,2]paraciclofano e os compostos relacionados e métodos para a formação de polímeros a partir de ciclofanos - Google Patents
formação de [2,2]paraciclofano e os compostos relacionados e métodos para a formação de polímeros a partir de ciclofanosInfo
- Publication number
- BR112015004274A2 BR112015004274A2 BR112015004274A BR112015004274A BR112015004274A2 BR 112015004274 A2 BR112015004274 A2 BR 112015004274A2 BR 112015004274 A BR112015004274 A BR 112015004274A BR 112015004274 A BR112015004274 A BR 112015004274A BR 112015004274 A2 BR112015004274 A2 BR 112015004274A2
- Authority
- BR
- Brazil
- Prior art keywords
- cyclophanes
- formation
- paracyclophane
- gas
- related compounds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/12—Polycyclic non-condensed hydrocarbons
- C07C15/18—Polycyclic non-condensed hydrocarbons containing at least one group with formula
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/92—Systems containing at least three condensed rings with a condensed ring system consisting of at least two mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic system, e.g. cyclophanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
abstract the present invention is an improved process and method for the formation of stable intermediate cyclophanes. the invention provides for a general method for the production of substituted and unsubstituted cyclophanes. the components of the invention are a pyrolysis reaction tube that may be electrically heated into which a flowing stream of nitrous oxide with xylene vapor in an optional inert carrier gas at atmospheric pressure. the exit gas is condensed resulting in the deposition of [2,2']paracyclophane. additionally a process and method whereby the reactive intermediates of the reaction described above can be directly deposited and polymerized at atmospheric pressures or thereabout is disclosed. tradução do resumo resumo patente de invenção: formação de [2,2]paraciclofano e os compostos relacionados e métodos para a formação de polímeros a partir de ciclofanos. a presente invenção se refere a um processo melhorado e a um método para a formação de ciclofanos intermediários estáveis. a invenção apresenta um método geral para a produção de ciclofanos substituídos e não substituídos. os componentes da invenção são um tubo de reação de pirólise que pode ser aquecido de maneira elétrica, em que um fluxo de óxido nitroso com vapor de xileno em um gás transportador inerte opcional à pressão atmosférica. o gás de saída é condensado resultante da deposição de [2,2]paraciclofano. além disso, um processo e um método pelos quais os intermediários reativos da reação descrita acima podem ser depositados e polimerizados de maneira direta a pressões atmosféricas ou em torno disso são descritos.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/599,996 | 2012-08-30 | ||
| US13/599,996 US8633289B2 (en) | 2011-08-31 | 2012-08-30 | Formation of [2,2]paracyclophane and related compounds and methods for the formation of polymers from cyclophanes |
| PCT/US2012/072335 WO2014035456A2 (en) | 2012-08-30 | 2012-12-31 | Formation of [2,2] paracyclophane and related compounds and methods for the formation of polymers from cyclophanes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015004274A2 true BR112015004274A2 (pt) | 2017-07-04 |
| BR112015004274B1 BR112015004274B1 (pt) | 2021-11-09 |
Family
ID=48173049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015004274-0A BR112015004274B1 (pt) | 2012-08-30 | 2012-12-31 | Método para a produção de dímeros, trímeros, oligômeros e polímeros a partir da oxidação de um átomo de hidrogênio alfa para um anel aromático |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8633289B2 (pt) |
| EP (1) | EP2890665B1 (pt) |
| JP (1) | JP6195926B2 (pt) |
| KR (1) | KR101717278B1 (pt) |
| CN (1) | CN105026352B (pt) |
| AU (1) | AU2012388717B2 (pt) |
| BR (1) | BR112015004274B1 (pt) |
| CA (1) | CA2883372C (pt) |
| HK (1) | HK1212322A1 (pt) |
| IN (1) | IN2015DN01925A (pt) |
| MX (1) | MX371156B (pt) |
| MY (1) | MY171391A (pt) |
| SG (1) | SG11201501399WA (pt) |
| WO (1) | WO2014035456A2 (pt) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8940850B2 (en) | 2012-08-30 | 2015-01-27 | Carver Scientific, Inc. | Energy storage device |
| JP5358839B2 (ja) | 2007-10-05 | 2013-12-04 | カーバー サイエンティフィック，インコーポレイテッド | 高誘電率低漏洩キャパシタおよびエネルギー蓄積デバイス、ならびにそれらを作製するための方法 |
| US9011627B2 (en) | 2007-10-05 | 2015-04-21 | Carver Scientific, Inc. | Method of manufacturing high permittivity low leakage capacitor and energy storing device |
| US9214280B2 (en) | 2008-10-03 | 2015-12-15 | Carver Scientific, Inc. | Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices |
| US9214281B2 (en) | 2008-10-03 | 2015-12-15 | Carver Scientific, Inc. | Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices |
| US10227432B2 (en) | 2011-08-31 | 2019-03-12 | Carver Scientific, Inc. | Formation of xylylene type copolymers, block polymers, and mixed composition materials |
| US10199165B2 (en) | 2012-08-30 | 2019-02-05 | Carver Scientific, Inc. | Energy storage device |
| US9899846B2 (en) | 2012-08-30 | 2018-02-20 | Carver Scientific, Inc. | Entropic energy transfer methods and circuits |
| US9805869B2 (en) | 2012-11-07 | 2017-10-31 | Carver Scientific, Inc. | High energy density electrostatic capacitor |
| TWI720948B (zh) * | 2014-09-26 | 2021-03-11 | 美商卡福科學公司 | 伸二甲苯類型共聚物、嵌段聚合物及混合組成物材料之形成 |
| SG11201704406WA (en) | 2014-12-17 | 2017-07-28 | Carver Scient Inc | Method for chemical binding of the dielectric to the electrode after their assembly |
| CN107112759B (zh) | 2014-12-17 | 2021-02-26 | 卡弗科学有限公司 | 熵能转移方法以及电路 |
| SG11201803277XA (en) | 2015-11-06 | 2018-05-30 | Carver Scientific Inc | Electroentropic memory device |
| US10249409B2 (en) | 2016-06-21 | 2019-04-02 | Schlumberger Technology Corporation | Coated conductors |
| AU2017367692B2 (en) | 2016-12-02 | 2022-04-14 | Carver Scientific, Inc. | Memory device and capacitive energy storage device |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3149175A (en) * | 1960-08-22 | 1964-09-15 | Union Carbide Corp | Preparation of di-para-xylylenes |
| US3198844A (en) * | 1961-07-12 | 1965-08-03 | Minnesota Mining & Mfg | Cyclic products of para-xylylene |
| US3271417A (en) | 1963-02-06 | 1966-09-06 | Eastman Kodak Co | 1, 2-thiazetidine-3-one-1-oxides and their preparation |
| US3271471A (en) * | 1965-03-23 | 1966-09-06 | Union Carbide Corp | Dimerization process |
| US3342754A (en) | 1966-02-18 | 1967-09-19 | Union Carbide Corp | Para-xylylene polymers |
| US3616314A (en) | 1969-11-24 | 1971-10-26 | Dow Chemical Co | Electrolytic process for preparing(2.2)-paracyclophane |
| US3907748A (en) | 1974-06-17 | 1975-09-23 | University Patents Inc | Paracyclophane polymers and the production thereof |
| FR2457709A1 (fr) | 1979-05-29 | 1980-12-26 | Anvar | Nouveaux agents d'adsorption de gaz utiles en particulier pour separer de l'hydrogene d'une phase le renfermant |
| DE3240303C1 (de) | 1982-10-30 | 1984-01-19 | Merck Patent Gmbh, 6100 Darmstadt | Verfahren zur Herstellung von [2,2]-Paracyclophan |
| US4500562A (en) | 1983-03-02 | 1985-02-19 | The United States Of America As Represented By The United States Department Of Energy | Di-p-xylylene polymer and method for making the same |
| IT1191632B (it) | 1985-10-30 | 1988-03-23 | Montedison Spa | Processo per la preparazione di (2,2)-paraciolofano |
| IT1191645B (it) | 1985-12-19 | 1988-03-23 | Montedison Spa | Processo per la preparazione di (2,2)-paraciclofano e suoi derivati |
| IT1190647B (it) | 1986-06-27 | 1988-02-16 | Montedison Spa | Processo per la preparazione di (2,2)-paraciclofano e suoi derivati |
| IT1190350B (it) | 1986-06-27 | 1988-02-16 | Montedison Spa | Processo per la preparazione di (2,2)-paraciclofano e suoi derivati |
| IT1203876B (it) | 1987-04-10 | 1989-02-23 | Montedison Spa | Processo per la preparazione di (2,2)-paraciclofano e suoi derivati |
| US4849559A (en) | 1987-05-15 | 1989-07-18 | Union Carbide Corporation | Process for the preparation of dichloro-[2,2]paracyclophane |
| US4806702A (en) | 1987-05-26 | 1989-02-21 | Union Carbide Corporation | Process for the preparation of the parylene dimer |
| US4769505A (en) | 1987-07-17 | 1988-09-06 | Union Carbide Corporation | Process for the preparation of the parylene dimer |
| IT1222683B (it) | 1987-09-18 | 1990-09-12 | Montedison Spa | Processo per la preparazione del triciclo 8.2.2.2. esadeca 4,6,10,12,13,15 esaene clorurato nei nuclei benzenici |
| US5110903A (en) | 1990-12-20 | 1992-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the preparation of mixed parylene dimers free of alpha-halogens |
| US5324702A (en) * | 1991-11-22 | 1994-06-28 | Amoco Corporation | Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions |
| US5266291A (en) * | 1992-05-05 | 1993-11-30 | Praxair Technology, Inc. | Packed bed arrangement for oxidation reaction system |
| US6107184A (en) * | 1998-12-09 | 2000-08-22 | Applied Materials, Inc. | Nano-porous copolymer films having low dielectric constants |
-
2012
- 2012-08-30 US US13/599,996 patent/US8633289B2/en active Active
- 2012-12-31 MX MX2015002577A patent/MX371156B/es active IP Right Grant
- 2012-12-31 SG SG11201501399WA patent/SG11201501399WA/en unknown
- 2012-12-31 CN CN201280076532.2A patent/CN105026352B/zh active Active
- 2012-12-31 AU AU2012388717A patent/AU2012388717B2/en active Active
- 2012-12-31 EP EP12883727.5A patent/EP2890665B1/en active Active
- 2012-12-31 MY MYPI2015700600A patent/MY171391A/en unknown
- 2012-12-31 JP JP2015529779A patent/JP6195926B2/ja active Active
- 2012-12-31 WO PCT/US2012/072335 patent/WO2014035456A2/en active Application Filing
- 2012-12-31 KR KR1020157007263A patent/KR101717278B1/ko active IP Right Grant
- 2012-12-31 IN IN1925DEN2015 patent/IN2015DN01925A/en unknown
- 2012-12-31 CA CA2883372A patent/CA2883372C/en active Active
- 2012-12-31 BR BR112015004274-0A patent/BR112015004274B1/pt active IP Right Grant
-
2016
- 2016-01-07 HK HK16100103.6A patent/HK1212322A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MY171391A (en) | 2019-10-10 |
| HK1212322A1 (en) | 2016-06-10 |
| WO2014035456A3 (en) | 2015-06-25 |
| SG11201501399WA (en) | 2015-03-30 |
| US20130109827A1 (en) | 2013-05-02 |
| EP2890665A2 (en) | 2015-07-08 |
| IN2015DN01925A (pt) | 2015-08-07 |
| KR20150044955A (ko) | 2015-04-27 |
| EP2890665A4 (en) | 2016-05-25 |
| CN105026352A (zh) | 2015-11-04 |
| JP6195926B2 (ja) | 2017-09-13 |
| KR101717278B1 (ko) | 2017-03-16 |
| JP2015529205A (ja) | 2015-10-05 |
| MX371156B (es) | 2020-01-20 |
| CA2883372A1 (en) | 2014-03-06 |
| BR112015004274B1 (pt) | 2021-11-09 |
| MX2015002577A (es) | 2015-06-10 |
| US8633289B2 (en) | 2014-01-21 |
| EP2890665B1 (en) | 2019-05-22 |
| WO2014035456A2 (en) | 2014-03-06 |
| CA2883372C (en) | 2019-10-15 |
| CN105026352B (zh) | 2018-03-16 |
| AU2012388717B2 (en) | 2017-03-09 |
| AU2012388717A1 (en) | 2015-03-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 31/12/2012, OBSERVADAS AS CONDICOES LEGAIS. |