BR112014032213A2 - processo para reformar hidrocarbonetos - Google Patents
processo para reformar hidrocarbonetosInfo
- Publication number
- BR112014032213A2 BR112014032213A2 BR112014032213A BR112014032213A BR112014032213A2 BR 112014032213 A2 BR112014032213 A2 BR 112014032213A2 BR 112014032213 A BR112014032213 A BR 112014032213A BR 112014032213 A BR112014032213 A BR 112014032213A BR 112014032213 A2 BR112014032213 A2 BR 112014032213A2
- Authority
- BR
- Brazil
- Prior art keywords
- reforming
- heat exchange
- synthesis gas
- autothermal
- relates
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2445—Stationary reactors without moving elements inside placed in parallel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/388—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the heat being generated by superheated steam
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- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
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- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
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- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- B01J2219/00277—Apparatus
- B01J2219/00495—Means for heating or cooling the reaction vessels
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- B01J2219/00583—Features relative to the processes being carried out
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2219/0059—Sequential processes
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- B01J2219/00718—Type of compounds synthesised
- B01J2219/00756—Compositions, e.g. coatings, crystals, formulations
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/068—Ammonia synthesis
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C01B2203/1235—Hydrocarbons
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- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
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- C01B2203/16—Controlling the process
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical & Material Sciences (AREA)
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- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
resumo processo para reformar hidrocarbonetos a invenção refere-se à produção de gás de síntese particularmente por meio de uma disposição em série de estágios de reformação por permutação de calor e de reformação autotérmica, no qual o calor necessário para as reações de reformação no estágio de reformação por permutação de calor é fornecido por gás de síntese efluente quente do estágio de reformação autotérmica. mais particularmente, a invenção se refere à otimização da operação e controle de uma disposição de estágios de reformação por permutação de calor e de reformação autotérmica e introdução de uma caldeira de calor residual adicional.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12172986.7A EP2676924A1 (en) | 2012-06-21 | 2012-06-21 | Process for Reforming Hydrocarbons |
EP12172986.7 | 2012-06-21 | ||
US13/542,292 | 2012-07-05 | ||
US13/542,292 US9156689B2 (en) | 2012-06-21 | 2012-07-05 | Process for reforming hydrocarbons |
US201261721359P | 2012-11-01 | 2012-11-01 | |
US61/721,359 | 2012-11-01 | ||
PCT/EP2013/062096 WO2013189791A1 (en) | 2012-06-21 | 2013-06-12 | Process for reforming hydrocarbons |
Publications (2)
Publication Number | Publication Date |
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BR112014032213A2 true BR112014032213A2 (pt) | 2017-06-27 |
BR112014032213B1 BR112014032213B1 (pt) | 2021-08-10 |
Family
ID=46320816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014032213-9A BR112014032213B1 (pt) | 2012-06-21 | 2013-06-12 | Processo para a produção de gás de síntese de uma matéria-prima de hidrocarboneto, método de uso de um processo, processo para inicializar a seção de síntese de hidrocarboneto |
Country Status (13)
Country | Link |
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US (3) | US9156689B2 (pt) |
EP (2) | EP2676924A1 (pt) |
KR (1) | KR102060451B1 (pt) |
CN (1) | CN104411625B (pt) |
AR (1) | AR091493A1 (pt) |
AU (1) | AU2013279617B2 (pt) |
BR (1) | BR112014032213B1 (pt) |
CA (1) | CA2877165C (pt) |
EA (1) | EA030103B1 (pt) |
MX (1) | MX349716B (pt) |
UA (1) | UA117459C2 (pt) |
WO (1) | WO2013189791A1 (pt) |
ZA (1) | ZA201409403B (pt) |
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EP2794465B1 (en) * | 2011-12-19 | 2018-07-18 | Stamicarbon B.V. acting under the name of MT Innovation Center | Process for producing ammonia and urea |
US9561968B2 (en) * | 2013-08-07 | 2017-02-07 | Kellogg Brown & Root Llc | Methods and systems for producing and processing syngas in a pressure swing adsorption unit and making ammonia therefrom |
US10093541B2 (en) | 2014-02-28 | 2018-10-09 | Haldor Topsoe A/S | Process for producing synthesis gas |
EP3050849A1 (en) * | 2015-01-27 | 2016-08-03 | Casale SA | A process for the synthesis of ammonia |
CN105623716B (zh) * | 2016-02-23 | 2017-08-25 | 石玉林 | 一种半再生催化重整反应系统及方法 |
DE102016108792A1 (de) * | 2016-05-12 | 2017-11-16 | Thyssenkrupp Ag | Verfahren zur Bildung eines Synthesegases |
US9938217B2 (en) | 2016-07-01 | 2018-04-10 | Res Usa, Llc | Fluidized bed membrane reactor |
WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
US10189763B2 (en) | 2016-07-01 | 2019-01-29 | Res Usa, Llc | Reduction of greenhouse gas emission |
DE102017201681A1 (de) | 2017-02-02 | 2018-08-02 | Thyssenkrupp Ag | Verfahren zur Behandlung eines Synthesegasstroms |
CN110944938A (zh) | 2017-07-25 | 2020-03-31 | 托普索公司 | 用于制备合成气的方法 |
AU2018305876B2 (en) | 2017-07-25 | 2023-12-14 | Haldor Topsøe A/S | Method for the preparation of synthesis gas |
WO2019020522A1 (en) | 2017-07-25 | 2019-01-31 | Haldor Topsøe A/S | PROCESS FOR THE COPRODUCTION OF METHANOL AND AMMONIA |
PL3658491T3 (pl) | 2017-07-25 | 2024-02-05 | Topsoe A/S | Sposób wytwarzania gazu do syntezy amoniaku |
GB2571136A (en) * | 2018-02-20 | 2019-08-21 | Reinertsen New Energy As | Gas processing |
AU2019361144A1 (en) | 2018-10-15 | 2021-04-22 | Haldor Topsøe A/S | Method for the preparation of synthesis gas |
EP3931147B1 (en) * | 2019-02-28 | 2023-06-07 | Topsoe A/S | Chemical plant with a reforming section and a process for producing a chemical product |
EA202192743A1 (ru) | 2019-04-08 | 2022-02-17 | Хальдор Топсёэ А/С | Установка химического синтеза |
DE102019211133A1 (de) * | 2019-07-26 | 2021-01-28 | Thyssenkrupp Ag | Reformeranordnung zur Herstellung von Synthesegas und/oder Wasserstoff |
EP3838841B1 (en) * | 2019-12-19 | 2023-11-01 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Process for start-up of an autothermal reformer |
US20220251455A1 (en) * | 2021-02-05 | 2022-08-11 | Infinium Technology, Llc | Efficent 2-step process for the direct production of liquid fuels from carbon dioxide and hydrogen |
BR102021007738A2 (pt) * | 2021-04-22 | 2022-11-01 | Petróleo Brasileiro S.A. - Petrobras | Método de manutenção da atividade de catalisadores de pré-reforma |
US11897769B2 (en) * | 2021-08-20 | 2024-02-13 | Air Products And Chemicals, Inc. | Process for H2 and syngas production |
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US4337170A (en) | 1980-01-23 | 1982-06-29 | Union Carbide Corporation | Catalytic steam reforming of hydrocarbons |
IT1141031B (it) | 1980-08-29 | 1986-10-01 | Snam Progetti | Procedimento per la preparazione di gas contenenti idrogeno ed azoto |
FR2522473B2 (fr) | 1981-04-02 | 1985-07-26 | Agro Technics Internal Ltd | Procede de culture fourragere hors sol et dispositif pour sa realisation |
DK147705C (da) | 1982-09-07 | 1985-05-13 | Haldor Topsoe As | Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas |
DK149529C (da) | 1983-05-11 | 1986-12-22 | Haldor Topsoe As | Fremgangsmaade til fremstilling af syntetiske carbonhydrider ud fra syntesegas |
ATE69559T1 (de) | 1985-06-27 | 1991-12-15 | Stone & Webster Eng Corp | Erzeugung von synthesegas durch konvektionsreformieren. |
DE68909979D1 (de) | 1988-03-24 | 1993-11-25 | Ici Plc | Zweistufiges Dampfreformierungsverfahren. |
US5011625A (en) | 1989-12-11 | 1991-04-30 | The M. W. Kellogg Company | Autothermal steam reforming process |
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NZ242569A (en) | 1991-05-30 | 1994-07-26 | British Petroleum Co Plc | Process for the conversion of natural gas into higher hydrocarbons by reforming combined with a fischer-tropsch process |
EP0959120B1 (en) * | 1996-10-03 | 2006-08-02 | Hajime Kato | Method for hydrocarbon steam reforming |
GB9817526D0 (en) * | 1998-08-13 | 1998-10-07 | Ici Plc | Steam reforming |
DK173742B1 (da) | 1998-09-01 | 2001-08-27 | Topsoe Haldor As | Fremgangsmåde og reaktorsystem til fremstilling af syntesegas |
PT1106570E (pt) | 1999-12-02 | 2013-10-15 | Haldor Topsoe As | Processo e reactor para realizar reacções catalíticas não adiabáticas |
GB0130145D0 (en) * | 2001-12-17 | 2002-02-06 | Ici Plc | Metal passivation |
EP1413547A1 (en) * | 2002-09-26 | 2004-04-28 | Haldor Topsoe A/S | Process for the production of synthesis gas |
GB0225961D0 (en) | 2002-11-07 | 2002-12-11 | Johnson Matthey Plc | Production of hydrocarbons |
DE102006023248C5 (de) * | 2006-05-18 | 2018-01-25 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas |
US20090184293A1 (en) | 2008-01-18 | 2009-07-23 | Han Pat A | Process for reforming hydrocarbons |
WO2012084135A1 (en) * | 2010-12-22 | 2012-06-28 | Haldor Topsøe A/S | Process for reforming hydrocarbon |
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2012
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2013
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- 2013-06-12 CN CN201380032077.0A patent/CN104411625B/zh active Active
- 2013-06-12 EP EP13728194.5A patent/EP2864243A1/en not_active Withdrawn
- 2013-06-12 WO PCT/EP2013/062096 patent/WO2013189791A1/en active Application Filing
- 2013-06-12 EA EA201590063A patent/EA030103B1/ru not_active IP Right Cessation
- 2013-06-12 MX MX2014015216A patent/MX349716B/es active IP Right Grant
- 2013-06-12 US US14/410,045 patent/US9434613B2/en active Active
- 2013-06-12 CA CA2877165A patent/CA2877165C/en active Active
- 2013-06-12 UA UAA201500432A patent/UA117459C2/uk unknown
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- 2013-06-12 BR BR112014032213-9A patent/BR112014032213B1/pt not_active IP Right Cessation
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AR091493A1 (es) | 2015-02-11 |
MX349716B (es) | 2017-08-10 |
CA2877165C (en) | 2019-07-23 |
US20130345324A1 (en) | 2013-12-26 |
US20160325253A1 (en) | 2016-11-10 |
AU2013279617B2 (en) | 2016-11-24 |
US9156689B2 (en) | 2015-10-13 |
EA030103B1 (ru) | 2018-06-29 |
ZA201409403B (en) | 2016-08-31 |
CN104411625A (zh) | 2015-03-11 |
CA2877165A1 (en) | 2013-12-27 |
MX2014015216A (es) | 2015-03-05 |
EP2864243A1 (en) | 2015-04-29 |
US20150321913A1 (en) | 2015-11-12 |
BR112014032213B1 (pt) | 2021-08-10 |
KR102060451B1 (ko) | 2020-02-11 |
CN104411625B (zh) | 2017-05-17 |
EP2676924A1 (en) | 2013-12-25 |
AU2013279617A1 (en) | 2015-01-22 |
UA117459C2 (uk) | 2018-08-10 |
US9434613B2 (en) | 2016-09-06 |
US10029224B2 (en) | 2018-07-24 |
EA201590063A1 (ru) | 2015-05-29 |
WO2013189791A1 (en) | 2013-12-27 |
KR20150028311A (ko) | 2015-03-13 |
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