BR112014029361A2 - método de produção de ácido tereftálico e seus derivados - Google Patents

método de produção de ácido tereftálico e seus derivados

Info

Publication number
BR112014029361A2
BR112014029361A2 BR112014029361A BR112014029361A BR112014029361A2 BR 112014029361 A2 BR112014029361 A2 BR 112014029361A2 BR 112014029361 A BR112014029361 A BR 112014029361A BR 112014029361 A BR112014029361 A BR 112014029361A BR 112014029361 A2 BR112014029361 A2 BR 112014029361A2
Authority
BR
Brazil
Prior art keywords
terephthalic acid
derivatives
production method
isobutene
xylene
Prior art date
Application number
BR112014029361A
Other languages
English (en)
Inventor
D Frey Guido
Strutz Heinz
Klabunde Jens
Original Assignee
Oxea Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxea Gmbh filed Critical Oxea Gmbh
Publication of BR112014029361A2 publication Critical patent/BR112014029361A2/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
    • C07C2/44—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion of conjugated dienes only
    • C07C2/46—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/026—Unsaturated compounds, i.e. alkenes, alkynes or allenes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/44—Polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/18—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo patente de invenção: "método de produção de ácido tereftálico e seus derivados". a presente invenção refere-se a um método de produção de derivados de ácido tereftálico de isobuteno por meio de p-xileno. o isobuteno é fermentativamente produzido, a pureza elevada do qual melhora o método e as propriedades do p-xileno produzido e dos derivados de ácido tereftálico derivados dos mesmos.
BR112014029361A 2012-07-02 2013-06-20 método de produção de ácido tereftálico e seus derivados BR112014029361A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012105876.8A DE102012105876A1 (de) 2012-07-02 2012-07-02 Verfahren zur Herstellung von Terephthalsäure und ihren Derivaten
PCT/EP2013/062853 WO2014005846A1 (de) 2012-07-02 2013-06-20 Verfahren zur herstellung von terephthalsäure und ihren derivaten

Publications (1)

Publication Number Publication Date
BR112014029361A2 true BR112014029361A2 (pt) 2017-06-27

Family

ID=48670559

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014029361A BR112014029361A2 (pt) 2012-07-02 2013-06-20 método de produção de ácido tereftálico e seus derivados

Country Status (8)

Country Link
US (1) US20150166457A1 (pt)
EP (1) EP2867198A1 (pt)
JP (1) JP2015522572A (pt)
CN (1) CN104302613A (pt)
BR (1) BR112014029361A2 (pt)
DE (1) DE102012105876A1 (pt)
TW (1) TW201402818A (pt)
WO (1) WO2014005846A1 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012105877A1 (de) * 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Diisobuten
WO2024075678A1 (ja) * 2022-10-07 2024-04-11 株式会社Adeka バイオ由来分岐アルキルグリセリルエーテルの製造方法及び該方法により製造されるバイオ由来分岐アルキルグリセリルエーテル

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2813119A (en) 1954-05-07 1957-11-12 Hercules Powder Co Ltd Hydrocarbon oxidation
NL6610623A (pt) 1965-07-28 1967-01-30
US3850981A (en) 1968-04-16 1974-11-26 Celanese Corp Liquid phase oxidation of p-xylene to terephthalic acid
US3644550A (en) 1969-04-21 1972-02-22 Gulf Research Development Co Single stage cyclodimerization of paraffins to aromatic compounds
US3830866A (en) 1970-10-27 1974-08-20 Atlantic Richfield Co Process for the catalytic conversion of olefins to aromatics
JPS5328419B1 (pt) 1971-04-26 1978-08-15
US3836603A (en) 1973-03-29 1974-09-17 Atlantic Richfield Co Process for preparing para-xylene
US4096340A (en) 1975-06-03 1978-06-20 Teijin Hercules Chemical Co., Ltd. Process for the preparation of dimethyl terephthalate
JPS5384933A (en) 1976-12-30 1978-07-26 Mitsubishi Chem Ind Ltd Preparation of terephthalic acid
US4100220A (en) 1977-06-27 1978-07-11 Petro-Tex Chemical Corporation Dimerization of isobutene
US4241220A (en) 1977-12-28 1980-12-23 Mitsui Petrochemical Industries, Ltd. Process for producing terephthalic acid
US4229320A (en) 1979-01-22 1980-10-21 Shell Oil Company Catalyst for making para-xylene
US4384154A (en) 1980-12-22 1983-05-17 Shell Oil Company Conversion of isobutene to aromatics
US4342876A (en) 1980-12-22 1982-08-03 Bechtel International Corporation Method for oxidation of p-xylene and method for preparing dimethylterephthalate
US4447668A (en) 1982-03-29 1984-05-08 Chemical Research & Licensing Company Process for producing high purity isoolefins and dimers thereof by dissociation of ethers
DE3407925C1 (de) 1984-03-03 1985-09-05 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur Herstellung von Terephthalsaeuredimethylester aus p-Xylol und Methanol
JPS6192579A (ja) 1984-10-09 1986-05-10 Hideo Fukuda 炭化水素混合物の製造法
DE3704720A1 (de) 1987-02-14 1988-08-25 Huels Troisdorf Verfahren und vorrichtung zur herstellung von benzolcarbonsaeuren bzw. benzoldicarbonsaeureestern
US5877372A (en) 1997-11-21 1999-03-02 Arco Chemical Technology, L.P. Isobutylene oligomerization using isooctane diluent
DE10113381A1 (de) 2001-02-13 2002-08-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von hochreinem Diisobuten
DE10327215A1 (de) 2003-06-17 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Isobuten aus tert.-Butanol
JP2011505490A (ja) * 2007-12-03 2011-02-24 ジーヴォ，インコーポレイテッド 再生可能組成物
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EP2336340A1 (en) 2009-12-21 2011-06-22 Philippe Marliere Method for producing an alkene comprising the step of converting an alcohol by an enzymatic dehydration step
EP2336341A1 (en) 2009-12-21 2011-06-22 Philippe Marliere Method for producing an alkene comprising the step of converting an alcohol by an enzymatic dehydration step
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BR112013009078A2 (pt) 2010-10-19 2016-07-19 Global Bioenergies produção de alquenos por conversão enzimática combinada de ácidos 3-hidroxialcanoicos
TW201307434A (zh) * 2011-06-17 2013-02-16 Toray Industries 源自生質資源之聚酯之製造方法及源自生質資源之聚酯

Also Published As

Publication number Publication date
EP2867198A1 (de) 2015-05-06
JP2015522572A (ja) 2015-08-06
DE102012105876A1 (de) 2014-01-02
CN104302613A (zh) 2015-01-21
US20150166457A1 (en) 2015-06-18
WO2014005846A1 (de) 2014-01-09
TW201402818A (zh) 2014-01-16

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Legal Events

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B08F Application fees: application dismissed [chapter 8.6 patent gazette]

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]