BR112014027793A2 - oligomerização de compostos olefínicos com formação de polímero reduzida - Google Patents

oligomerização de compostos olefínicos com formação de polímero reduzida

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Publication number
BR112014027793A2
BR112014027793A2 BR112014027793A BR112014027793A BR112014027793A2 BR 112014027793 A2 BR112014027793 A2 BR 112014027793A2 BR 112014027793 A BR112014027793 A BR 112014027793A BR 112014027793 A BR112014027793 A BR 112014027793A BR 112014027793 A2 BR112014027793 A2 BR 112014027793A2
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BR
Brazil
Prior art keywords
oligomerization
catalyst
olefinic compounds
containing additive
reduced polymer
Prior art date
Application number
BR112014027793A
Other languages
English (en)
Other versions
BR112014027793B1 (pt
Inventor
Matthew Smith David
John Hanton Martin
John Evans Stephen
Fullard Gabrielli William
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of BR112014027793A2 publication Critical patent/BR112014027793A2/pt
Publication of BR112014027793B1 publication Critical patent/BR112014027793B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/78—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/30—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

resumo patente de invenção: "oligomerização de compostos olefínicos com formação de polímero reduzida". a presente invenção refere-se a um processo para oligomerização de um composto olefínico para produção de um produto oligomérico é realizado na presença de um catalisador ativado, um aditivo não metálico contendo oxigênio e opcionalmente um composto de zinco. o catalisador de oligomerização é um catalisador ativado, que é fornecido por combinação de uma fonte de cromo, um composto de ligação, e um ativador de catalisador ou a combinação de ativadores de catalisador. o aditivo não metálico contendo oxigênio está presente em uma quantidade tal que a proporção da quantidade molar do aditivo não metálico contendo oxigênio para a quantidade molar de cromo na fonte de cromo por 106 g/g de produtividade de cr esteja entre 0,01 e 400. 22555473v1 1/1 22555473v1
BR112014027793-1A 2012-05-09 2013-05-08 Processos para produção de um produto oligomérico por oligomerização e para ativar um catalisador de oligomerização BR112014027793B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261644733P 2012-05-09 2012-05-09
US61/644,733 2012-05-09
PCT/IB2013/053693 WO2013168103A1 (en) 2012-05-09 2013-05-08 Oligomerisation of olefinic compounds with reduced polymer formation

Publications (2)

Publication Number Publication Date
BR112014027793A2 true BR112014027793A2 (pt) 2017-07-18
BR112014027793B1 BR112014027793B1 (pt) 2021-11-09

Family

ID=48699874

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014027793-1A BR112014027793B1 (pt) 2012-05-09 2013-05-08 Processos para produção de um produto oligomérico por oligomerização e para ativar um catalisador de oligomerização

Country Status (13)

Country Link
US (1) US9447202B2 (pt)
EP (1) EP2847149B1 (pt)
KR (1) KR102088445B1 (pt)
CN (1) CN104271537B (pt)
BR (1) BR112014027793B1 (pt)
CA (1) CA2866971C (pt)
ES (1) ES2904662T3 (pt)
IN (1) IN2014DN10415A (pt)
MX (1) MX352923B (pt)
MY (1) MY164153A (pt)
SG (1) SG11201407140SA (pt)
WO (1) WO2013168103A1 (pt)
ZA (1) ZA201406072B (pt)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2764913A1 (en) * 2013-02-11 2014-08-13 Linde AG Method for purifying a crude PNPNH compound
KR101657259B1 (ko) * 2013-11-19 2016-09-13 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
KR101607214B1 (ko) * 2014-06-18 2016-03-29 주식회사 엘지화학 올레핀 올리고머의 제조 방법
EP3286172B1 (en) 2015-04-23 2019-06-12 Constellation Pharmaceuticals, Inc. Lsd1 inhibitors and uses thereof
KR20160134464A (ko) 2015-05-15 2016-11-23 주식회사 엘지화학 혼성 담지 촉매계, 및 이를 이용한 폴리올레핀의 제조방법
AT517626B1 (de) * 2015-09-02 2017-06-15 Technische Universität Wien Verwendung neuer Aryliodonium- und Sulfoniumsalze als Photoinitiatoren
KR102058142B1 (ko) 2015-09-02 2019-12-20 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
KR101761830B1 (ko) 2015-10-21 2017-07-26 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
KR101982789B1 (ko) 2015-12-04 2019-05-27 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
US10414699B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Process improvements in selective ethylene oligomerizations
US10414698B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10329212B2 (en) 2016-05-27 2019-06-25 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
KR102563683B1 (ko) 2016-07-18 2023-08-07 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
RS64889B1 (sr) 2016-10-26 2023-12-29 Constellation Pharmaceuticals Inc Inhibitori lsd1 i njihova medicinska upotreba
US10232339B2 (en) 2017-06-06 2019-03-19 Chevron Phillips Chemical Company Lp Fouling protection for an oligomerization reactor inlet
US10464862B2 (en) 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
KR102087994B1 (ko) * 2018-06-07 2020-03-12 아주대학교산학협력단 에틸렌 사량화 촉매 시스템 제조 방법, 에틸렌 사량화 촉매 시스템, 에틸렌 사량체 제조 방법, 및 비스포스핀 리간드 화합물
EP3805240B1 (en) 2018-06-07 2022-12-14 Ajou University Industry-Academic Cooperation Foundation Bisphosphine ligand compound, chromium compound, ethylene oligomerization catalyst system, and ethylene oligomer preparing method
WO2022060108A1 (ko) * 2020-09-15 2022-03-24 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 시스템
AR124332A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS
CN114160199B (zh) * 2021-11-02 2024-01-16 浙江智英石化技术有限公司 乙烯选择性三聚和四聚的催化体系及其应用
KR20230134931A (ko) * 2022-03-15 2023-09-22 한화토탈에너지스 주식회사 에틸렌 올리고머화 방법 및 그 에틸렌 올리고머
CN115028509B (zh) * 2022-07-01 2024-02-02 万华化学集团股份有限公司 反应活性提升和聚合物形成降低的乙烯齐聚工艺

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540755A (en) * 1982-09-30 1985-09-10 National Petro Chemicals Corporation Inclusion of oxygen in the polymerization of olefins
SG99843A1 (en) 1992-09-17 2003-11-27 Mitsubishi Chem Corp Method for oligomerizing an alpha-olefin
TW354300B (en) 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
JP3492396B2 (ja) 1993-05-06 2004-02-03 日本ポリオレフィン株式会社 オレフィン類の精製方法
MY115177A (en) 1994-06-21 2003-04-30 Mitsubishi Chem Corp Process for producing (alpha) -olefin oligomers
JP3503245B2 (ja) 1995-03-14 2004-03-02 三菱化学株式会社 α−オレフイン低重合体の製造方法
US5856257A (en) 1997-05-16 1999-01-05 Phillips Petroleum Company Olefin production
US6022933A (en) * 1997-08-14 2000-02-08 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of polyethylene
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
JP4266827B2 (ja) 2001-12-20 2009-05-20 サソル テクノロジー （ピーティーワイ）リミテッド クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化
EP1456152B1 (en) 2001-12-20 2012-06-13 Sasol Technology (Pty) Ltd Trimerisation and oligomerisation of olefins using a chromium based catalyst
AU2003297547A1 (en) 2002-12-20 2004-07-14 Sasol Technology (Pty) Limited Tandem tetramerisation-polymerisation of olefins
ATE457196T1 (de) 2002-12-20 2010-02-15 Sasol Tech Pty Ltd Trimerisierung von olefinen
DE102005022593A1 (de) 2004-05-18 2006-02-16 Sasol Wax (South Africa) (Pty.) Ltd. Polymerisation von Olefinverbindungen
CA2570054C (en) 2004-06-18 2012-10-02 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds in an aliphatic medium
ATE523250T1 (de) 2004-06-18 2011-09-15 Sasol Tech Pty Ltd Oligomerisation in gegenwart sowohl eines tetramerisationskatalysators als auch eines weiteren oligomerisationskatalysators
WO2006107373A1 (en) * 2005-03-31 2006-10-12 Exxonmobil Chemical Patents Inc. Processes for producing high density polyethylene
ES2390858T5 (es) 2005-07-12 2016-09-20 Sasol Technology (Pty) Ltd Oligomerización de compuestos olefínicos en presencia de un activador diluido con contenido en metal
GB0520085D0 (en) 2005-10-03 2005-11-09 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
CN101687189A (zh) 2007-05-28 2010-03-31 Sasol技术股份有限公司 低聚催化剂的两段活化和在如此活化的低聚催化剂的存在下烯属化合物的低聚
MY148675A (en) 2007-07-11 2013-05-31 Linde Ag Catalyst composition and process for di-, tri-and/or tetramerization of ethylene
MX2010005266A (es) 2007-11-28 2010-06-02 Linde Ag Composicion catalizadora y proceso para oligomerizacion de etileno.
CN101932617B (zh) * 2008-02-27 2012-10-03 尤尼威蒂恩技术有限责任公司 改性的铬系催化剂和使用其的聚合方法
CA2639882C (en) 2008-09-29 2016-07-12 Nova Chemicals Corporation Tetramerization
US9035119B2 (en) 2009-02-16 2015-05-19 Sasol Technology (Pty) Limited Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst
IN2012DN03367A (pt) * 2009-10-19 2015-10-23 Sasol Technolgoy Pty Ltd
CN106083927B (zh) 2009-12-31 2018-10-26 切弗朗菲利浦化学公司 膦基脒化合物、金属络合物、催化剂系统以及它们低聚或聚合烯烃的用途
EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
CA2703435C (en) * 2010-05-12 2017-05-02 Nova Chemicals Corporation Oligomerization process using a chromium p-n-p catalyst with added alkyl zinc

Also Published As

Publication number Publication date
KR102088445B1 (ko) 2020-03-13
KR20150006474A (ko) 2015-01-16
MX2014011595A (es) 2014-11-21
CA2866971A1 (en) 2013-11-14
EP2847149B1 (en) 2022-01-12
SG11201407140SA (en) 2014-11-27
MX352923B (es) 2017-12-14
MY164153A (en) 2017-11-30
BR112014027793B1 (pt) 2021-11-09
US20150152200A1 (en) 2015-06-04
CN104271537B (zh) 2017-03-08
ES2904662T3 (es) 2022-04-05
ZA201406072B (en) 2015-11-25
EP2847149A1 (en) 2015-03-18
CN104271537A (zh) 2015-01-07
WO2013168103A1 (en) 2013-11-14
US9447202B2 (en) 2016-09-20
CA2866971C (en) 2020-07-07
IN2014DN10415A (pt) 2015-08-14

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 08/05/2013, OBSERVADAS AS CONDICOES LEGAIS.