AR124332A1 - UN PROCESO PARA PRODUCIR a-OLEFINAS - Google Patents
UN PROCESO PARA PRODUCIR a-OLEFINASInfo
- Publication number
- AR124332A1 AR124332A1 ARP210103465A ARP210103465A AR124332A1 AR 124332 A1 AR124332 A1 AR 124332A1 AR P210103465 A ARP210103465 A AR P210103465A AR P210103465 A ARP210103465 A AR P210103465A AR 124332 A1 AR124332 A1 AR 124332A1
- Authority
- AR
- Argentina
- Prior art keywords
- olefins
- oligomerization
- reaction zone
- oligomerization reaction
- catalyst system
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 238000006384 oligomerization reaction Methods 0.000 abstract 18
- 239000003054 catalyst Substances 0.000 abstract 8
- 239000004711 α-olefin Substances 0.000 abstract 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 5
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- 239000001301 oxygen Substances 0.000 abstract 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
- C07C2/34—Metal-hydrocarbon complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Abstract
Un proceso para producir a-olefinas que comprende poner en contacto una alimentación de etileno con un sistema de catalizador de oligomerización en una zona de reacción de oligomerización en condiciones de reacción de oligomerización para producir una corriente de producto que comprende a-olefinas en donde el sistema de catalizador comprende un complejo de hierro-ligando y un cocatalizador y la relación molar de oxígeno con respecto a hierro que se alimenta a la zona de reacción de oligomerización es de 1:1 a 200:1. Alternativamente, la relación molar de oxígeno con respecto a aluminio en MMAO que se alimenta a la zona de reacción de oligomerización es menor de 1:5. Reivindicación 1: Un proceso para producir a-olefinas que comprende poner en contacto una alimentación de etileno con un sistema de catalizador de oligomerización en una zona de reacción de oligomerización en condiciones de reacción de oligomerización para producir una corriente de producto que comprende a-olefinas en donde el sistema de catalizador comprende un complejo de hierro-ligando y un cocatalizador y la relación molar de oxígeno con respecto a hierro que se alimenta a la zona de reacción de oligomerización es de 1:1 a 200:1. Reivindicación 12: Un proceso para producir a-olefinas que comprende poner en contacto una alimentación de etileno con un sistema de catalizador de oligomerización en una zona de reacción de oligomerización en condiciones de reacción de oligomerización para producir una corriente de producto que comprende a-olefinas en donde el sistema de catalizador comprende un complejo de hierro-ligando y un cocatalizador que comprende aluminio y la relación molar de oxígeno con respecto a aluminio en MMAO que se alimenta a la zona de reacción de oligomerización es menor de 1:5. Reivindicación 14: Un proceso para producir a-olefinas que comprende poner en contacto una alimentación de etileno con un sistema de catalizador de oligomerización en una zona de reacción de oligomerización en condiciones de reacción de oligomerización para producir una corriente de producto que comprende a-olefinas en donde el sistema de catalizador comprende un complejo de hierro-ligando y un cocatalizador y el oxígeno alimentado a la zona de reacción de oligomerización está a una concentración de 0,2 a 200 ppmw, calculada en función del contenido de la zona de reacción de oligomerización.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202063125713P | 2020-12-15 | 2020-12-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR124332A1 true AR124332A1 (es) | 2023-03-15 |
Family
ID=79287830
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP210103465A AR124332A1 (es) | 2020-12-15 | 2021-12-13 | UN PROCESO PARA PRODUCIR a-OLEFINAS |
Country Status (7)
Country | Link |
---|---|
US (1) | US20230416171A1 (es) |
EP (1) | EP4263475A1 (es) |
JP (1) | JP2024500384A (es) |
CN (1) | CN116615402A (es) |
AR (1) | AR124332A1 (es) |
CA (1) | CA3203759A1 (es) |
WO (1) | WO2022132734A1 (es) |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GC0000291A (en) | 2000-06-30 | 2006-11-01 | Shell Int Research | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
CZ2004163A3 (cs) | 2001-08-01 | 2004-09-15 | Shell Internationale Research Maatschappij B.V. | Ligandy a katalytické systémy s jejich obsahem pro oligomeraci ethylenu na lineární alfa-olefiny |
EP1456152B1 (en) * | 2001-12-20 | 2012-06-13 | Sasol Technology (Pty) Ltd | Trimerisation and oligomerisation of olefins using a chromium based catalyst |
CA2723515C (en) | 2010-12-01 | 2018-05-15 | Nova Chemicals Corporation | Heat management in ethylene oligomerization |
MX352923B (es) * | 2012-05-09 | 2017-12-14 | Sasol Tech Pty Ltd | Oligomerizacion de compuestos olefinicos con menor formacion de polimeros. |
CN102850168B (zh) | 2012-09-19 | 2015-02-25 | 浙江大学 | 一种防止或减少在反应器内壁形成粘附物的乙烯齐聚反应工艺 |
US9266983B2 (en) * | 2013-04-17 | 2016-02-23 | China Petroleum & Chemical Corporation | Catalyst composition and process for ethylene oligomerization |
US20210009486A1 (en) * | 2018-03-23 | 2021-01-14 | Exxonmobil Chemical Patents Inc. | Linear Alpha Olefin Processes |
-
2021
- 2021-12-13 AR ARP210103465A patent/AR124332A1/es unknown
- 2021-12-14 CN CN202180083934.4A patent/CN116615402A/zh active Pending
- 2021-12-14 EP EP21840349.1A patent/EP4263475A1/en active Pending
- 2021-12-14 JP JP2023536046A patent/JP2024500384A/ja active Pending
- 2021-12-14 CA CA3203759A patent/CA3203759A1/en active Pending
- 2021-12-14 US US18/252,930 patent/US20230416171A1/en active Pending
- 2021-12-14 WO PCT/US2021/063261 patent/WO2022132734A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2022132734A1 (en) | 2022-06-23 |
JP2024500384A (ja) | 2024-01-09 |
CA3203759A1 (en) | 2022-06-23 |
US20230416171A1 (en) | 2023-12-28 |
EP4263475A1 (en) | 2023-10-25 |
CN116615402A (zh) | 2023-08-18 |
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