BR112013025497B8 - Tinturas reativas com fibras, seu uso e seu processo de preparação, tinta aquosa, e processo para impressão de material de fibra têxtil, papel ou película plástica - Google Patents
Tinturas reativas com fibras, seu uso e seu processo de preparação, tinta aquosa, e processo para impressão de material de fibra têxtil, papel ou película plásticaInfo
- Publication number
- BR112013025497B8 BR112013025497B8 BR112013025497A BR112013025497A BR112013025497B8 BR 112013025497 B8 BR112013025497 B8 BR 112013025497B8 BR 112013025497 A BR112013025497 A BR 112013025497A BR 112013025497 A BR112013025497 A BR 112013025497A BR 112013025497 B8 BR112013025497 B8 BR 112013025497B8
- Authority
- BR
- Brazil
- Prior art keywords
- radical
- formula
- reactive dyes
- fibers
- hal
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title abstract 4
- 239000000985 reactive dye Substances 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000002657 fibrous material Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000002985 plastic film Substances 0.000 title 1
- 229920006255 plastic film Polymers 0.000 title 1
- 238000007639 printing Methods 0.000 title 1
- 230000008569 process Effects 0.000 title 1
- 239000004753 textile Substances 0.000 title 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 3
- 125000001424 substituent group Chemical group 0.000 abstract 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/24—Monoazo dyes prepared by diazotising and coupling from coupling components containing both hydroxyl and amino directing groups
- C09B29/28—Amino naphthols
- C09B29/30—Amino naphtholsulfonic acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
- C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
- C09B62/4411—Azo dyes
- C09B62/4415—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/465—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an acryloyl group, a quaternised or non-quaternised aminoalkyl carbonyl group or a (—N)n—CO—A—O—X or (—N)n—CO—A—Hal group, wherein A is an alkylene or alkylidene group, X is hydrogen or an acyl radical of an organic or inorganic acid, Hal is a halogen atom, and n is 0 or 1
- C09B62/47—Azo dyes
- C09B62/475—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/507—Azo dyes
- C09B62/51—Monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
- C09B62/507—Azo dyes
- C09B62/513—Disazo or polyazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Coloring (AREA)
- Paper (AREA)
Abstract
TINTURAS REATIVAS COM FIBRAS, SUA PREPARAÇÃO E SEU USO. A presente invenção refere-se à tinturas reativas de fórmula (1), em que R1 e R2 são cada qual independentemente um do outro hidrogênio ou C1-C4alquila substituída ou não substituída, um dos radicais D1 e D2 é um radical da fórmula (2), o outro dos radicais D1 e D2 é um radical da fórmula (3a), ou (3b), em que (R3)n significa substituintes idênticos ou diferentes de n selecionados do grupo C1-C4alquila, C1-C4alcóxi e sulfo, Z1 é um radical da fórmula -SO2-Y (4a), -CONH-(CH2)p-SO2-Y (4b), -NH-CO-CH(Hal)-CH2-Hal (4c), -NH-CO-C(Hal)=CH2 (4d), ou (4e), em que X1 é halogênio, T1, independentemente, tem a definição de X1, é um substituinte diferente de fibra reativa ou é um radical de fibra reativa da fórmula (5a), -NH-(CH2)2-3-SO2-Y (5b), ou -NH-(CH2)2-3-O-(CH2)2-3-SO2-Y (5c), R4 é hidrogênio ou C1-C4alquila substituída ou não substituída, (R5)0-2 indica de 0 a 2 substituintes idênticos ou diferentes do grupo C1-C4alquila, C1-C4alcóxi e sulfo, Hal é halogênio, Y é vinila ou um radical de -CH2-CH2-U e U é um grupo que é removível sob condições alcalinas, k é o número 0, 1 ou 2, m é o número 2, 3 ou 4, n é o número 0, 1 ou 2, e p é o número 2, 3 ou 4, são adequadas para tingimento de materiais contendo grupo amida ou celulósicos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11161503 | 2011-04-07 | ||
PCT/EP2012/053724 WO2012136428A1 (en) | 2011-04-07 | 2012-03-05 | Fibre-reactive dyes, their preparation and their use |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112013025497A2 BR112013025497A2 (pt) | 2016-12-27 |
BR112013025497B1 BR112013025497B1 (pt) | 2019-12-03 |
BR112013025497B8 true BR112013025497B8 (pt) | 2023-05-16 |
Family
ID=45787215
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112013025497A BR112013025497B8 (pt) | 2011-04-07 | 2012-03-05 | Tinturas reativas com fibras, seu uso e seu processo de preparação, tinta aquosa, e processo para impressão de material de fibra têxtil, papel ou película plástica |
Country Status (17)
Country | Link |
---|---|
US (1) | US20140026333A1 (pt) |
EP (1) | EP2694473B1 (pt) |
KR (1) | KR101966616B1 (pt) |
CN (1) | CN103443073B (pt) |
BR (1) | BR112013025497B8 (pt) |
CO (1) | CO6791624A2 (pt) |
DO (1) | DOP2013000227A (pt) |
ES (1) | ES2714684T3 (pt) |
MA (1) | MA35071B1 (pt) |
MX (1) | MX354037B (pt) |
MY (1) | MY169307A (pt) |
PE (1) | PE20140674A1 (pt) |
PT (1) | PT2694473T (pt) |
RU (1) | RU2596766C2 (pt) |
TR (1) | TR201903778T4 (pt) |
WO (1) | WO2012136428A1 (pt) |
ZA (1) | ZA201307112B (pt) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106833013A (zh) * | 2016-12-05 | 2017-06-13 | 泰兴锦云染料有限公司 | 一种活性深红染料及其制备和应用 |
CN106634038B (zh) * | 2016-12-05 | 2018-07-24 | 泰兴锦云染料有限公司 | 一种活性深蓝染料及其制备方法 |
WO2019158341A1 (en) | 2018-02-16 | 2019-08-22 | Huntsman Advanced Materials (Switzerland) Gmbh | Process for the simultaneous tanning and dyeing of collagen containing fibrous material |
WO2021219556A1 (en) | 2020-04-27 | 2021-11-04 | Huntsman Advanced Materials (Switzerland) Gmbh | Mixtures of reactive dyes and their use for the dyeing or printing of textile fibre materials |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3033611A1 (de) | 1980-09-06 | 1982-04-29 | Hoechst Ag, 6000 Frankfurt | Wasserloesliche disazoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
US4841049A (en) | 1986-09-12 | 1989-06-20 | Ciba-Geigy Corporation | Reactive dyes of the dioxazine series |
JPH0860017A (ja) | 1994-08-23 | 1996-03-05 | Sumitomo Chem Co Ltd | ビスアゾ化合物およびそれを用いて繊維材料を染色または捺染する方法 |
DE59906709D1 (de) * | 1998-07-27 | 2003-09-25 | Ciba Sc Holding Ag | Reaktivfarbstoffe, mischungen von reaktivfarbstoffen, deren herstellung und deren verwendung |
US6353094B1 (en) * | 1999-03-22 | 2002-03-05 | Ciba Specialty Chemicals Corporation | Dyes, a process for their preparation and their use |
ES2202029T3 (es) * | 1999-11-05 | 2004-04-01 | Ciba Specialty Chemicals Holding Inc. | Colorantes reactivos, procedimiento de obtencion y utilizacion de los mismos. |
GB0006029D0 (en) | 2000-03-14 | 2000-05-03 | Clariant Int Ltd | Organic compounds |
MXPA03009019A (es) * | 2001-04-20 | 2004-02-17 | Clariant Finance Bvi Ltd | Mono-azocolorantes reactivos de fibras. |
PL368380A1 (en) * | 2001-10-08 | 2005-03-21 | Clariant Finance (Bvi) Limited | Organic compounds |
MY158815A (en) | 2003-04-01 | 2016-11-15 | Ciba Specialty Chemicals Holding Inc | Mixture of reactive dyes and their use |
CN100335561C (zh) * | 2003-04-01 | 2007-09-05 | 西巴特殊化学品控股有限公司 | 活性染料混合物以及其应用 |
BRPI0508957B1 (pt) * | 2004-03-19 | 2015-08-11 | Huntsman Adv Mat Switzerland | Tintura reativa, seu uso e seu processo de preparação, tinta aquosa, e processo para imprimir material de fibra têxtil, papel ou filme plastico |
MY139986A (en) * | 2005-07-06 | 2009-11-30 | Ciba Sc Holding Ag | Mixtures of reactive dyes and their use |
CN101195715A (zh) | 2006-12-05 | 2008-06-11 | 明德国际仓储贸易(上海)有限公司 | 反应性红色染料组成物及其应用 |
-
2012
- 2012-03-05 CN CN201280017213.4A patent/CN103443073B/zh active Active
- 2012-03-05 KR KR1020137029419A patent/KR101966616B1/ko active IP Right Grant
- 2012-03-05 MY MYPI2013003125A patent/MY169307A/en unknown
- 2012-03-05 MX MX2013011478A patent/MX354037B/es active IP Right Grant
- 2012-03-05 PE PE2013002193A patent/PE20140674A1/es active IP Right Grant
- 2012-03-05 WO PCT/EP2012/053724 patent/WO2012136428A1/en active Application Filing
- 2012-03-05 ES ES12706857T patent/ES2714684T3/es active Active
- 2012-03-05 US US14/009,574 patent/US20140026333A1/en not_active Abandoned
- 2012-03-05 MA MA36379A patent/MA35071B1/fr unknown
- 2012-03-05 TR TR2019/03778T patent/TR201903778T4/tr unknown
- 2012-03-05 BR BR112013025497A patent/BR112013025497B8/pt active IP Right Grant
- 2012-03-05 RU RU2013149271/05A patent/RU2596766C2/ru active
- 2012-03-05 EP EP12706857.5A patent/EP2694473B1/en active Active
- 2012-03-05 PT PT12706857T patent/PT2694473T/pt unknown
-
2013
- 2013-09-17 CO CO13220555A patent/CO6791624A2/es active IP Right Grant
- 2013-09-20 ZA ZA2013/07112A patent/ZA201307112B/en unknown
- 2013-10-07 DO DO2013000227A patent/DOP2013000227A/es unknown
Also Published As
Publication number | Publication date |
---|---|
BR112013025497B1 (pt) | 2019-12-03 |
CN103443073B (zh) | 2016-09-28 |
RU2013149271A (ru) | 2015-05-20 |
ES2714684T3 (es) | 2019-05-29 |
MX2013011478A (es) | 2013-11-04 |
EP2694473A1 (en) | 2014-02-12 |
PE20140674A1 (es) | 2014-06-19 |
DOP2013000227A (es) | 2014-01-31 |
PT2694473T (pt) | 2019-04-23 |
ZA201307112B (en) | 2014-05-28 |
KR101966616B1 (ko) | 2019-04-09 |
RU2596766C2 (ru) | 2016-09-10 |
EP2694473B1 (en) | 2019-01-02 |
MY169307A (en) | 2019-03-21 |
KR20140020319A (ko) | 2014-02-18 |
CN103443073A (zh) | 2013-12-11 |
WO2012136428A1 (en) | 2012-10-11 |
US20140026333A1 (en) | 2014-01-30 |
MA35071B1 (fr) | 2014-04-03 |
CO6791624A2 (es) | 2013-11-14 |
MX354037B (es) | 2018-02-06 |
TR201903778T4 (tr) | 2019-04-22 |
BR112013025497A2 (pt) | 2016-12-27 |
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Legal Events
Date | Code | Title | Description |
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B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/03/2012, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/03/2012, OBSERVADAS AS CONDICOES LEGAIS |
|
B25A | Requested transfer of rights approved |
Owner name: HUNTSMAN TEXTILE EFFECTS (SWITZERLAND) GMBH (CH) |
|
B25D | Requested change of name of applicant approved |
Owner name: ARCHROMA (SWITZERLAND) GMBH (CH) |
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B25G | Requested change of headquarter approved |
Owner name: ARCHROMA (SWITZERLAND) GMBH (CH) |