BR112012031613A2 - método de desidratação e de isomerização de álcoois em c4, utilizando um sólido amorfo com porosidade adaptada - Google Patents
método de desidratação e de isomerização de álcoois em c4, utilizando um sólido amorfo com porosidade adaptadaInfo
- Publication number
- BR112012031613A2 BR112012031613A2 BR112012031613A BR112012031613A BR112012031613A2 BR 112012031613 A2 BR112012031613 A2 BR 112012031613A2 BR 112012031613 A BR112012031613 A BR 112012031613A BR 112012031613 A BR112012031613 A BR 112012031613A BR 112012031613 A2 BR112012031613 A2 BR 112012031613A2
- Authority
- BR
- Brazil
- Prior art keywords
- dehydration
- isomerization
- alcohols
- amorphous solid
- porosity
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
- C07C11/09—Isobutene
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2772—Catalytic processes with metal oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
- C07C2523/22—Vanadium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
método de desidratação e de isomerização de álcoois em c4,utilizando um sólido amorfo com porosidade adaptada.a presente invenção refere-se a um método de produção de olefinas em c4, a patir de uma carga de monoálcool em c4, no qual se realiza uma reação de desidratação do monoálcool em pelo menos uma olefina, e uma reação de isomerização estrutural de pelo menos uma das olefinas produzidas em um mesmo compartimento reacional, em presença de um catalisador á base de alumina com porosidade adaptada.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10/02.469 | 2010-06-11 | ||
| FR1002469A FR2961202B1 (fr) | 2010-06-11 | 2010-06-11 | Procede de deshydratation et d'isomerisation d'alcools en c4 utilisant un solide amorphe a porosite adaptee |
| PCT/FR2011/000316 WO2011154621A1 (fr) | 2010-06-11 | 2011-05-27 | Procédé de déshydratation et d'isomérisation d'alcools en c4 utilisant un solide amorphe à porosité adaptée |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012031613A2 true BR112012031613A2 (pt) | 2016-11-08 |
| BR112012031613B1 BR112012031613B1 (pt) | 2018-07-10 |
Family
ID=43478146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012031613-3A BR112012031613B1 (pt) | 2010-06-11 | 2011-05-27 | Método de desidratação e de isomerização de álcoois em c4, utilizando um sólido amorfo com porosidade adaptada |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9132414B2 (pt) |
| EP (1) | EP2580178B1 (pt) |
| CN (1) | CN102906055B (pt) |
| BR (1) | BR112012031613B1 (pt) |
| CA (1) | CA2797748C (pt) |
| FR (1) | FR2961202B1 (pt) |
| PL (1) | PL2580178T3 (pt) |
| RU (1) | RU2563632C2 (pt) |
| UA (1) | UA109280C2 (pt) |
| WO (1) | WO2011154621A1 (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2988717B1 (fr) * | 2012-03-29 | 2014-04-11 | IFP Energies Nouvelles | Procede de deshydratation et d'isomerisation d'alcools utilisant un catalyseur a base d'un materiau mesostructure comprenant du silicium |
| FR2988718B1 (fr) * | 2012-03-29 | 2014-04-11 | Ifp Energies Now | Procede de deshydratation et d'isomerisation d'alcools utilisant un solide de type aluminosilicate non zeolithique |
| EP3071538B1 (en) * | 2013-11-20 | 2021-02-17 | Lummus Technology LLC | Olefin double bond isomerization catalyst with high poison resistance |
| FR3040703B1 (fr) * | 2015-09-03 | 2017-10-06 | Ifp Energies Now | Procede integre de production de butadiene a partir de butanol |
| FR3058413A1 (fr) * | 2016-11-08 | 2018-05-11 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin |
| FR3058414B1 (fr) | 2016-11-08 | 2019-08-16 | IFP Energies Nouvelles | Procede de deshydratation isomerisante d'un alcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un liant aluminique |
| FR3084267B1 (fr) * | 2018-07-25 | 2021-10-08 | Axens | Alumine a acidite et structure de porosite optimales |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2499675A (en) * | 1945-12-13 | 1950-03-07 | Phillips Petroleum Co | Preparation of pelleted alumina catalyst |
| SU429050A1 (ru) * | 1971-12-17 | 1974-05-25 | Способ получения бутадиена | |
| FR2484400A1 (fr) * | 1980-05-13 | 1981-12-18 | Inst Francais Du Petrole | Procede d'isomerisation d'olefines |
| US4404417A (en) * | 1981-07-24 | 1983-09-13 | Polysar International S.A. | Isomerization |
| FR2527197B1 (fr) * | 1982-05-19 | 1985-06-21 | Rhone Poulenc Spec Chim | Procede de fabrication de billes d'alumine mises en forme par coagulation en gouttes |
| FR2634218B1 (fr) | 1988-07-13 | 1992-02-21 | Inst Francais Du Petrole | Procede de production de butanol et d'acetone par fermentation a partir de melasse de canne a sucre |
| SU1683811A1 (ru) * | 1989-06-28 | 1991-10-15 | Институт катализа СО АН СССР | Катализатор дл изомеризации бутена и дегидратации изобутилового спирта |
| FR2714051B1 (fr) | 1993-12-22 | 1996-02-02 | Inst Francais Du Petrole | Procédé d'isomérisation squelettale des oléfines utilisant une matière à base d'alumine. |
| EP2235193B1 (en) | 2007-12-23 | 2015-11-25 | GEVO, Inc. | Yeast organism producing isobutanol at a high yield |
-
2010
- 2010-06-11 FR FR1002469A patent/FR2961202B1/fr active Active
-
2011
- 2011-05-27 RU RU2013100971/04A patent/RU2563632C2/ru active
- 2011-05-27 CN CN201180027162.9A patent/CN102906055B/zh active Active
- 2011-05-27 US US13/703,107 patent/US9132414B2/en active Active
- 2011-05-27 CA CA2797748A patent/CA2797748C/fr active Active
- 2011-05-27 BR BR112012031613-3A patent/BR112012031613B1/pt active IP Right Grant
- 2011-05-27 PL PL11728642T patent/PL2580178T3/pl unknown
- 2011-05-27 UA UAA201300353A patent/UA109280C2/ru unknown
- 2011-05-27 WO PCT/FR2011/000316 patent/WO2011154621A1/fr active Application Filing
- 2011-05-27 EP EP11728642.7A patent/EP2580178B1/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2797748C (fr) | 2018-05-08 |
| FR2961202A1 (fr) | 2011-12-16 |
| EP2580178A1 (fr) | 2013-04-17 |
| RU2013100971A (ru) | 2014-07-20 |
| RU2563632C2 (ru) | 2015-09-20 |
| US9132414B2 (en) | 2015-09-15 |
| FR2961202B1 (fr) | 2012-07-27 |
| CA2797748A1 (fr) | 2011-12-15 |
| PL2580178T3 (pl) | 2015-04-30 |
| UA109280C2 (uk) | 2015-08-10 |
| BR112012031613B1 (pt) | 2018-07-10 |
| US20130137908A1 (en) | 2013-05-30 |
| CN102906055B (zh) | 2015-08-19 |
| WO2011154621A1 (fr) | 2011-12-15 |
| EP2580178B1 (fr) | 2014-09-03 |
| CN102906055A (zh) | 2013-01-30 |
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| IN2015DN03035A (pt) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B15I | Others concerning applications: loss of priority | ||
| B12F | Other appeals [chapter 12.6 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |