BR112012021913A2 - método para produção de gás de síntese - Google Patents
método para produção de gás de sínteseInfo
- Publication number
- BR112012021913A2 BR112012021913A2 BR112012021913A BR112012021913A BR112012021913A2 BR 112012021913 A2 BR112012021913 A2 BR 112012021913A2 BR 112012021913 A BR112012021913 A BR 112012021913A BR 112012021913 A BR112012021913 A BR 112012021913A BR 112012021913 A2 BR112012021913 A2 BR 112012021913A2
- Authority
- BR
- Brazil
- Prior art keywords
- sulfur
- carbon dioxide
- synthesis gas
- reformer
- sulfur compounds
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 8
- 150000003464 sulfur compounds Chemical class 0.000 abstract 5
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- 239000001569 carbon dioxide Substances 0.000 abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 238000006477 desulfuration reaction Methods 0.000 abstract 2
- 230000023556 desulfurization Effects 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 231100000572 poisoning Toxicity 0.000 abstract 1
- 230000000607 poisoning effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000002407 reforming Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1025—Natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/06—Gasoil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/08—Jet fuel
Abstract
método para produção de gás de síntese. é evitado que os compostos de enxofre provenientes do revestimento sejam misturados no gás de síntese produzido, os compostos de enxofre misturados são separados e recolhidos com dióxido de carbono, o dióxido de carbono recolhido é reciclado como gás de matéria-prima e então os compostos de enxofre são diretamente fornecidos para o reformador para posteriormente degradarem o catalisador de reforma no reformador através de envenenamento por enxofre. o dióxido de carbono separado e recolhido na etapa de remoção de dióxido de carbono é introduzido no aparelho de dessulfurização da etapa de dessulfarização ou no aparelho de adsorção dos compostos de enxofre antes de ser rciclado para o reformador para a remoção dos compostos de enxofre.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010-045697 | 2010-03-02 | ||
JP2010045697 | 2010-03-02 | ||
JP2010-045699 | 2010-03-02 | ||
JP2010045699 | 2010-03-02 | ||
PCT/JP2011/000934 WO2011108212A1 (ja) | 2010-03-02 | 2011-02-21 | 合成ガスの製造方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112012021913A2 true BR112012021913A2 (pt) | 2016-05-24 |
BR112012021913B1 BR112012021913B1 (pt) | 2020-12-29 |
BR112012021913B8 BR112012021913B8 (pt) | 2021-10-19 |
Family
ID=44541882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012021913A BR112012021913B8 (pt) | 2010-03-02 | 2011-02-21 | método para produção de gás de síntese |
Country Status (11)
Country | Link |
---|---|
US (1) | US9056772B2 (pt) |
EP (1) | EP2543626B1 (pt) |
JP (1) | JP5638600B2 (pt) |
CN (1) | CN102781819A (pt) |
AU (1) | AU2011222347B2 (pt) |
BR (1) | BR112012021913B8 (pt) |
CA (1) | CA2791860C (pt) |
EA (1) | EA019982B1 (pt) |
MY (1) | MY161732A (pt) |
WO (1) | WO2011108212A1 (pt) |
ZA (1) | ZA201206246B (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5906074B2 (ja) | 2011-12-08 | 2016-04-20 | 川崎重工業株式会社 | 水素製造システム |
KR101277123B1 (ko) * | 2012-09-07 | 2013-06-20 | 한국기초과학지원연구원 | 플라즈마 건식 개질장치 |
EP3032027B1 (en) * | 2013-08-06 | 2019-10-09 | Chiyoda Corporation | Hydrogen supply system and hydrogen supply method |
KR101487100B1 (ko) * | 2013-09-30 | 2015-01-27 | 전북대학교산학협력단 | 합성가스 제조방법 및 이의 제조를 위해 이중 유동층 이산화탄소 가스화 장치 |
AU2015336109B2 (en) * | 2014-10-24 | 2020-11-19 | Research Triangle Institute | Integrated system and method for removing acid gas from a gas stream |
FR3085370B1 (fr) | 2018-08-28 | 2020-09-04 | Europlasma | Procede de production d'un gaz de synthese par traitement d'un flux gazeux contenant du co2 et un ou plusieurs hydrocarbures |
CN110589765A (zh) * | 2019-10-09 | 2019-12-20 | 中石化南京工程有限公司 | 一种利用天然气制备不同比例合成气的方法及系统 |
EP4323085A1 (en) * | 2021-04-13 | 2024-02-21 | Infinium Technology, LLC | Process for purification and conversion of carbon dioxide using renewable energy |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3593356B2 (ja) * | 1993-12-28 | 2004-11-24 | 三菱化工機株式会社 | 都市ガスの製造方法 |
JPH07197058A (ja) * | 1993-12-30 | 1995-08-01 | Tonen Corp | 潤滑油組成物 |
GB9817526D0 (en) | 1998-08-13 | 1998-10-07 | Ici Plc | Steam reforming |
JP2000169411A (ja) * | 1998-12-08 | 2000-06-20 | Jgc Corp | ジメチルエーテルの製造装置及びその方法 |
JP4533515B2 (ja) * | 2000-08-16 | 2010-09-01 | 三菱重工業株式会社 | 合成ガスの製造方法 |
US7168265B2 (en) * | 2003-03-27 | 2007-01-30 | Bp Corporation North America Inc. | Integrated processing of natural gas into liquid products |
US20060106119A1 (en) * | 2004-01-12 | 2006-05-18 | Chang-Jie Guo | Novel integration for CO and H2 recovery in gas to liquid processes |
HUE033751T2 (en) * | 2005-06-06 | 2017-12-28 | L'air Liquide Sa Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for simultaneous production of hydrogen and carbon monoxide |
JP4653138B2 (ja) * | 2007-04-16 | 2011-03-16 | アイシン精機株式会社 | 燃料電池システム |
JP5424566B2 (ja) | 2008-03-14 | 2014-02-26 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 天然ガスからの液状炭化水素製造プロセスにおける合成ガスの製造方法 |
JP2010045697A (ja) | 2008-08-18 | 2010-02-25 | Nec Infrontia Corp | 通報装置内保存データ収集システムにおける通報装置、および通報装置内保存データ収集方法 |
JP4548529B2 (ja) | 2008-08-18 | 2010-09-22 | ソニー株式会社 | 情報記録装置、撮像装置、情報記録方法およびプログラム |
-
2011
- 2011-02-21 WO PCT/JP2011/000934 patent/WO2011108212A1/ja active Application Filing
- 2011-02-21 AU AU2011222347A patent/AU2011222347B2/en active Active
- 2011-02-21 EA EA201290737A patent/EA019982B1/ru not_active IP Right Cessation
- 2011-02-21 EP EP11750326.8A patent/EP2543626B1/en active Active
- 2011-02-21 CA CA2791860A patent/CA2791860C/en active Active
- 2011-02-21 BR BR112012021913A patent/BR112012021913B8/pt active IP Right Grant
- 2011-02-21 JP JP2012502990A patent/JP5638600B2/ja active Active
- 2011-02-21 US US13/581,026 patent/US9056772B2/en active Active
- 2011-02-21 CN CN2011800116619A patent/CN102781819A/zh active Pending
- 2011-02-21 MY MYPI2012003878A patent/MY161732A/en unknown
-
2012
- 2012-08-20 ZA ZA2012/06246A patent/ZA201206246B/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU2011222347B2 (en) | 2014-04-10 |
ZA201206246B (en) | 2013-05-29 |
BR112012021913B8 (pt) | 2021-10-19 |
AU2011222347A1 (en) | 2012-09-20 |
MY161732A (en) | 2017-05-15 |
US20120316252A1 (en) | 2012-12-13 |
CN102781819A (zh) | 2012-11-14 |
EP2543626A1 (en) | 2013-01-09 |
EA201290737A1 (ru) | 2013-02-28 |
EP2543626B1 (en) | 2018-05-30 |
WO2011108212A1 (ja) | 2011-09-09 |
JPWO2011108212A1 (ja) | 2013-06-20 |
CA2791860A1 (en) | 2011-09-09 |
BR112012021913B1 (pt) | 2020-12-29 |
EP2543626A4 (en) | 2013-11-06 |
US9056772B2 (en) | 2015-06-16 |
EA019982B1 (ru) | 2014-07-30 |
CA2791860C (en) | 2015-10-27 |
JP5638600B2 (ja) | 2014-12-10 |
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