BR0315769B1 - método de separação de ìons multivalentes e ìons de lactato de um caldo de fermentação compreendendo um sal de lactato de ìon multivalente pela utilização de um aparelho de eletrodiálise ou eletrólise. - Google Patents
método de separação de ìons multivalentes e ìons de lactato de um caldo de fermentação compreendendo um sal de lactato de ìon multivalente pela utilização de um aparelho de eletrodiálise ou eletrólise. Download PDFInfo
- Publication number
- BR0315769B1 BR0315769B1 BRPI0315769-5A BR0315769A BR0315769B1 BR 0315769 B1 BR0315769 B1 BR 0315769B1 BR 0315769 A BR0315769 A BR 0315769A BR 0315769 B1 BR0315769 B1 BR 0315769B1
- Authority
- BR
- Brazil
- Prior art keywords
- selective
- multivalent
- ion
- lactate
- ions
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 46
- 150000002500 ions Chemical class 0.000 title claims description 43
- 238000000909 electrodialysis Methods 0.000 title claims description 40
- -1 lactate ions Chemical class 0.000 title claims description 34
- 238000005868 electrolysis reaction Methods 0.000 title claims description 23
- 238000000855 fermentation Methods 0.000 title claims description 22
- 230000004151 fermentation Effects 0.000 title claims description 22
- 239000012528 membrane Substances 0.000 claims description 75
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 49
- 150000001450 anions Chemical class 0.000 claims description 35
- 239000004310 lactic acid Substances 0.000 claims description 22
- 235000014655 lactic acid Nutrition 0.000 claims description 22
- 150000001768 cations Chemical class 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 229940001447 lactate Drugs 0.000 description 12
- 206010061876 Obstruction Diseases 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 4
- 239000000920 calcium hydroxide Substances 0.000 description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 235000011088 sodium lactate Nutrition 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 3
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 3
- 239000001527 calcium lactate Substances 0.000 description 3
- 235000011086 calcium lactate Nutrition 0.000 description 3
- 229960002401 calcium lactate Drugs 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000001540 sodium lactate Substances 0.000 description 3
- 229940005581 sodium lactate Drugs 0.000 description 3
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- RZOBLYBZQXQGFY-UHFFFAOYSA-N ammonium lactate Chemical class [NH4+].CC(O)C([O-])=O RZOBLYBZQXQGFY-UHFFFAOYSA-N 0.000 description 2
- 235000019286 ammonium lactate Nutrition 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 235000011085 potassium lactate Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004251 Ammonium lactate Substances 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229940059265 ammonium lactate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- UTBZLHWSBYWAOP-UHFFFAOYSA-N azane;2-hydroxypropanoic acid;sodium Chemical compound N.[Na].CC(O)C(O)=O UTBZLHWSBYWAOP-UHFFFAOYSA-N 0.000 description 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000009285 membrane fouling Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000001521 potassium lactate Substances 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/56—Lactic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M47/00—Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
- C12M47/10—Separation or concentration of fermentation products
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/005—Combined electrochemical biological processes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Biotechnology (AREA)
- Water Supply & Treatment (AREA)
- Wood Science & Technology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Urology & Nephrology (AREA)
- Microbiology (AREA)
- Genetics & Genomics (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Sustainable Development (AREA)
- General Chemical & Material Sciences (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02079493.9 | 2002-10-28 | ||
| EP20020079493 EP1415702A1 (en) | 2002-10-28 | 2002-10-28 | Method of separating multivalent ions and lactate ions from a fermentation broth |
| PCT/EP2003/050759 WO2004037397A1 (en) | 2002-10-28 | 2003-10-27 | Method of separating multivalent ions and lactate ions from a fermentation broth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0315769A BR0315769A (pt) | 2005-09-06 |
| BR0315769B1 true BR0315769B1 (pt) | 2012-01-10 |
Family
ID=32088038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0315769-5A BR0315769B1 (pt) | 2002-10-28 | 2003-10-27 | método de separação de ìons multivalentes e ìons de lactato de um caldo de fermentação compreendendo um sal de lactato de ìon multivalente pela utilização de um aparelho de eletrodiálise ou eletrólise. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7217349B2 (enExample) |
| EP (2) | EP1415702A1 (enExample) |
| JP (1) | JP2006503571A (enExample) |
| CN (1) | CN100594967C (enExample) |
| AU (1) | AU2003301648A1 (enExample) |
| BR (1) | BR0315769B1 (enExample) |
| WO (1) | WO2004037397A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1632568A1 (en) * | 2004-09-03 | 2006-03-08 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO | Process and apparatus for the production and separation of fermentation products |
| EP2522631A1 (en) * | 2011-05-12 | 2012-11-14 | Rohm and Haas Company | Method for the separation of monovalent metals from multivalent metals |
| CN103160853A (zh) * | 2011-12-12 | 2013-06-19 | 中国科学院过程工程研究所 | 一种用氨基功能化离子液体电解液电解铝的方法 |
| ES2564549T3 (es) * | 2012-01-30 | 2016-03-23 | Universiteit Gent | Procedimientos electroquímicos para separar productos procedentes de conversiones biológicas |
| NZ743055A (en) * | 2013-03-08 | 2020-03-27 | Xyleco Inc | Equipment protecting enclosures |
| CN105566094A (zh) * | 2016-01-20 | 2016-05-11 | 奥为（天津）环保科技有限公司 | 生物质固废厌氧发酵-电渗析法制取短链羧酸盐 |
| AU2022237620A1 (en) | 2021-03-17 | 2023-09-28 | Electrasteel, Inc. | Carbon capture using electrochemically-produced acid and base |
| CN113461154B (zh) * | 2021-08-03 | 2024-12-13 | 同济大学 | 一种从厌氧消化液中在线选择性分离有机酸的装置 |
| CN119638094A (zh) * | 2023-09-18 | 2025-03-18 | 中国石油天然气股份有限公司 | 一种戊醛缩合废碱液的处理方法及处理系统 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62146595A (ja) * | 1985-12-20 | 1987-06-30 | Daicel Chem Ind Ltd | 醗酵による有機酸の連続製造方法 |
| JPH02286090A (ja) * | 1989-04-18 | 1990-11-26 | Michigan Biotechnol Inst | 乳酸の生産および精製方法 |
| US5746920A (en) * | 1994-06-08 | 1998-05-05 | Fraunhofer-Gesellschaft Zur Foerder Der Angewandten Forschung E.V. | Process for purifying dairy wastewater |
| US5681728A (en) * | 1995-06-07 | 1997-10-28 | Chronopol, Inc. | Method and apparatus for the recovery and purification of organic acids |
| CA2227398A1 (en) * | 1997-01-23 | 1998-07-23 | K.N. Mani | Apparatus and process for electrodialysis of salts |
| US6294066B1 (en) * | 1997-01-23 | 2001-09-25 | Archer Daniels Midland Company | Apparatus and process for electrodialysis of salts |
| US6331236B1 (en) * | 1998-07-21 | 2001-12-18 | Archer Daniels Midland Company | Electrodialysis of salts for producing acids and bases |
| US6495013B2 (en) * | 2000-07-13 | 2002-12-17 | The Electrosynthesis Company, Inc. | Bipolar membrane electrodialysis of multivalent metal salts whose corresponding base is insoluble |
-
2002
- 2002-10-28 EP EP20020079493 patent/EP1415702A1/en not_active Withdrawn
-
2003
- 2003-10-27 CN CN200380102251A patent/CN100594967C/zh not_active Expired - Lifetime
- 2003-10-27 JP JP2004546052A patent/JP2006503571A/ja active Pending
- 2003-10-27 AU AU2003301648A patent/AU2003301648A1/en not_active Abandoned
- 2003-10-27 EP EP03809353A patent/EP1558369A1/en not_active Ceased
- 2003-10-27 BR BRPI0315769-5A patent/BR0315769B1/pt active IP Right Grant
- 2003-10-27 WO PCT/EP2003/050759 patent/WO2004037397A1/en not_active Ceased
- 2003-10-28 US US10/693,922 patent/US7217349B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1415702A1 (en) | 2004-05-06 |
| CN100594967C (zh) | 2010-03-24 |
| JP2006503571A (ja) | 2006-02-02 |
| US7217349B2 (en) | 2007-05-15 |
| AU2003301648A1 (en) | 2004-05-13 |
| WO2004037397A1 (en) | 2004-05-06 |
| US20040137587A1 (en) | 2004-07-15 |
| EP1558369A1 (en) | 2005-08-03 |
| BR0315769A (pt) | 2005-09-06 |
| CN1708347A (zh) | 2005-12-14 |
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