BR0114931A - Processo para a preparação de álcool 4-metil-2,3,5,6-tetra-fluorobenzìlico, e, composto - Google Patents
Processo para a preparação de álcool 4-metil-2,3,5,6-tetra-fluorobenzìlico, e, compostoInfo
- Publication number
- BR0114931A BR0114931A BR0114931-8A BR0114931A BR0114931A BR 0114931 A BR0114931 A BR 0114931A BR 0114931 A BR0114931 A BR 0114931A BR 0114931 A BR0114931 A BR 0114931A
- Authority
- BR
- Brazil
- Prior art keywords
- methyl
- preparation
- compound
- tetrafluorobenzyl alcohol
- alcohol
- Prior art date
Links
- PJCSTULKVNHEGW-UHFFFAOYSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methanol Chemical compound CC1=C(F)C(F)=C(CO)C(F)=C1F PJCSTULKVNHEGW-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 2
- AYCZMWCDBIZDAD-UHFFFAOYSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methanamine Chemical compound CC1=C(F)C(F)=C(CN)C(F)=C1F AYCZMWCDBIZDAD-UHFFFAOYSA-N 0.000 abstract 3
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical group FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 abstract 1
- NUSQQHOHSBCDQX-UHFFFAOYSA-N 2,3,5,6-tetrafluoro-4-methylbenzonitrile Chemical compound CC1=C(F)C(F)=C(C#N)C(F)=C1F NUSQQHOHSBCDQX-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/26—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring
- C07C211/29—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
"PROCESSO PARA A PREPARAçãO DE áLCOOL 4-METIL-2,3,5,6-TETRA-FLUOROBENZìLICO, E, COMPOSTO". Um processo para a preparação do álcool 4-metil-2,3,5,6-tetrafluorobenzílico que compreende hidrogenar a 4-metil-2,3,5,6-tetrafluorobenzonitrila a 4-metil-2,3,5,6-tetrafluorobenzilamina e converter a 4-metil2,3,5,6-tetrafluorobenzilamina ao álcool 4-metil-2,3,5,6-tetrafluoro-benzílico. O processo, opcionalmente, também compreende a outra etapa de reagir o álcool 4-Metil-2,3,5,6-tetrafluorobenzílico com o cloreto de cis-Z-3-(2-cloro-1,1,1-trifluoro-2-propenil)-2,2-dimetilciclopropanocar bonila à forma teflutrina. A 4-metil-2,3,5,6-tetrafluorobenzilamina e seus sais também são reivindicados.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0026348.3A GB0026348D0 (en) | 2000-10-27 | 2000-10-27 | Chemical process |
PCT/GB2001/004692 WO2002034707A1 (en) | 2000-10-27 | 2001-10-18 | Preparation of 4-methyl-2,3,5,6-tetrafluorobenzyl alcohol |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0114931A true BR0114931A (pt) | 2004-01-06 |
BR0114931B1 BR0114931B1 (pt) | 2012-03-20 |
Family
ID=9902107
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0114931-8A BR0114931B1 (pt) | 2000-10-27 | 2001-10-18 | processo para a preparação de álcool 4-metil-2,3,5,6-tetra-fluorobenzìlico, e, composto |
Country Status (14)
Country | Link |
---|---|
US (1) | US6894195B2 (pt) |
EP (1) | EP1332125B1 (pt) |
JP (1) | JP3984913B2 (pt) |
KR (1) | KR100788927B1 (pt) |
CN (1) | CN1213992C (pt) |
AT (1) | ATE277885T1 (pt) |
AU (1) | AU2002210695A1 (pt) |
BR (1) | BR0114931B1 (pt) |
DE (1) | DE60106073T2 (pt) |
GB (1) | GB0026348D0 (pt) |
HU (1) | HU228240B1 (pt) |
IL (2) | IL155200A0 (pt) |
TW (1) | TWI229065B (pt) |
WO (1) | WO2002034707A1 (pt) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7939695B2 (en) | 2005-06-22 | 2011-05-10 | Showa Denko K.K. | Production process of nucleus-halogenated methylbenzyl alcohol |
EP2471766B1 (en) * | 2007-02-16 | 2013-09-04 | Sumitomo Chemical Company, Limited | Process for producing 4-methyl-2,3,5,6-tetrafluorobenzyl alcohol |
CN102617279B (zh) * | 2012-03-31 | 2014-06-11 | 浙江工业大学 | 一种由胺类化合物制备醇类化合物的方法 |
AU2017203635B2 (en) * | 2017-05-30 | 2022-02-03 | Rotam Agrochem International Company Limited | A novel crystalline form of tefluthrin, a process for its preparation and use of the same |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3406024A (en) * | 1965-08-27 | 1968-10-15 | Velsicol Chemical Corp | Method for the control of weeds |
EP0031199B1 (en) * | 1979-12-21 | 1983-12-14 | Imperial Chemical Industries Plc | Substituted benzyl esters of cyclopropane carboxylic acids and their preparation, compositions containing them and methods of combating insect pests therewith, and substituted benzyl alcohols |
GB2123823B (en) | 1982-07-21 | 1985-12-04 | Ici Plc | 4-methyl-2 3 5 6-tetrafluorobenzaldiacetate and a process for its preparation |
GB2123824B (en) | 1982-07-21 | 1986-07-30 | Ici Plc | 4-methyl-2 3 5 6-tetrafluorobenzyl acetate and a process for its preparation |
GB2127013B (en) * | 1982-09-17 | 1985-12-11 | Ici Plc | Tetrafluoroterephthalyl alcohol esters thereof and a process for their preparation |
DE3714602A1 (de) | 1987-05-01 | 1988-11-10 | Bayer Ag | Verfahren zur herstellung von 2,3,5,6-tetrafluor-benzyl-alkoholen |
JP3701032B2 (ja) * | 1996-08-29 | 2005-09-28 | 昭和電工株式会社 | ベンゾニトリル及びベンジルアルコールの製造方法 |
JP2000086583A (ja) * | 1998-09-17 | 2000-03-28 | Asahi Glass Co Ltd | 含フッ素ベンジル誘導体の製造方法 |
JP2001294560A (ja) * | 2000-04-13 | 2001-10-23 | Central Glass Co Ltd | トリフルオロメチルベンジルアミン類の製造方法 |
JP2003089679A (ja) * | 2001-09-17 | 2003-03-28 | Nippon Shokubai Co Ltd | 含フッ素アミン化合物 |
JP2003089664A (ja) * | 2001-09-17 | 2003-03-28 | Nippon Shokubai Co Ltd | 含フッ素パラシクロファンの製法 |
-
2000
- 2000-10-27 GB GBGB0026348.3A patent/GB0026348D0/en not_active Ceased
-
2001
- 2001-10-18 KR KR1020037005664A patent/KR100788927B1/ko not_active IP Right Cessation
- 2001-10-18 HU HU0301158A patent/HU228240B1/hu not_active IP Right Cessation
- 2001-10-18 BR BRPI0114931-8A patent/BR0114931B1/pt not_active IP Right Cessation
- 2001-10-18 IL IL15520001A patent/IL155200A0/xx unknown
- 2001-10-18 JP JP2002537701A patent/JP3984913B2/ja not_active Expired - Fee Related
- 2001-10-18 DE DE60106073T patent/DE60106073T2/de not_active Expired - Lifetime
- 2001-10-18 US US10/415,262 patent/US6894195B2/en not_active Expired - Fee Related
- 2001-10-18 CN CNB018180205A patent/CN1213992C/zh not_active Expired - Fee Related
- 2001-10-18 AT AT01978595T patent/ATE277885T1/de not_active IP Right Cessation
- 2001-10-18 EP EP01978595A patent/EP1332125B1/en not_active Expired - Lifetime
- 2001-10-18 AU AU2002210695A patent/AU2002210695A1/en not_active Abandoned
- 2001-10-18 WO PCT/GB2001/004692 patent/WO2002034707A1/en active IP Right Grant
- 2001-10-22 TW TW090126037A patent/TWI229065B/zh not_active IP Right Cessation
-
2003
- 2003-04-02 IL IL155200A patent/IL155200A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
GB0026348D0 (en) | 2000-12-13 |
US20040063993A1 (en) | 2004-04-01 |
US6894195B2 (en) | 2005-05-17 |
EP1332125A1 (en) | 2003-08-06 |
CN1213992C (zh) | 2005-08-10 |
CN1494525A (zh) | 2004-05-05 |
IL155200A0 (en) | 2003-11-23 |
JP2004512320A (ja) | 2004-04-22 |
DE60106073D1 (de) | 2004-11-04 |
TWI229065B (en) | 2005-03-11 |
WO2002034707A1 (en) | 2002-05-02 |
DE60106073T2 (de) | 2006-03-09 |
EP1332125B1 (en) | 2004-09-29 |
HU228240B1 (hu) | 2013-02-28 |
KR20030044032A (ko) | 2003-06-02 |
IL155200A (en) | 2010-04-15 |
HUP0301158A2 (en) | 2007-03-28 |
JP3984913B2 (ja) | 2007-10-03 |
BR0114931B1 (pt) | 2012-03-20 |
ATE277885T1 (de) | 2004-10-15 |
HUP0301158A3 (en) | 2007-06-28 |
AU2002210695A1 (en) | 2002-05-06 |
KR100788927B1 (ko) | 2007-12-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25G | Requested change of headquarter approved | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 20/03/2012, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |