WO2002070441A1 - Procede de preparation de cyclohexenes optiquement actifs et derives de cyclohexenes optiquement actifs a utiliser dans la preparation - Google Patents

Procede de preparation de cyclohexenes optiquement actifs et derives de cyclohexenes optiquement actifs a utiliser dans la preparation Download PDF

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Publication number
WO2002070441A1
WO2002070441A1 PCT/JP2002/001907 JP0201907W WO02070441A1 WO 2002070441 A1 WO2002070441 A1 WO 2002070441A1 JP 0201907 W JP0201907 W JP 0201907W WO 02070441 A1 WO02070441 A1 WO 02070441A1
Authority
WO
WIPO (PCT)
Prior art keywords
optically active
preparation
cyclohexenes
cyclohexene derivatives
cyclohexene
Prior art date
Application number
PCT/JP2002/001907
Other languages
English (en)
Japanese (ja)
Inventor
Fumie Sato
Sentaro Okamoto
Original Assignee
Nissan Chemical Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Industries, Ltd. filed Critical Nissan Chemical Industries, Ltd.
Publication of WO2002070441A1 publication Critical patent/WO2002070441A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/32—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by aldehydo- or ketonic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

L'invention concerne des composés optiquement actifs de cyclohexène, de cyclohexanone et d'oxyde de cyclohexène, représentés par la formule générale (1) à (4), dans laquelle R représente hydrogène ou CH2R2 (où R2 représente hydrogène ou alkyle en C1-C4 linéaire ou ramifié et éventuellement fluoré) et X représente un groupe protecteur hydroxyle.
PCT/JP2002/001907 2001-03-02 2002-03-01 Procede de preparation de cyclohexenes optiquement actifs et derives de cyclohexenes optiquement actifs a utiliser dans la preparation WO2002070441A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001-058102 2001-03-02
JP2001058102A JP4811547B2 (ja) 2000-10-24 2001-03-02 光学活性シクロヘキセン化合物の製造法及びこの製造に用いる光学活性シクロヘキセン誘導体

Publications (1)

Publication Number Publication Date
WO2002070441A1 true WO2002070441A1 (fr) 2002-09-12

Family

ID=18917882

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/001907 WO2002070441A1 (fr) 2001-03-02 2002-03-01 Procede de preparation de cyclohexenes optiquement actifs et derives de cyclohexenes optiquement actifs a utiliser dans la preparation

Country Status (2)

Country Link
JP (1) JP4811547B2 (fr)
WO (1) WO2002070441A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5417597B2 (ja) * 2006-10-25 2014-02-19 国立大学法人 千葉大学 ベンゼン誘導体の製造方法及びそれに有用なシクロヘキセン誘導体の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE929369C (de) * 1952-09-11 1955-06-27 Leo Pharm Prod Ltd Verfahren zur Herstellung von in 4-Stellung veraetherten oder veresterten 1-Methyl-cyclohexen-A1(6)-onen-(2)
EP0516410A2 (fr) * 1991-05-28 1992-12-02 Wisconsin Alumni Research Foundation Nouveau procédé pour la préparation des composés 19-nor vitamine D
EP1078931A2 (fr) * 1999-08-23 2001-02-28 F. Hoffmann-La Roche Ag Procédé de préparation d'analogues de vitamine D

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE929369C (de) * 1952-09-11 1955-06-27 Leo Pharm Prod Ltd Verfahren zur Herstellung von in 4-Stellung veraetherten oder veresterten 1-Methyl-cyclohexen-A1(6)-onen-(2)
EP0516410A2 (fr) * 1991-05-28 1992-12-02 Wisconsin Alumni Research Foundation Nouveau procédé pour la préparation des composés 19-nor vitamine D
EP1078931A2 (fr) * 1999-08-23 2001-02-28 F. Hoffmann-La Roche Ag Procédé de préparation d'analogues de vitamine D

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BARROS, M.T. ET AL.: "The first synthesis of (-)-Asperpentyn and efficient syntheses of (+)-Harveynone, (+)-Epiepoformin and (-)-Theobroxide", CHEMISTRY-A EUROPEAN JOURNAL, vol. 6, no. 21, 2000, pages 3991 - 3996, XP002953121 *
MOURINO A. ET AL.: "Efficient and versatile synthesis of A-ring precursors of 1alpha, 25-dihydroxyvitamin D3 and analogues", TETRAHEDRON LETTERS, vol. 38, no. 26, 1997, pages 4713 - 4716, XP002953120 *

Also Published As

Publication number Publication date
JP2002201150A (ja) 2002-07-16
JP4811547B2 (ja) 2011-11-09

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