BR0102766B1 - aditivo refrigerante hìbrido suplementar. - Google Patents
aditivo refrigerante hìbrido suplementar. Download PDFInfo
- Publication number
- BR0102766B1 BR0102766B1 BRPI0102766-2A BR0102766A BR0102766B1 BR 0102766 B1 BR0102766 B1 BR 0102766B1 BR 0102766 A BR0102766 A BR 0102766A BR 0102766 B1 BR0102766 B1 BR 0102766B1
- Authority
- BR
- Brazil
- Prior art keywords
- additive
- salt
- corrosion
- salts
- refrigerant
- Prior art date
Links
- 239000000654 additive Substances 0.000 title claims description 106
- 239000003507 refrigerant Substances 0.000 title claims description 80
- 230000000996 additive effect Effects 0.000 title claims description 74
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 36
- 238000005260 corrosion Methods 0.000 claims description 35
- 230000007797 corrosion Effects 0.000 claims description 28
- -1 cationic alkali metal salts Chemical class 0.000 claims description 25
- 238000001816 cooling Methods 0.000 claims description 25
- 150000003839 salts Chemical class 0.000 claims description 24
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 18
- 239000001361 adipic acid Substances 0.000 claims description 18
- 235000011037 adipic acid Nutrition 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000006172 buffering agent Substances 0.000 claims description 16
- 239000002826 coolant Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 150000002826 nitrites Chemical class 0.000 claims description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical class [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 10
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 8
- 239000012964 benzotriazole Substances 0.000 claims description 8
- 150000004760 silicates Chemical class 0.000 claims description 8
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 150000002823 nitrates Chemical class 0.000 claims description 7
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 230000003134 recirculating effect Effects 0.000 claims description 2
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 230000000153 supplemental effect Effects 0.000 description 37
- 239000000203 mixture Substances 0.000 description 35
- 238000012360 testing method Methods 0.000 description 23
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 21
- 229910052782 aluminium Inorganic materials 0.000 description 20
- 239000008233 hard water Substances 0.000 description 18
- 238000005057 refrigeration Methods 0.000 description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 230000008901 benefit Effects 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- 230000003139 buffering effect Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 150000007524 organic acids Chemical class 0.000 description 8
- 230000002528 anti-freeze Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical compound C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 235000014666 liquid concentrate Nutrition 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000002455 scale inhibitor Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 239000012085 test solution Substances 0.000 description 4
- 229910001018 Cast iron Inorganic materials 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 150000003851 azoles Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- 239000004484 Briquette Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002334 glycols Polymers 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000015393 sodium molybdate Nutrition 0.000 description 2
- 239000011684 sodium molybdate Substances 0.000 description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- 229940117958 vinyl acetate Drugs 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- BXALRZFQYDYTGH-UHFFFAOYSA-N 1-oxoprop-2-ene-1-sulfonic acid Chemical class OS(=O)(=O)C(=O)C=C BXALRZFQYDYTGH-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 1
- ZDFKSZDMHJHQHS-UHFFFAOYSA-N 2-tert-butylbenzoic acid Chemical compound CC(C)(C)C1=CC=CC=C1C(O)=O ZDFKSZDMHJHQHS-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000001279 adipic acids Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- UYLXPXFRVJUNIF-UHFFFAOYSA-N but-3-enoic acid ethene 2-phenylethenesulfonic acid Chemical compound C(=CC1=CC=CC=C1)S(=O)(=O)O.C(=C)CC(=O)O.C=C UYLXPXFRVJUNIF-UHFFFAOYSA-N 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- AKTYUTRHNMIXHM-UHFFFAOYSA-N ethenyl acetate;ethenyl prop-2-enoate Chemical compound CC(=O)OC=C.C=COC(=O)C=C AKTYUTRHNMIXHM-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- MEUIIHOXOWVKNP-UHFFFAOYSA-N phosphanylformic acid Chemical compound OC(P)=O MEUIIHOXOWVKNP-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/611,332 US6733687B1 (en) | 2000-07-06 | 2000-07-06 | Hybrid supplemental coolant additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0102766A BR0102766A (pt) | 2002-07-16 |
| BR0102766B1 true BR0102766B1 (pt) | 2011-09-06 |
Family
ID=24448604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0102766-2A BR0102766B1 (pt) | 2000-07-06 | 2001-07-06 | aditivo refrigerante hìbrido suplementar. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6733687B1 (enExample) |
| EP (1) | EP1170347B1 (enExample) |
| JP (1) | JP4803912B2 (enExample) |
| AU (1) | AU760483B2 (enExample) |
| BR (1) | BR0102766B1 (enExample) |
| DE (1) | DE60140921D1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10235477A1 (de) * | 2002-08-02 | 2004-02-12 | Basf Ag | Glykolfreie wässrige Gefrierschutzmittel enthaltend Dicarbonsäuresalze |
| US7153422B2 (en) * | 2004-01-29 | 2006-12-26 | Fleetguard, Inc. | Liquid additive slow-release apparatus driven by a filter pressure gradient |
| CN1297623C (zh) * | 2004-07-23 | 2007-01-31 | 中国石油化工股份有限公司 | 一种提高发动机冷却液稳定性的方法 |
| US7435359B2 (en) * | 2004-12-21 | 2008-10-14 | Hercules Chemical Company Incorporated | Corrosion inhibiting heat transfer materials |
| US20070001150A1 (en) * | 2005-06-29 | 2007-01-04 | Hudgens Roy D | Corrosion-inhibiting composition and method of use |
| US9994755B2 (en) | 2012-09-07 | 2018-06-12 | Prestone Products Corporation | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
| US9023235B2 (en) * | 2012-09-07 | 2015-05-05 | Prestone Products Corporation | Heat transfer fluid additive composition |
| US10336928B2 (en) * | 2014-10-10 | 2019-07-02 | Dober Chemical Corporation | Corrosion inhibited compositions and methods of using same |
| CN104593779B (zh) * | 2015-01-21 | 2018-02-16 | 北京科技大学 | 一种低pH可控释放的智能缓蚀剂的制备方法 |
| CN108165239A (zh) * | 2017-12-08 | 2018-06-15 | 洪梓峰 | 一种复合纳米银添加剂及其制备方法 |
| EP4056664A1 (de) | 2021-03-10 | 2022-09-14 | Basf Se | Feste kühlmittelkonzentrate und deren herstellung |
| JP2024527290A (ja) * | 2021-06-25 | 2024-07-24 | ソリュゲン インコーポレーテッド | 非鉄金属腐食防止剤及びその使用方法 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3607757A (en) | 1968-07-24 | 1971-09-21 | Stauffer Chemical Co | Corrosion resistant antifreeze compositions |
| US3931029A (en) | 1974-10-15 | 1976-01-06 | Basf Wyandotte Corporation | Corrosion inhibited antifreeze compositions and process for inhibiting the corrosion of solder alloys |
| JPS5937750B2 (ja) * | 1978-10-30 | 1984-09-11 | 株式会社片山化学工業研究所 | 金属防食剤 |
| SE434409B (sv) | 1979-05-04 | 1984-07-23 | Boliden Ab | Sett att behandla ett vattenhaltigt system for att inhibera korrosion av gjutjern och gjutaluminium, samt medel for utforande av settet |
| GB2075483A (en) | 1980-03-12 | 1981-11-18 | Ici Ltd | Corrosion inhibitors and compositions containing them |
| US4342596A (en) | 1980-04-10 | 1982-08-03 | Conner Alvin James Sen | Non-petroleum based metal corrosion inhibitor |
| US4452758A (en) | 1981-07-08 | 1984-06-05 | Basf Wyandotte Corporation | Compositions and process for inhibiting corrosion of aluminum |
| US4548787A (en) | 1981-10-26 | 1985-10-22 | Basf Wyandotte Corporation | Aqueous liquids containing metal cavitation-erosion corrosion inhibitors |
| FR2538406B1 (fr) | 1982-12-27 | 1985-09-20 | Bp Chimie Sa | Procede de traitement de fluides aqueux en vue de reduire la corrosion des metaux en leur contact |
| US4454050A (en) | 1983-03-21 | 1984-06-12 | Pennwalt Corporation | Aqueous release agent and lubricant |
| AU562417B2 (en) | 1983-04-13 | 1987-06-11 | W.R. Grace & Co. | Phosphate or molybdate anti-corrosive compositions |
| US4640793A (en) | 1984-02-14 | 1987-02-03 | Calgon Corporation | Synergistic scale and corrosion inhibiting admixtures containing carboxylic acid/sulfonic acid polymers |
| US4561990A (en) | 1984-10-04 | 1985-12-31 | Texaco Inc. | High lead solder corrosion inhibitors |
| US4587028A (en) | 1984-10-15 | 1986-05-06 | Texaco Inc. | Non-silicate antifreeze formulations |
| US4717495A (en) | 1984-11-30 | 1988-01-05 | Fleetguard, Inc. | Diesel engine cooling system compositions |
| US4647392A (en) | 1985-12-27 | 1987-03-03 | Texaco Inc. | Monobasic-dibasic acid/salt antifreeze corrosion inhibitor |
| GB8606901D0 (en) | 1986-03-20 | 1986-04-23 | Shell Int Research | Corrosion-inhibiting heat-transfer composition |
| US4851145A (en) | 1986-06-30 | 1989-07-25 | S.A. Texaco Petroleum Nv | Corrosion-inhibited antifreeze/coolant composition |
| US4775415A (en) | 1986-08-06 | 1988-10-04 | First Brands Corporation | Alcohol-based aluminum corrosion inhibitor compositions comprising polysilyl compounds |
| KR910003915B1 (ko) | 1988-01-27 | 1991-06-15 | 한국과학기술원 | 자동차 방열기용 부동액 조성물 |
| US5002697A (en) | 1988-03-15 | 1991-03-26 | Nalco Chemical Company | Molybdate-containing corrosion inhibitors |
| US4798683A (en) | 1988-04-21 | 1989-01-17 | Calgon Corporation | Method for controlling corrosion using molybdate compositions |
| JPH01315481A (ja) * | 1988-06-15 | 1989-12-20 | Nippon Shokubai Kagaku Kogyo Co Ltd | 不凍液 |
| US5071580A (en) * | 1988-09-29 | 1991-12-10 | W. R. Grace & Co.-Conn. | Pumpable corrosion inhibitor slurries suitable for charging cooling system filters |
| US4946616A (en) | 1988-11-14 | 1990-08-07 | The Dow Chemical Company | Heat transfer fluids containing dicarboxylic acid mixtures as corrosion inhibitors |
| SU1726489A1 (ru) * | 1990-06-25 | 1992-04-15 | Уральский политехнический институт им.С.М.Кирова | Охлаждающа жидкость |
| US5085793A (en) | 1990-11-19 | 1992-02-04 | Texaco Chemical Company | Corrosion-inhibited antifreeze/coolant composition |
| US5422026A (en) | 1990-12-14 | 1995-06-06 | Arco Chemical Technology, L.P. | Phosphate-free antifreeze formulation |
| US5320779A (en) | 1991-06-06 | 1994-06-14 | Nalco Chemical Company | Use of molybdate as corrosion inhibitor in a zinc/phosphonate cooling water treatment |
| US5192447A (en) | 1991-07-09 | 1993-03-09 | Nalco Chemical Company | Use of molybdate as a cooling water corrosion inhibitor at higher temperatures |
| US5288419A (en) | 1991-07-23 | 1994-02-22 | Basf Corporation | Glycol-based polycarboxylate-containing antifreeze/coolant formulations for resisting cavitation erosion-corrosion on aluminum |
| DK187391D0 (da) | 1991-11-15 | 1991-11-15 | Inst Produktudvikling | Fremgangsmaade til efterbehandling af zinkbelagte materialer samt behandlingsoploesning til brug ved fremgangsmaaden |
| FR2686346B1 (fr) | 1992-01-21 | 1994-09-30 | Bp Chemicals Snc | Composition antigel et fluide aqueux. |
| US5646211A (en) | 1992-01-31 | 1997-07-08 | Henkel Corporation | Autodeposition coating composition |
| JPH06116764A (ja) * | 1992-10-07 | 1994-04-26 | Echiren Chem Kk | 不凍液組成物 |
| US5668096A (en) | 1994-05-20 | 1997-09-16 | Betzdearborn Inc. | Cleaning and passivating treatment for metals |
| JP2820034B2 (ja) * | 1994-07-14 | 1998-11-05 | 株式会社デンソー | 点火コイル |
| FR2733509B1 (fr) | 1995-04-28 | 1997-07-04 | Bp Chemicals Snc | Composition d'antigel et fluide aqueux comprenant la composition |
| US5800732A (en) | 1997-02-07 | 1998-09-01 | Diversey Lever, Inc. | All-in-one treatment agent for cooling water |
| JPH1161117A (ja) * | 1997-08-27 | 1999-03-05 | Tokyo Fine Chem Kk | 防錆液組成物 |
| US5997763A (en) | 1998-04-27 | 1999-12-07 | Shell Oil Company | Corrosion inhibiting antifreeze compositions containing various carboxylic acids |
| JP2000026845A (ja) * | 1998-07-15 | 2000-01-25 | Ethylene Chem Kk | リサイクル容易な冷却液組成物 |
-
2000
- 2000-07-06 US US09/611,332 patent/US6733687B1/en not_active Expired - Lifetime
-
2001
- 2001-07-04 DE DE60140921T patent/DE60140921D1/de not_active Expired - Lifetime
- 2001-07-04 EP EP01305789A patent/EP1170347B1/en not_active Expired - Lifetime
- 2001-07-05 AU AU54230/01A patent/AU760483B2/en not_active Ceased
- 2001-07-05 JP JP2001204829A patent/JP4803912B2/ja not_active Expired - Fee Related
- 2001-07-06 BR BRPI0102766-2A patent/BR0102766B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR0102766A (pt) | 2002-07-16 |
| US6733687B1 (en) | 2004-05-11 |
| JP4803912B2 (ja) | 2011-10-26 |
| EP1170347A3 (en) | 2004-01-02 |
| AU5423001A (en) | 2002-01-10 |
| DE60140921D1 (de) | 2010-02-11 |
| EP1170347A2 (en) | 2002-01-09 |
| JP2002069676A (ja) | 2002-03-08 |
| EP1170347B1 (en) | 2009-12-30 |
| AU760483B2 (en) | 2003-05-15 |
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| B08G | Application fees: restoration [chapter 8.7 patent gazette] | ||
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| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
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