BR0016440A - Processo de fabricação de uma mistura de cetonas/álcoois - Google Patents

Processo de fabricação de uma mistura de cetonas/álcoois

Info

Publication number
BR0016440A
BR0016440A BR0016440-2A BR0016440A BR0016440A BR 0016440 A BR0016440 A BR 0016440A BR 0016440 A BR0016440 A BR 0016440A BR 0016440 A BR0016440 A BR 0016440A
Authority
BR
Brazil
Prior art keywords
ketone
mixture
manufacturing process
alcohol mixture
organometallic
Prior art date
Application number
BR0016440-2A
Other languages
English (en)
Inventor
James Clark
Eric Fache
Ducan Macquarrie
Peter Price
John Rafelt
Original Assignee
Rhodia Polyamide Intermediates
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates
Publication of BR0016440A publication Critical patent/BR0016440A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO DE FABRICAçãO DE UMA MISTURA DE CETONAS/áLCOOIS". A invenção refere-se a um processo de preparação de uma mistura de álcoois/cetonas por decomposição de um hidroperóxido de alquila. Ela se refere mais particularmente à preparação de uma mistura de ciclo-hexanol/ciclo-hexanona por decomposição de hidroperóxido de ciclo-hexila em presença de uma catálise heterogênea. De acordo com a invenção, a reação é realizada em presença de um catalisador heterogêneo que compreende um segmento organometálico fixado na superfície de um composto sólido poroso como a sílica. O segmento organometálico pode corresponder à formula geral (I).
BR0016440-2A 1999-12-17 2000-12-14 Processo de fabricação de uma mistura de cetonas/álcoois BR0016440A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9916010A FR2802526B1 (fr) 1999-12-17 1999-12-17 Procede de preparation de melanges alcools/cetones
PCT/FR2000/003517 WO2001044153A1 (fr) 1999-12-17 2000-12-14 Procede de preparation de melanges alcools/cetones

Publications (1)

Publication Number Publication Date
BR0016440A true BR0016440A (pt) 2002-10-01

Family

ID=9553436

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0016440-2A BR0016440A (pt) 1999-12-17 2000-12-14 Processo de fabricação de uma mistura de cetonas/álcoois

Country Status (13)

Country Link
US (1) US6677490B2 (pt)
EP (1) EP1237836B1 (pt)
JP (1) JP2003517030A (pt)
KR (1) KR20020062348A (pt)
CN (1) CN1414937A (pt)
BR (1) BR0016440A (pt)
CA (1) CA2394259A1 (pt)
DE (1) DE60010510D1 (pt)
FR (1) FR2802526B1 (pt)
PL (1) PL355723A1 (pt)
RU (1) RU2233830C2 (pt)
SK (1) SK8462002A3 (pt)
WO (1) WO2001044153A1 (pt)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2823745A1 (fr) * 2001-04-20 2002-10-25 Rhodia Polyamide Intermediates Procede de decomposition catalytique des hydroperoxydes organiques
FR2831535B1 (fr) * 2001-10-30 2004-08-13 Rhodia Polyamide Intermediates Procede de decomposition catalytique des hydroperoxydes organiques
FR2834478A1 (fr) * 2002-01-04 2003-07-11 Rhodia Chimie Sa Catalyseur immobilise sur silice pour catalyse heterogene
GB0218675D0 (en) * 2002-08-12 2002-09-18 Ici Plc Nitrogen-containing ligands
ES2387016T3 (es) * 2003-10-17 2012-09-11 Tyco Healthcare Group Lp Dispositivo de grapado quirúrgico
US7442841B2 (en) * 2006-08-18 2008-10-28 Invista North America S.A R.L. Extraction process
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US7888537B2 (en) * 2006-12-29 2011-02-15 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
EP2753655B1 (en) 2011-09-07 2019-12-04 Dow Silicones Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
JP6066355B2 (ja) 2011-09-07 2017-01-25 ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ ジルコニウム含有錯体及び縮合反応触媒、該触媒の調製方法、及び該触媒を含有する組成物
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9328205B2 (en) 2011-10-04 2016-05-03 Dow Corning Corporation Iron(III) containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
JP6628800B2 (ja) * 2014-11-28 2020-01-15 ロディア オペレーションズＲｈｏｄｉａ Ｏｐｅｒａｔｉｏｎｓ アルコール及び／又はケトンの製造方法
ES2713189T3 (es) * 2014-12-22 2019-05-20 Rhodia Operations Catalizadores de oxidación de cicloalcano y método para producir alcoholes y cetonas
WO2016181943A1 (ja) * 2015-05-12 2016-11-17 本田技研工業株式会社 燃料改質システム
CN108654684B (zh) * 2017-03-29 2020-09-04 中国科学院大连化学物理研究所 一种b/l酸修饰的有机硅球催化剂及制备和其应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1547427A (fr) * 1967-05-26 1968-11-29 Rhone Poulenc Sa Perfectionnement à la préparation de mélanges cycloalcanols/cycloalcanones
US3987100A (en) * 1974-04-11 1976-10-19 E. I. Du Pont De Nemours And Company Cyclohexane oxidation in the presence of binary catalysts
NL7802125A (nl) * 1978-02-25 1979-08-28 Stamicarbon Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen.
US4900705A (en) * 1983-06-20 1990-02-13 Texaco Inc. Novel ligand catalyst systems formed by reaction of carbonyl compounds with organosilicon compounds
US4720592A (en) * 1986-09-05 1988-01-19 E. I. Du Pont De Nemours And Company Preparation of cyclohexanone and cyclohexanol
NL8802592A (nl) * 1988-10-21 1990-05-16 Stamicarbon Werkwijze voor de bereiding van een k/a-mengsel.
NL9000893A (nl) * 1990-04-14 1991-11-01 Stamicarbon Werkwijze voor de bereiding van een cycloalkanon en/of cycloalkanol.
NL9100521A (nl) * 1991-03-25 1992-10-16 Stamicarbon Werkwijze voor de bereiding van een alkanon en/of alkanol.
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
US6160183A (en) * 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes

Also Published As

Publication number Publication date
US20030097025A1 (en) 2003-05-22
KR20020062348A (ko) 2002-07-25
DE60010510D1 (de) 2004-06-09
US6677490B2 (en) 2004-01-13
EP1237836B1 (fr) 2004-05-06
PL355723A1 (en) 2004-05-17
CN1414937A (zh) 2003-04-30
FR2802526A1 (fr) 2001-06-22
JP2003517030A (ja) 2003-05-20
CA2394259A1 (fr) 2001-06-21
RU2233830C2 (ru) 2004-08-10
FR2802526B1 (fr) 2003-04-18
WO2001044153A1 (fr) 2001-06-21
EP1237836A1 (fr) 2002-09-11
SK8462002A3 (en) 2003-01-09

Similar Documents

Publication Publication Date Title
BR0016440A (pt) Processo de fabricação de uma mistura de cetonas/álcoois
WO2002048125A3 (en) Process for preparing oxirane compounds
BRPI0411459A (pt) processo para aepoxidação de propeno
RU2003121244A (ru) Получение соединений оксирана
ATE270282T1 (de) Verfahren zur kontinuierlichen herstellung eines epoxids
BR0115988A (pt) Derivados de tetralona como agentes antitumorais
BR0108050A (pt) Processo de fabricação de um oxirano por reação entre uma olefina e peróxido de hidrogênio em presença de um catalisador e de um diluente orgânico, instalação, e, processo integrado de fabricação de h2o2
BR0207063A (pt) processo para a epoxidação de um composto orgánico
TW200613057A (en) Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
BR9810113A (pt) Processo para a produção de 1,3 - propanodiol
WO2003105756A3 (en) STEREOSELECTIVE SYNTHESIS OF SUBSTITUTED CYCLOALKYLES IN POSITIONS 1 AND 2
BR0209197A (pt) Processo para produção de óxido de propileno
MY144065A (en) Epimerisation of allylic alcohols.
BR0311699A (pt) Processo para a decomposição de hidroperóxido de cicloexila
BR9902357A (pt) Processo para a fabricação de citral.
MXPA03011411A (es) Hidrohilacion de beta-dicarbonilos con catalizadores de zirconio.
RU2004111680A (ru) Способ получения органических гидропероксидов
KR970010731A (ko) 광학 활성 2-할로-1-(치환된 페닐) 에탄올 및 치환된 스티렌 옥사이드의 제조방법
MXPA03011973A (es) Sistema catalitico y proceso para el reordenamiento de epoxidos a alcoholes alilicos.
BR9916382A (pt) Processo para a preparação de um composto
Doyle et al. Silane reductions in acidic media. 9. The effect of Lewis acids on stereoselectivities in ketone reductions. The principle of complexation-induced conformational perturbation. Energy minimization in the transition states for hydride transfer
BR9917285A (pt) Processo de decomposição de hidroperóxidos
BRPI0411779A (pt) processos para a produção de um alquilbenzeno e para a produção de cumeno
ATE332907T1 (de) Racemoselektive herstellung rac- diorganosilylbis(2- methylbenzo eöindenyl)zirconium-verbindungen
ATE315548T1 (de) Farbzahlverbesserung von mehrwertigen alkoholen durch hydrierung

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1929 DE 26/12/2007.