MXPA03011973A - Sistema catalitico y proceso para el reordenamiento de epoxidos a alcoholes alilicos. - Google Patents

Sistema catalitico y proceso para el reordenamiento de epoxidos a alcoholes alilicos.

Info

Publication number
MXPA03011973A
MXPA03011973A MXPA03011973A MXPA03011973A MXPA03011973A MX PA03011973 A MXPA03011973 A MX PA03011973A MX PA03011973 A MXPA03011973 A MX PA03011973A MX PA03011973 A MXPA03011973 A MX PA03011973A MX PA03011973 A MXPA03011973 A MX PA03011973A
Authority
MX
Mexico
Prior art keywords
catalyst system
rearrangement
allylic alcohols
epoxides
allylic
Prior art date
Application number
MXPA03011973A
Other languages
English (en)
Inventor
G Kolomeyer Gennadiy
Original Assignee
Millennium Specialty Chem Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Millennium Specialty Chem Inc filed Critical Millennium Specialty Chem Inc
Publication of MXPA03011973A publication Critical patent/MXPA03011973A/es

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B01J31/0238—Amines with a primary amino group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00—Fermentation processes for beer
    • C12C11/02—Pitching yeast
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mycology (AREA)
  • Food Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un sistema catalitico que puede usarse para lograr (a) la preparacion de los alcoholes alilicos mediante el reordenamiento del epoxido correspondiente, cuando el alcohol alilico es un producto deseado; (b) reaccion subsecuente, es decir, oxidacion selectiva de los alcoholes alilicos obtenidos en la etapa (a) para producir un producto deseado, es decir, compuestos carbonilo alfa, beta-no saturados y/o (c) la habilidad de realizar las etapas a) y b) en un proceso de un solo contenedor. En una modalidad, el sistema catalitico incluye (i) al menos un catalizador primario que incluye uno o mas compuestos que contienen complejos metalicos u organicos, inorganicos, homogeneos o heterogeneos y (ii) al menos un modificador/activador que comprende al menos un compuesto fenolico.
MXPA03011973A 2001-07-05 2002-07-02 Sistema catalitico y proceso para el reordenamiento de epoxidos a alcoholes alilicos. MXPA03011973A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/899,518 US6835686B2 (en) 2001-07-05 2001-07-05 Catalyst system and process for rearrangement of epoxides to allylic alcohols
PCT/US2002/021168 WO2003004448A1 (en) 2001-07-05 2002-07-02 Catalyst system and process for rearrangement of epoxides to allylic alcohols

Publications (1)

Publication Number Publication Date
MXPA03011973A true MXPA03011973A (es) 2004-03-26

Family

ID=25411122

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA03011973A MXPA03011973A (es) 2001-07-05 2002-07-02 Sistema catalitico y proceso para el reordenamiento de epoxidos a alcoholes alilicos.

Country Status (9)

Country Link
US (1) US6835686B2 (es)
EP (1) EP1404635B1 (es)
JP (1) JP4299121B2 (es)
AT (1) ATE466829T1 (es)
DE (1) DE60236283D1 (es)
ES (1) ES2341228T3 (es)
IL (2) IL159319A0 (es)
MX (1) MXPA03011973A (es)
WO (1) WO2003004448A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7884252B1 (en) 2010-04-19 2011-02-08 Lyondellbasell Flavors & Fragrances, Llc Process for making trans-isocarveol
US7851660B1 (en) 2010-04-19 2010-12-14 Millennium Specialty Chemicals, Inc. Process for making perillyl alcohol
CN101891602A (zh) * 2010-07-21 2010-11-24 浙江新化化工股份有限公司 一种香芹酮的合成方法
RU2458902C1 (ru) * 2011-07-08 2012-08-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Способ получения миртанола
US10119096B2 (en) * 2015-08-07 2018-11-06 Symrise Inc. Spearmint flavor enhancer
HUP1600341A2 (en) * 2016-05-26 2017-11-28 Flexinnova Kft Antislip flexible materials and methods for their making and use
US20240051907A1 (en) * 2020-01-27 2024-02-15 Symrise Ag Catalyst system
EP4175950A1 (de) 2020-07-01 2023-05-10 Symrise AG Neue verfahren zur herstellung von cis-cedrandiol
CN113185383B (zh) * 2021-04-28 2022-07-12 福州大学 一种以柠檬烯环氧化物为加氢受体的香芹酚制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2426264A (en) 1945-01-16 1947-08-26 Carbide & Carbon Chem Corp Production of allyl alcohol
DE109524C (es) 1959-04-02
JPS5518697B2 (es) 1973-09-21 1980-05-21
US4080491A (en) * 1975-08-27 1978-03-21 Showa Denko K.K. Process of producing ring-opening polymerization products
US4496776A (en) 1983-08-11 1985-01-29 Shell Oil Company Epoxide isomerization process
US4760117A (en) * 1985-06-11 1988-07-26 General Electric Company Method for preparing copolycarbonates from cyclic polycarbonate oligomers
JP2766482B2 (ja) * 1988-08-09 1998-06-18 古河電気工業株式会社 アルミニウム基合金圧延板の製造方法
US5114900A (en) * 1988-09-30 1992-05-19 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts
US5118650A (en) * 1988-09-30 1992-06-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified group iiib metal-containing bimetallic or polymetallic catalysts
US5104987A (en) * 1990-09-20 1992-04-14 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of active hydrogen-containing compounds
US5262371A (en) * 1992-05-06 1993-11-16 Arco Chemical Technology, L.P. Alkylene oxide isomerization process and catalyst
GB9405036D0 (en) * 1994-03-15 1994-04-27 Univ Reading Preparation of allyl alcohols
US5712402A (en) * 1994-08-22 1998-01-27 Board Of Trustees Operating Michigan State University Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation
US5455215A (en) 1994-10-17 1995-10-03 Arco Chemical Technology, L.P. Epoxide isomerization catalysts
GB9525079D0 (en) 1995-12-07 1996-02-07 Zylepsis Ltd Organic compounds and their preparation and uses
DE19702787A1 (de) * 1997-01-27 1998-07-30 Bayer Ag Verfahren zur Herstellung von Polyetherpolyolen
US5780525A (en) * 1997-02-14 1998-07-14 Reliance Electric Industrial Company Photocurable composition for electrical insulation
US5883265A (en) * 1997-04-15 1999-03-16 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactones and/or hydrates and/or esters thereof
DE19723950A1 (de) * 1997-06-06 1998-12-10 Basf Ag Verfahren zur Oxidation einer mindestens eine C-C-Doppelbindung aufweisenden organischen Verbindung
JP3989598B2 (ja) 1997-08-05 2007-10-10 株式会社クラレ アリル型アルコールの製造方法
US6180726B1 (en) * 1998-03-10 2001-01-30 H. B. Fuller Licensing & Financing Inc. High temperature resistant coating composition and method of using thereof
US6492565B2 (en) * 1998-10-07 2002-12-10 Bayer Aktiengesellschaft Process for the preparation of polyether polyols
US6376672B1 (en) * 1999-04-27 2002-04-23 Hoffmann-La Roche Inc. Naphthalenylmethoxypiperidines as renin inhibitors
US6906208B2 (en) * 1999-09-07 2005-06-14 Abb Lummus Global Inc. Mesoporous material and use thereof for the selective oxidation of organic compounds
US6335304B1 (en) * 1999-11-09 2002-01-01 King Industries, Inc Metal salts of phosphoric acid esters as cross linking catalysts
US6743748B2 (en) * 2001-03-12 2004-06-01 Nippon Shokubai Co., Ltd. Catalyst for producing epoxy compounds and method of producing epoxy compounds using the same
US6600007B2 (en) * 2001-03-27 2003-07-29 Southwest Distributing Co. Preparation of bromine-containing hydroxy-functional copolymers

Also Published As

Publication number Publication date
WO2003004448A1 (en) 2003-01-16
EP1404635B1 (en) 2010-05-05
ATE466829T1 (de) 2010-05-15
IL159319A0 (en) 2004-06-01
DE60236283D1 (de) 2010-06-17
IL159319A (en) 2009-07-20
JP2004533926A (ja) 2004-11-11
EP1404635A1 (en) 2004-04-07
JP4299121B2 (ja) 2009-07-22
US6835686B2 (en) 2004-12-28
US20030065230A1 (en) 2003-04-03
ES2341228T3 (es) 2010-06-17

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