BG29288A3 - Метод за получаване на катализатор за полимеризиране на пропилен - Google Patents
Метод за получаване на катализатор за полимеризиране на пропиленInfo
- Publication number
- BG29288A3 BG29288A3 BG033790A BG3379076A BG29288A3 BG 29288 A3 BG29288 A3 BG 29288A3 BG 033790 A BG033790 A BG 033790A BG 3379076 A BG3379076 A BG 3379076A BG 29288 A3 BG29288 A3 BG 29288A3
- Authority
- BG
- Bulgaria
- Prior art keywords
- component
- molar ratio
- compound
- lewis base
- catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title 1
- 239000002879 Lewis base Substances 0.000 abstract 4
- 150000007527 lewis bases Chemical class 0.000 abstract 4
- 150000003609 titanium compounds Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 239000011368 organic material Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 abstract 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- -1 aluminum compound Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 235000011147 magnesium chloride Nutrition 0.000 abstract 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 235000002867 manganese chloride Nutrition 0.000 abstract 1
- 239000011565 manganese chloride Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Метод за получаване на катализатор за полимеризиране на порпилен, съгласно който при температура от 15,5 до 100'с се смесват първи компонент получен от смесването на халогенирано дву-, триили четиривалентно титаново съединение, основа на люис и съединение, избрано измежду магнезиеви и манганови двухалиди, евентуално заедно с твърд органичен материал,който е инертен към катализаторните компоненти, като първият компонент съдържа от 35 до 65% тегл. Магнезиев или манганов двухлорид, от 10 до 60% тегл. Твърд инертен органичен материал и от 5 до 25% тегл. Обединени титаново съединение и основа на люис, като моларното съотношение на титановото съединение към основата на люис е от 0,7:1 до 1,3:1, втори компонент, избран измежду триалкилалуминий и органоалуминиеви съединения, които имат два или повече алуминиеви атома, свързани един с друг посредством кислороден или азотен атом и трети компонент, който е основа на люис, като моларното съотношение на втория компонент към третия компонент е от 1:1 до 8:1 и където моларното съотношение на алуминиевото съединение към първия компонент е от 1:1 до 150:1, характеризиращ се с това, че се добавя четвърти катализаторен компонент, който е органоалуминиево монохалоидно съединение с формула аlr2х, където r групите представляват алкилови радикали с 1-12 въглеродни атома и са еднакви или различни, а х е халогенен атом, като моларното съотношение на четвъртия компонент към титановото съединение е от 0,5:1 до 200:1. Патентните претенции са формулирани в 5 точки
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59896575A | 1975-07-24 | 1975-07-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG29288A3 true BG29288A3 (bg) | 1980-10-15 |
Family
ID=24397649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG033790A BG29288A3 (bg) | 1975-07-24 | 1976-07-20 | Метод за получаване на катализатор за полимеризиране на пропилен |
Country Status (12)
| Country | Link |
|---|---|
| JP (2) | JPS5215589A (bg) |
| AT (1) | AT374810B (bg) |
| BE (1) | BE843224A (bg) |
| BG (1) | BG29288A3 (bg) |
| DE (1) | DE2633195C2 (bg) |
| ES (1) | ES449488A1 (bg) |
| FR (1) | FR2318880A1 (bg) |
| GB (1) | GB1536358A (bg) |
| IT (1) | IT1063406B (bg) |
| NL (1) | NL162665C (bg) |
| NO (1) | NO147757C (bg) |
| RO (1) | RO72800A (bg) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53143684A (en) * | 1977-05-20 | 1978-12-14 | Mitsui Petrochem Ind Ltd | Polymerization of olefin |
| US4330648A (en) | 1977-12-13 | 1982-05-18 | Phillips Petroleum Company | Catalyst and process of polymerization of alpha-monoolefins |
| US4312784A (en) | 1977-12-13 | 1982-01-26 | Phillips Petroleum Co. | Catalyst and process of polymerization of alpha monoolefins |
| US4242480A (en) * | 1977-12-13 | 1980-12-30 | Phillips Petroleum Company | Catalyst and process of polymerization of alpha monoolefins |
| US4397763A (en) | 1977-12-13 | 1983-08-09 | Phillips Petroleum Company | Catalyst and process of polymerization of alpha-monoolefins |
| JPS54112982A (en) * | 1978-02-02 | 1979-09-04 | Sumitomo Chem Co Ltd | Polymerization of olefins |
| US4260708A (en) * | 1978-09-01 | 1981-04-07 | Phillips Petroleum Company | Phosphite in MgX2 supported TiX3 /AlCl3 catalyst system |
| JPS595203B2 (ja) | 1979-07-25 | 1984-02-03 | 東亜燃料工業株式会社 | α−オレフイン重合用触媒成分の製造方法 |
| US4419269A (en) | 1982-12-06 | 1983-12-06 | The Dow Chemical Company | Transition metal containing catalyst |
| JPS6067508A (ja) * | 1983-09-22 | 1985-04-17 | Toa Nenryo Kogyo Kk | オレフインの重合方法 |
| JPS61136975U (bg) * | 1985-02-18 | 1986-08-26 | ||
| US4851488A (en) * | 1987-04-23 | 1989-07-25 | Shell Oil Company | Process for altering hydrogenated polymer compositions from high melt flow to low melt flow |
| GB8825056D0 (en) * | 1988-10-26 | 1988-11-30 | Shell Int Research | Alkene polymerization process & catalyst compositions therefor |
| JPH0270707A (ja) * | 1989-03-27 | 1990-03-09 | Mitsui Petrochem Ind Ltd | オレフイン重合用触媒 |
| US5459116A (en) * | 1993-05-07 | 1995-10-17 | Samsung General Chemicals Co., Ltd. | Highly active catalyst for the polymerization of olefins and method for the preparation of the same |
| TWI695513B (zh) | 2015-03-27 | 2020-06-01 | 日商半導體能源研究所股份有限公司 | 半導體裝置及電子裝置 |
| TWI693719B (zh) | 2015-05-11 | 2020-05-11 | 日商半導體能源研究所股份有限公司 | 半導體裝置的製造方法 |
| US10553690B2 (en) | 2015-08-04 | 2020-02-04 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and manufacturing method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2976271A (en) * | 1955-10-28 | 1961-03-21 | Exxon Research Engineering Co | Propylene polymerization |
| BE791044A (en) * | 1971-11-08 | 1973-05-07 | Standard Oil Co | Olefins polymn catalyst - consisting of organoaluminium cpd ,transition metal compound amine oxide and organometal cpd |
| IT967867B (it) * | 1972-09-26 | 1974-03-11 | Montedison Spa | Procedimento per la polimerizzazio ne stereospecifica delle alfa ole fine |
| JPS5654323B2 (bg) * | 1973-02-09 | 1981-12-24 | ||
| JPS5719122B2 (bg) * | 1973-12-26 | 1982-04-21 |
-
1976
- 1976-06-21 BE BE168162A patent/BE843224A/xx not_active IP Right Cessation
- 1976-07-02 ES ES449488A patent/ES449488A1/es not_active Expired
- 1976-07-06 AT AT0492576A patent/AT374810B/de not_active IP Right Cessation
- 1976-07-20 BG BG033790A patent/BG29288A3/bg unknown
- 1976-07-21 NO NO762555A patent/NO147757C/no unknown
- 1976-07-22 GB GB30653/76A patent/GB1536358A/en not_active Expired
- 1976-07-22 JP JP51087714A patent/JPS5215589A/ja active Granted
- 1976-07-23 FR FR7622660A patent/FR2318880A1/fr active Granted
- 1976-07-23 IT IT25682/76A patent/IT1063406B/it active
- 1976-07-23 DE DE2633195A patent/DE2633195C2/de not_active Expired
- 1976-07-23 NL NL7608205.A patent/NL162665C/xx not_active IP Right Cessation
- 1976-07-24 RO RO7687095A patent/RO72800A/ro unknown
-
1977
- 1977-11-09 JP JP52133645A patent/JPS5910681B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| RO72800A (ro) | 1983-08-03 |
| NO147757C (no) | 1983-06-08 |
| NL162665B (nl) | 1980-01-15 |
| NL7608205A (nl) | 1977-01-26 |
| JPS5910681B2 (ja) | 1984-03-10 |
| NO147757B (no) | 1983-02-28 |
| BE843224A (fr) | 1976-12-21 |
| FR2318880A1 (fr) | 1977-02-18 |
| AU1603576A (en) | 1978-01-26 |
| AT374810B (de) | 1984-06-12 |
| NL162665C (nl) | 1980-06-16 |
| JPS5366890A (en) | 1978-06-14 |
| IT1063406B (it) | 1985-02-11 |
| JPS547318B2 (bg) | 1979-04-05 |
| DE2633195A1 (de) | 1977-01-27 |
| FR2318880B1 (bg) | 1980-03-28 |
| GB1536358A (en) | 1978-12-20 |
| JPS5215589A (en) | 1977-02-05 |
| NO762555L (bg) | 1977-01-25 |
| RO72800B (ro) | 1983-07-30 |
| ES449488A1 (es) | 1977-08-16 |
| ATA492576A (de) | 1979-05-15 |
| DE2633195C2 (de) | 1983-11-24 |
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