BE807760A - Procede de regeneration de solutions de catalyseurs epuises a base de produits reactionnels de composants de rhodium de composants halogenes - Google Patents

Procede de regeneration de solutions de catalyseurs epuises a base de produits reactionnels de composants de rhodium de composants halogenes

Info

Publication number
BE807760A
BE807760A BE138132A BE138132A BE807760A BE 807760 A BE807760 A BE 807760A BE 138132 A BE138132 A BE 138132A BE 138132 A BE138132 A BE 138132A BE 807760 A BE807760 A BE 807760A
Authority
BE
Belgium
Prior art keywords
components
halogenic
regeneration
solutions based
catalyst solutions
Prior art date
Application number
BE138132A
Other languages
English (en)
French (fr)
Inventor
L W Fannin
V D Phillips
T C Singleton
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of BE807760A publication Critical patent/BE807760A/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0211—Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal (M)n rings, e.g. Rh4(CO)12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/25—Nitrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BE138132A 1972-11-24 1973-11-23 Procede de regeneration de solutions de catalyseurs epuises a base de produits reactionnels de composants de rhodium de composants halogenes BE807760A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US309560A US3887489A (en) 1972-11-24 1972-11-24 Rhodium catalyst regeneration method

Publications (1)

Publication Number Publication Date
BE807760A true BE807760A (fr) 1974-05-24

Family

ID=23198709

Family Applications (1)

Application Number Title Priority Date Filing Date
BE138132A BE807760A (fr) 1972-11-24 1973-11-23 Procede de regeneration de solutions de catalyseurs epuises a base de produits reactionnels de composants de rhodium de composants halogenes

Country Status (13)

Country Link
US (1) US3887489A (xx)
JP (1) JPS581974B2 (xx)
AR (1) AR196803A1 (xx)
BE (1) BE807760A (xx)
BR (1) BR7309073D0 (xx)
CA (1) CA1003812A (xx)
DE (1) DE2358410C2 (xx)
ES (1) ES420713A1 (xx)
FR (1) FR2213096B1 (xx)
GB (1) GB1425872A (xx)
IT (1) IT997218B (xx)
NL (1) NL183750C (xx)
SU (1) SU501661A3 (xx)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen
US4081271A (en) * 1975-03-27 1978-03-28 Protec Process E Tecnologie S.P.A. Process for separating and recovering rhodium and iridium from their mixtures with other precious metals
IT1034633B (it) * 1975-03-27 1979-10-10 Tecnologie Spa Processo per la precipitazione di metalli preziosi da soluzioni che li contengono
US4007130A (en) * 1975-12-29 1977-02-08 Monsanto Company Catalyst regeneration method
DE2911193C2 (de) * 1979-03-22 1981-12-17 W.C. Heraeus Gmbh, 6450 Hanau Verfahren zur Wiedergewinnung von Rhodium
ZA801718B (en) * 1979-03-27 1981-10-28 British Petroleum Co Functionalised inorganic oxide products and their use in the removal of heavy metals,transistion metals and actinidemetals from solution
US4312779A (en) * 1980-09-25 1982-01-26 Uop Inc. Recovery of catalysts
WO1982001829A1 (en) * 1980-11-24 1982-06-10 Kodak Co Eastman Process for the recovery of rhodium catalyst
US4388217A (en) * 1980-11-24 1983-06-14 Eastman Kodak Company Process for the recovery of catalyst values
US4340569A (en) * 1981-03-06 1982-07-20 The Halcon Sd Group, Inc. Treatment of carbonylation residues
US4476238A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
US4476237A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
US4364907A (en) * 1981-06-18 1982-12-21 Eastman Kodak Company Process for recovery of rhodium values
US4434240A (en) 1981-11-16 1984-02-28 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4659682A (en) * 1985-07-08 1987-04-21 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4628041A (en) * 1986-02-10 1986-12-09 Celanese Corporation Rhodium and iodine recovery method
GB8724972D0 (en) * 1987-10-24 1987-11-25 Bp Chem Int Ltd Recovery of noble metals
DE3744213A1 (de) * 1987-12-24 1989-07-06 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DE3903909A1 (de) * 1989-02-10 1990-08-16 Hoechst Ag Verfahren zur entfernung metallischer korrosionsprodukte aus einer bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden, verunreinigten katalysatorloesung
US5237097A (en) * 1990-02-09 1993-08-17 Quantum Chemical Corporation Catalytic carbonylation process
US6133477A (en) * 1997-07-23 2000-10-17 E. I. Du Pont De Nemours And Company Preparation of 3-pentenoic acid
IT1318441B1 (it) * 2000-03-31 2003-08-25 Chimet S P A Procedimento per il recupero e l'affinazione del rodio.
TWI465424B (zh) * 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
JP5486299B2 (ja) * 2006-04-14 2014-05-07 セラニーズ・インターナショナル・コーポレーション 標的ストリーム中のアルデヒド濃度の低減法
US11033890B2 (en) * 2017-11-13 2021-06-15 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2839580A (en) * 1956-01-11 1958-06-17 Exxon Research Engineering Co Preparation of diethyl ketone
NL98500C (xx) * 1956-01-11
US3220957A (en) * 1962-10-31 1965-11-30 Standard Oil Co Catalyst regeneration
US3636034A (en) * 1964-10-02 1972-01-18 Mitsubishi Chem Ind Surfactant production via rhodium-catalyzed oxo process
US3579552A (en) * 1968-08-15 1971-05-18 Monsanto Co Production of carboxylic acids
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe

Also Published As

Publication number Publication date
BR7309073D0 (pt) 1974-08-29
NL183750C (nl) 1989-01-16
NL7315925A (xx) 1974-05-28
AU6284773A (en) 1975-05-29
GB1425872A (en) 1976-02-18
FR2213096A1 (xx) 1974-08-02
JPS581974B2 (ja) 1983-01-13
DE2358410A1 (de) 1974-06-06
US3887489A (en) 1975-06-03
FR2213096B1 (xx) 1980-04-25
ES420713A1 (es) 1976-04-01
SU501661A3 (ru) 1976-01-30
NL183750B (nl) 1988-08-16
CA1003812A (en) 1977-01-18
DE2358410C2 (de) 1982-10-21
AR196803A1 (es) 1974-02-19
IT997218B (it) 1975-12-30
JPS4982597A (xx) 1974-08-08

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Legal Events

Date Code Title Description
RE20 Patent expired

Owner name: BP CHEMICALS LTD

Effective date: 19931123