IT997218B - Procedimento per rigenerare catalizzatori utilizzati parti colarmente nella produzione di acidi carbossilici - Google Patents

Procedimento per rigenerare catalizzatori utilizzati parti colarmente nella produzione di acidi carbossilici

Info

Publication number
IT997218B
IT997218B IT5208/73A IT520873A IT997218B IT 997218 B IT997218 B IT 997218B IT 5208/73 A IT5208/73 A IT 5208/73A IT 520873 A IT520873 A IT 520873A IT 997218 B IT997218 B IT 997218B
Authority
IT
Italy
Prior art keywords
procedure
production
carboxylic acids
partly used
regenerating catalysts
Prior art date
Application number
IT5208/73A
Other languages
English (en)
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Application granted granted Critical
Publication of IT997218B publication Critical patent/IT997218B/it

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/464Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202Polynuclearity
    • B01J2531/0208Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202Polynuclearity
    • B01J2531/0211Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal (M)n rings, e.g. Rh4(CO)12
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • B01J27/25Nitrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
IT5208/73A 1972-11-24 1973-11-26 Procedimento per rigenerare catalizzatori utilizzati parti colarmente nella produzione di acidi carbossilici IT997218B (it)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US309560A US3887489A (en) 1972-11-24 1972-11-24 Rhodium catalyst regeneration method

Publications (1)

Publication Number Publication Date
IT997218B true IT997218B (it) 1975-12-30

Family

ID=23198709

Family Applications (1)

Application Number Title Priority Date Filing Date
IT5208/73A IT997218B (it) 1972-11-24 1973-11-26 Procedimento per rigenerare catalizzatori utilizzati parti colarmente nella produzione di acidi carbossilici

Country Status (13)

Country Link
US (1) US3887489A (it)
JP (1) JPS581974B2 (it)
AR (1) AR196803A1 (it)
BE (1) BE807760A (it)
BR (1) BR7309073D0 (it)
CA (1) CA1003812A (it)
DE (1) DE2358410C2 (it)
ES (1) ES420713A1 (it)
FR (1) FR2213096B1 (it)
GB (1) GB1425872A (it)
IT (1) IT997218B (it)
NL (1) NL183750C (it)
SU (1) SU501661A3 (it)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe
DE2448005C2 (de) * 1974-10-09 1983-10-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Regenerierung von Rhodium oder Iridium enthaltenden Katalysatoren aus Destillationsrückständen von Hydroformylierungsgemischen
US4081271A (en) * 1975-03-27 1978-03-28 Protec Process E Tecnologie S.P.A. Process for separating and recovering rhodium and iridium from their mixtures with other precious metals
IT1034633B (it) * 1975-03-27 1979-10-10 Tecnologie Spa Processo per la precipitazione di metalli preziosi da soluzioni che li contengono
US4007130A (en) * 1975-12-29 1977-02-08 Monsanto Company Catalyst regeneration method
DE2911193C2 (de) * 1979-03-22 1981-12-17 W.C. Heraeus Gmbh, 6450 Hanau Verfahren zur Wiedergewinnung von Rhodium
ZA801718B (en) * 1979-03-27 1981-10-28 British Petroleum Co Functionalised inorganic oxide products and their use in the removal of heavy metals,transistion metals and actinidemetals from solution
US4312779A (en) * 1980-09-25 1982-01-26 Uop Inc. Recovery of catalysts
US4388217A (en) * 1980-11-24 1983-06-14 Eastman Kodak Company Process for the recovery of catalyst values
WO1982001829A1 (en) * 1980-11-24 1982-06-10 Kodak Co Eastman Process for the recovery of rhodium catalyst
US4340569A (en) * 1981-03-06 1982-07-20 The Halcon Sd Group, Inc. Treatment of carbonylation residues
US4476238A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
US4476237A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
US4364907A (en) * 1981-06-18 1982-12-21 Eastman Kodak Company Process for recovery of rhodium values
US4434240A (en) 1981-11-16 1984-02-28 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4659682A (en) * 1985-07-08 1987-04-21 The Halcon Sd Group, Inc. Recovery of noble metal values from carbonylation residues
US4628041A (en) * 1986-02-10 1986-12-09 Celanese Corporation Rhodium and iodine recovery method
GB8724972D0 (en) * 1987-10-24 1987-11-25 Bp Chem Int Ltd Recovery of noble metals
DE3744213A1 (de) * 1987-12-24 1989-07-06 Ruhrchemie Ag Verfahren zur rueckgewinnung von rhodium aus rhodiumkomplexverbindungen enthaltenden waessrigen loesungen
DE3903909A1 (de) * 1989-02-10 1990-08-16 Hoechst Ag Verfahren zur entfernung metallischer korrosionsprodukte aus einer bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden, verunreinigten katalysatorloesung
US5237097A (en) * 1990-02-09 1993-08-17 Quantum Chemical Corporation Catalytic carbonylation process
US6133477A (en) * 1997-07-23 2000-10-17 E. I. Du Pont De Nemours And Company Preparation of 3-pentenoic acid
IT1318441B1 (it) * 2000-03-31 2003-08-25 Chimet S P A Procedimento per il recupero e l'affinazione del rodio.
TWI465424B (zh) * 2006-03-21 2014-12-21 Bp Chem Int Ltd 製造醋酸的方法
DE12007339T8 (de) * 2006-04-14 2014-01-09 Celanese International Corporation Verfahren zur Reduktion von Aldehydkonzentration in einem Targetstrom
CN111278560B (zh) * 2017-11-13 2023-07-21 陶氏技术投资有限责任公司 从氢甲酰化方法回收铑的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2839580A (en) * 1956-01-11 1958-06-17 Exxon Research Engineering Co Preparation of diethyl ketone
NL213649A (it) * 1956-01-11
US3220957A (en) * 1962-10-31 1965-11-30 Standard Oil Co Catalyst regeneration
US3636034A (en) * 1964-10-02 1972-01-18 Mitsubishi Chem Ind Surfactant production via rhodium-catalyzed oxo process
US3579552A (en) * 1968-08-15 1971-05-18 Monsanto Co Production of carboxylic acids
AT312559B (de) * 1972-01-07 1974-01-10 Basf Ag Verfahren zur Abscheidung von Rhodium aus Rhodiumcarbonylkomplexe enthaltenden Lösungen und Überführung des abgescheidenen Rhodiums in lösliche Rhodiumcarbonylkomplexe

Also Published As

Publication number Publication date
NL183750C (nl) 1989-01-16
GB1425872A (en) 1976-02-18
JPS4982597A (it) 1974-08-08
AU6284773A (en) 1975-05-29
DE2358410A1 (de) 1974-06-06
BE807760A (fr) 1974-05-24
NL7315925A (it) 1974-05-28
NL183750B (nl) 1988-08-16
US3887489A (en) 1975-06-03
ES420713A1 (es) 1976-04-01
JPS581974B2 (ja) 1983-01-13
BR7309073D0 (pt) 1974-08-29
FR2213096B1 (it) 1980-04-25
CA1003812A (en) 1977-01-18
SU501661A3 (ru) 1976-01-30
DE2358410C2 (de) 1982-10-21
FR2213096A1 (it) 1974-08-02
AR196803A1 (es) 1974-02-19

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