BE587897A - - Google Patents
Info
- Publication number
- BE587897A BE587897A BE587897DA BE587897A BE 587897 A BE587897 A BE 587897A BE 587897D A BE587897D A BE 587897DA BE 587897 A BE587897 A BE 587897A
- Authority
- BE
- Belgium
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US794841A US3050546A (en) | 1959-02-24 | 1959-02-24 | Process for the manufacture of acrylonitrile |
CH7038959A CH385192A (fr) | 1959-02-24 | 1959-03-05 | Procédé de fabrication de nitriles aliphatiques non saturés |
Publications (1)
Publication Number | Publication Date |
---|---|
BE587897A true BE587897A (it) | 1960-08-22 |
Family
ID=25738043
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE571200D BE571200A (it) | 1959-02-24 | 1958-09-13 | |
BE587897D BE587897A (it) | 1959-02-24 | 1960-02-22 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE571200D BE571200A (it) | 1959-02-24 | 1958-09-13 |
Country Status (12)
Country | Link |
---|---|
US (2) | US2904580A (it) |
BE (2) | BE571200A (it) |
CA (2) | CA687664A (it) |
CH (2) | CH385192A (it) |
DE (2) | DE1127351B (it) |
DK (1) | DK102906C (it) |
FR (2) | FR1222460A (it) |
GB (2) | GB867438A (it) |
IT (2) | IT801567A (it) |
MX (2) | MX64564A (it) |
MY (1) | MY6200020A (it) |
NL (3) | NL107721C (it) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1235297B (de) * | 1959-07-18 | 1967-03-02 | Bayer Ag | Verfahren zur Herstellung von Methacrylsaeurenitril durch Umsetzung von Isobutylen mit Ammoniak und Sauerstoff |
Families Citing this family (91)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE577691A (it) * | 1958-04-16 | |||
US3153085A (en) * | 1959-02-14 | 1964-10-13 | Distillers Co Yeast Ltd | Production of aliphatic nitriles |
CA751473A (en) * | 1959-02-16 | 1967-01-24 | Minekawa Saburo | Process for the production of unsaturated nitriles |
NL248447A (it) * | 1959-04-02 | |||
BE640872A (it) * | 1962-12-08 | |||
US3152170A (en) * | 1959-07-01 | 1964-10-06 | Distillers Co Yeast Ltd | Production of unsaturated aliphatic nitriles |
US3151150A (en) * | 1959-09-14 | 1964-09-29 | Edna Y Kamlet | Process for the manufacture of acrylonitrile |
NL256686A (it) * | 1959-10-28 | |||
CA708973A (en) * | 1960-01-02 | 1965-05-04 | Knapsack-Griesheim Aktiengesellschaft | Process for the manufacture of unsaturated nitriles |
NL261672A (it) * | 1960-02-26 | |||
CA635328A (en) * | 1960-03-09 | 1962-01-23 | Minekawa Saburo | Process for preparing acrylonitrile |
NL265916A (it) * | 1960-04-26 | |||
BE603030A (it) * | 1960-04-26 | |||
CA684867A (en) * | 1960-04-26 | 1964-04-21 | Rottig Walter | Production of aliphatic unsaturated nitriles |
NL266208A (it) * | 1960-06-21 | |||
DE1212962B (de) * | 1960-08-12 | 1966-03-24 | Knapsack Ag | Verfahren zur Abtrennung und Gewinnung von Acrylsaeurenitril und Ammoniak aus gasfoermigen Gemischen durch Auswaschen |
IT658963A (it) * | 1960-11-12 | |||
MX71999A (it) * | 1960-12-07 | |||
US3161670A (en) * | 1960-12-12 | 1964-12-15 | Shell Oil Co | Preparation of olefinic compounds |
US3106574A (en) * | 1960-12-19 | 1963-10-08 | Standard Oil Co | Method for the manufacture of acetonitrile |
US3126407A (en) * | 1960-12-30 | 1964-03-24 | Process for making aliphatic nitriles | |
CA715118A (en) * | 1961-01-23 | 1965-08-03 | Eastman Kodak Company | Catalytic synthesis of acrylonitrile from olefins, ammonia and oxygen |
NL125891C (it) * | 1961-01-26 | |||
US3141902A (en) * | 1961-03-17 | 1964-07-21 | Du Pont | Process for preparation of acrylonitrile |
NL276444A (it) * | 1961-03-29 | |||
IT667228A (it) * | 1961-04-18 | |||
BE618298A (it) * | 1961-05-31 | |||
IT669035A (it) * | 1961-06-20 | |||
US3346617A (en) * | 1961-07-11 | 1967-10-10 | Nitto Chemical Industry Co Ltd | Method for preparing methacrylonitrile |
CA714082A (en) * | 1961-07-14 | 1965-07-20 | Ferlazzo Natale | Process for the catalytic preparation of nitriles starting from olefinic hydrocarbons |
IT672994B (it) * | 1961-07-31 | |||
BE621685A (it) * | 1961-08-24 | |||
CA695698A (en) * | 1961-10-04 | 1964-10-06 | Knapsack-Griesheim Aktiengesellschaft | Process for transforming acetonitrile |
IT701822A (it) * | 1961-11-30 | |||
US3354197A (en) * | 1962-04-25 | 1967-11-21 | Standard Oil Co | Process for the manufacture of unsaturated nitriles from olefins and ammonia |
DE1196179B (de) * | 1962-05-18 | 1965-07-08 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Adipinsaeuredinitril |
DE1280865B (de) * | 1962-05-25 | 1968-10-24 | Metallgesellschaft Ag | Verfahren zur Durchfuehrung der katalytischen Dampfphasenoxydation von Kohlenwasserstoffen |
US3186955A (en) * | 1962-05-28 | 1965-06-01 | Standard Oil Co | Bismuth-molybdenum oxidation catalyst promoted with a ba-si oxide mixture |
MX81014A (it) * | 1962-08-23 | |||
CA709774A (en) * | 1962-09-15 | 1965-05-18 | Knapsack-Griesheim Aktiengesellschaft | Process for transforming acrolein-cyanohydrin |
CA742727A (en) * | 1962-11-28 | 1966-09-13 | The Standard Oil Company | Process for preparing olefinically unsaturated nitriles |
NL135670C (it) * | 1963-05-09 | |||
US3200141A (en) * | 1963-05-27 | 1965-08-10 | Standard Oil Co | Process for the manufacture of acrylonitrile |
US3342849A (en) * | 1963-11-01 | 1967-09-19 | Petro Tex Chem Corp | Production of aliphatic nitriles |
IL22742A (en) * | 1964-01-10 | 1968-09-26 | Princeton Chemical Res Inc | Production of nitriles |
US3260731A (en) * | 1964-03-02 | 1966-07-12 | Shell Oil Co | Process for preparing furonitrile |
US3321411A (en) * | 1964-05-04 | 1967-05-23 | Eastman Kodak Co | Novel catalyst system for the synthesis of unsaturated nitriles |
DE1468879A1 (de) * | 1964-08-01 | 1969-05-08 | Roehm & Haas Gmbh | Verfahren zur Herstellung von Acrylsaeurenitril und Methacrylsaeurenitril |
US3435061A (en) * | 1965-01-06 | 1969-03-25 | Standard Oil Co | Manufacture of aromatic aldehydes and nitriles |
US3462476A (en) * | 1966-03-21 | 1969-08-19 | Exxon Research Engineering Co | Ammoxidation of aromatic hydrocarbons to aromatic nitriles using substantial quantities of water in the reaction mixture |
US3541129A (en) * | 1966-08-12 | 1970-11-17 | Ube Kogyo Kk | Process for the preparation of acrylonitrile |
IT859097A (it) * | 1967-11-28 | |||
US3661723A (en) * | 1969-05-26 | 1972-05-09 | Standard Oil Co Ohio | Process for recovering of acrylonitrile and hydrocyanic acid by addition of acetonitrile to the aqueous acid neutralized effluent |
US3720724A (en) * | 1970-06-03 | 1973-03-13 | Phillips Petroleum Co | Dehydrogenation cyclohexane or mono- or polyalkylcyclohexanes |
US4077912A (en) * | 1972-10-12 | 1978-03-07 | Standard Oil Company | Catalysts useful for exothermic reactions |
US3907859A (en) * | 1972-10-25 | 1975-09-23 | Standard Oil Co Ohio | Coproduction of acrylonitrile and acrylic acid |
GB1417787A (en) * | 1972-11-13 | 1975-12-17 | Mitsubishi Rayon Co | Catalyst composition for oxidation of butenes |
DE2428218A1 (de) * | 1973-06-15 | 1975-01-09 | Forni Ed Impianti Ind Ingg De | Verfahren zur behandlung von abfaellen, insbesondere von muell |
GB1432032A (en) * | 1973-09-07 | 1976-04-14 | Bp Chem Int Ltd | Process for the production of acrylinitrile |
US4000088A (en) * | 1974-06-03 | 1976-12-28 | Nippon Kayaku Co., Ltd. | Oxidation catalyst for the manufacture of methacrylic acid |
CA1076144A (en) * | 1975-12-09 | 1980-04-22 | Alvin B. Stiles | Process for oxidation of 1-propanol |
US4065486A (en) * | 1976-09-13 | 1977-12-27 | E. I. Du Pont De Nemours And Company | Process for recovery of products from a waste stream in the manufacture of acrylonitrile |
JPS582232B2 (ja) * | 1977-12-31 | 1983-01-14 | 旭化成株式会社 | アクリロニトリルの製造方法 |
US4414134A (en) * | 1981-01-05 | 1983-11-08 | The Standard Oil Co. | Impregnating catalysts |
US4814537A (en) * | 1986-09-12 | 1989-03-21 | The Dow Chemical Company | Oxidative coupling of methyl-substituted benzenes |
US4727208A (en) * | 1986-09-12 | 1988-02-23 | The Dow Chemical Company | Oxidative coupling with methyl-substituted benzenes |
US5013860A (en) * | 1988-05-12 | 1991-05-07 | The Dow Chemical Company | Oxydehydrogenation of dinitriles |
DE4000692A1 (de) * | 1990-01-12 | 1991-07-18 | Henkel Kgaa | Verwendung von kolloidalem kieselsaeuresol als hilfsstoff fuer katalysatoren |
US5349109A (en) * | 1991-06-04 | 1994-09-20 | The Board Of Regents Of The University Of Oklahoma | Molybdenum-catalyzed amination of olefins |
JP3573959B2 (ja) | 1998-05-12 | 2004-10-06 | ダイヤニトリックス株式会社 | モリブデン含有酸化物流動層触媒の再生法 |
US5869730A (en) * | 1998-05-13 | 1999-02-09 | The Standard Oil Company | Oxidant reduction by manipulation and/or treatment of aqueous acrylonitrile process streams |
US6284196B1 (en) | 1999-04-01 | 2001-09-04 | Bp Corporation North America Inc. | Apparatus for monitor and control of an ammoxidation reactor with a fourier transform infrared spectrometer |
US20090299087A1 (en) * | 2008-05-28 | 2009-12-03 | Solutia, Inc. | Process for manufacturing unsaturated mononitriles to improve on-stream time and reduce fouling |
JP5906734B2 (ja) * | 2011-12-28 | 2016-04-20 | 三菱レイヨン株式会社 | 含窒素化合物の製造方法 |
EP2821392B1 (en) | 2012-02-29 | 2019-06-19 | Mitsubishi Chemical Corporation | Method for producing acrylonitrile |
EP3310736B1 (de) | 2015-06-17 | 2019-01-30 | Clariant International Ltd | Wasserlösliche oder wasserquellbare polymere als wasserverlustreduzierer in zementschlämmen |
CN108883366A (zh) | 2016-01-09 | 2018-11-23 | 奥升德高性能材料公司 | 用于在丙烯腈反应器进给物流中氰化氢的直接制备的催化剂组合物及方法 |
US11142494B2 (en) | 2016-06-20 | 2021-10-12 | Clariant International Ltd. | Compound comprising certain level of bio-based carbon |
EP3551679B1 (en) | 2016-12-12 | 2023-05-24 | Clariant International Ltd | Polymer comprising certain level of bio-based carbon |
US11311473B2 (en) | 2016-12-12 | 2022-04-26 | Clariant International Ltd | Use of a bio-based polymer in a cosmetic, dermatological or pharmaceutical composition |
US11384186B2 (en) | 2016-12-12 | 2022-07-12 | Clariant International Ltd | Polymer comprising certain level of bio-based carbon |
US20190338060A1 (en) | 2016-12-12 | 2019-11-07 | Clariant International Ltd. | Polymer Comprising Certain Level Of Bio-Based Carbon |
US11401362B2 (en) | 2016-12-15 | 2022-08-02 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
US11306170B2 (en) | 2016-12-15 | 2022-04-19 | Clariant International Ltd. | Water-soluble and/or water-swellable hybrid polymer |
EP3554644A1 (en) | 2016-12-15 | 2019-10-23 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
EP3554646A1 (en) | 2016-12-15 | 2019-10-23 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
CN109207532B (zh) * | 2017-06-29 | 2022-08-12 | 中国石油化工股份有限公司 | 丙烯酰胺水溶液的制造方法 |
WO2019030681A1 (en) | 2017-08-07 | 2019-02-14 | King Abdullah University Of Science And Technology | COMPLEX PROCESSES AND CATALYSTS SUPPORTED FOR OXIDATION AND / OR AMMOXYDATION OF OLEFINS; PROCESS FOR PREPARING THEM |
FR3125064B1 (fr) | 2021-07-09 | 2024-07-12 | Snf Sa | Procédé biologique d’obtention de monomères comprenant une insaturation éthylénique par bioconversion d’un composé biosourcé comprenant au moins une fonction nitrile |
FR3125042B1 (fr) | 2021-07-09 | 2024-04-12 | Snf Sa | Procédé d’obtention d’alkyl(méth)acrylamide substitué biosourcé |
EP4442859A1 (de) | 2023-04-06 | 2024-10-09 | Covestro Deutschland AG | Nachhaltige herstellung von hexamethylendiisocyanat für die produktion von polyurethan |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2417893A (en) * | 1944-10-12 | 1947-03-25 | Sinclair Refining Co | Production of nitriles and amines |
US2520181A (en) * | 1946-08-31 | 1950-08-29 | Sinclair Refining Co | Process of preparing amines and nitriles from ammonia and olefins |
US2481826A (en) * | 1947-02-28 | 1949-09-13 | Allied Chem & Dye Corp | Process for making aliphatic nitriles |
US2496659A (en) * | 1947-07-19 | 1950-02-07 | Socony Vacuum Oil Co Inc | Production of nitriles |
GB709337A (en) * | 1950-12-30 | 1954-05-19 | Distillers Co Yeast Ltd | Manufacture of nitriles |
US2671107A (en) * | 1951-06-26 | 1954-03-02 | Sinclair Refining Co | Catalytic dehydrogenation of aliphatic nitriles |
GB719635A (en) * | 1951-11-08 | 1954-12-08 | Distillers Co Yeast Ltd | Manufacture of substantially pure unsaturated nitriles |
IT494584A (it) * | 1952-10-09 | 1900-01-01 | Distillers Co Yeast Ltd | |
FR1098400A (fr) * | 1953-04-13 | 1955-07-25 | Bataafsche Petroleum | Procédé de préparation des nitriles non saturés |
GB744011A (en) * | 1953-05-07 | 1956-01-25 | Distillers Co Yeast Ltd | Production of unsaturated aliphatic nitriles and catalysts therefor |
-
0
- MX MX67287D patent/MX67287A/es unknown
- CA CA718025A patent/CA718025A/en not_active Expired
- IT IT605134D patent/IT605134A/it unknown
- IT IT801567D patent/IT801567A/it unknown
- MX MX64564D patent/MX64564A/es unknown
- CA CA687664A patent/CA687664A/en not_active Expired
-
1957
- 1957-09-20 US US685352A patent/US2904580A/en not_active Expired - Lifetime
-
1958
- 1958-08-18 GB GB26495/58A patent/GB867438A/en not_active Expired
- 1958-09-11 FR FR774289A patent/FR1222460A/fr not_active Expired
- 1958-09-12 NL NL231326A patent/NL107721C/xx active
- 1958-09-13 BE BE571200D patent/BE571200A/xx unknown
- 1958-09-13 DE DEST14237A patent/DE1127351B/de active Pending
-
1959
- 1959-02-24 US US794841A patent/US3050546A/en not_active Expired - Lifetime
- 1959-03-05 CH CH7038959A patent/CH385192A/fr unknown
-
1960
- 1960-01-29 GB GB3303/60A patent/GB884437A/en not_active Expired
- 1960-02-20 DK DK65260AA patent/DK102906C/da active
- 1960-02-22 BE BE587897D patent/BE587897A/xx unknown
- 1960-02-22 FR FR819209A patent/FR77200E/fr not_active Expired
- 1960-02-23 DE DEST16146A patent/DE1180739B/de active Pending
- 1960-02-24 NL NL248761A patent/NL110666C/xx active
- 1960-02-24 CH CH209160A patent/CH404640A/fr unknown
-
1962
- 1962-12-31 MY MY196220A patent/MY6200020A/xx unknown
-
1963
- 1963-05-09 NL NL292532A patent/NL120493C/xx active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1235297B (de) * | 1959-07-18 | 1967-03-02 | Bayer Ag | Verfahren zur Herstellung von Methacrylsaeurenitril durch Umsetzung von Isobutylen mit Ammoniak und Sauerstoff |
Also Published As
Publication number | Publication date |
---|---|
US3050546A (en) | 1962-08-21 |
FR77200E (fr) | 1962-01-27 |
BE571200A (it) | 1959-03-13 |
MX64564A (it) | |
NL120493C (it) | 1965-12-15 |
DK102906C (da) | 1965-10-25 |
CH404640A (fr) | 1965-12-31 |
DE1127351B (de) | 1962-04-12 |
MX67287A (it) | |
FR1222460A (fr) | 1960-06-10 |
CA687664A (en) | 1964-06-02 |
CH385192A (fr) | 1964-12-15 |
NL107721C (it) | 1964-03-16 |
CA718025A (en) | 1965-09-14 |
IT605134A (it) | |
IT801567A (it) | |
GB884437A (en) | 1961-12-13 |
NL110666C (it) | 1965-02-15 |
MY6200020A (en) | 1962-12-31 |
US2904580A (en) | 1959-09-15 |
GB867438A (en) | 1961-05-10 |
DE1180739B (de) | 1964-11-05 |