BE564772A - - Google Patents
Info
- Publication number
- BE564772A BE564772A BE564772DA BE564772A BE 564772 A BE564772 A BE 564772A BE 564772D A BE564772D A BE 564772DA BE 564772 A BE564772 A BE 564772A
- Authority
- BE
- Belgium
- Prior art keywords
- sep
- polymerization
- mixture
- compounds
- parts
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 8
- 229910001385 heavy metal Inorganic materials 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- 230000000875 corresponding Effects 0.000 claims description 4
- 239000003426 co-catalyst Substances 0.000 claims description 3
- 125000001033 ether group Chemical group 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 150000004292 cyclic ethers Chemical group 0.000 claims description 2
- 230000000737 periodic Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000379 polymerizing Effects 0.000 claims 1
- 229920001098 polystyrene-block-poly(ethylene/propylene) Polymers 0.000 description 63
- -1 polyethylenes Polymers 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 17
- 239000005977 Ethylene Substances 0.000 description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 15
- 150000002430 hydrocarbons Chemical class 0.000 description 15
- 239000000654 additive Substances 0.000 description 13
- 229910010062 TiCl3 Inorganic materials 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000012190 activator Substances 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 230000037048 polymerization activity Effects 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M Diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N Diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene (PE) Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N Tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000008378 aryl ethers Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ONRSPOWNRLCCGF-UHFFFAOYSA-N 2,2-diphenyloxolane Chemical compound C1CCOC1(C=1C=CC=CC=1)C1=CC=CC=C1 ONRSPOWNRLCCGF-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N Bibenzyl Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N Hafnium Chemical class [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- IIMIOEBMYPRQGU-UHFFFAOYSA-L Picoplatin Chemical compound N.[Cl-].[Cl-].[Pt+2].CC1=CC=CC=N1 IIMIOEBMYPRQGU-UHFFFAOYSA-L 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J Titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K Titanium(III) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229910052770 Uranium Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- GKRALBJDXHXFNB-UHFFFAOYSA-N butoxycyclohexane Chemical class CCCCOC1CCCCC1 GKRALBJDXHXFNB-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atoms Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000011651 chromium Chemical class 0.000 description 1
- 230000003247 decreasing Effects 0.000 description 1
- 230000001809 detectable Effects 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N diisopropyl ether Chemical class CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 150000005218 dimethyl ethers Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical class [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Chemical class 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium Chemical class [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- DSNYFFJTZPIKFZ-UHFFFAOYSA-N propoxybenzene Chemical class CCCOC1=CC=CC=C1 DSNYFFJTZPIKFZ-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- ZSLUVFAKFWKJRC-UHFFFAOYSA-N thorium Chemical class [Th] ZSLUVFAKFWKJRC-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical class [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Chemical class 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical class [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical class [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical class [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE564772A true BE564772A (de) |
Family
ID=185519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE564772D BE564772A (de) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE564772A (de) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3219652A (en) * | 1958-09-17 | 1965-11-23 | Gulf Oil Corp | Process of polymerizing ethylene in the presence of a ziegler-type catalyst and a polyether or hydroxyether |
| US3219648A (en) * | 1964-01-08 | 1965-11-23 | Gulf Oil Corp | Polyolefin catalysts and processes |
| US3219650A (en) * | 1958-09-17 | 1965-11-23 | Gulf Oil Corp | Process for the polymerization of diolefins |
| US3317498A (en) * | 1963-01-03 | 1967-05-02 | Phillips Petroleum Co | Aromatic ethers as catalyst adjuvants for production of crystalline polyolefins |
| US3320227A (en) * | 1962-10-22 | 1967-05-16 | Solvay | Catalyst for the polymerization of olefins consisting of tin or lead tetrahydrocarbyls, a transition metal halide, a halide of a metal selected from the third and fifth groups and an ether |
| US3340241A (en) * | 1960-10-24 | 1967-09-05 | Montedison Spa | Process for producing elastomeric copolymers of ethylene with higher alpha-olefins |
| US3369011A (en) * | 1960-10-26 | 1968-02-13 | Montedison Spa | Process for producing amorphous copolymerizates of ethylene and higher alpha-olefin |
| US3441551A (en) * | 1961-05-01 | 1969-04-29 | Avisun Corp | Novel catalyst and olefin polymerization therewith |
| DE1301085B (de) * | 1963-08-27 | 1969-08-14 | California Research Corp | Verfahren zur Herstellung von Mischpolymerisaten aus alpha-Olefinen und ªÏ-Halogen-alpefinen |
| DE1301901B (de) * | 1959-03-02 | 1969-08-28 | Gulf Oil Corp | Verfahren zur Polymerisation von alpha-Olefinen mit mindestens drei Kohlenstoffatomen |
| DE1495054B1 (de) * | 1964-02-21 | 1971-02-04 | Avisun Corp | Verfahren zur Herstellung von in Pentan unloeslichen Blockmischpolymerisaten aus AEthylen und Propylen |
| EP0177841A1 (de) * | 1984-09-26 | 1986-04-16 | Mitsubishi Petrochemical Co., Ltd. | Verfahren zur Herstellung von Olefinpolymeren |
-
0
- BE BE564772D patent/BE564772A/fr unknown
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3219650A (en) * | 1958-09-17 | 1965-11-23 | Gulf Oil Corp | Process for the polymerization of diolefins |
| US3219652A (en) * | 1958-09-17 | 1965-11-23 | Gulf Oil Corp | Process of polymerizing ethylene in the presence of a ziegler-type catalyst and a polyether or hydroxyether |
| DE1301901B (de) * | 1959-03-02 | 1969-08-28 | Gulf Oil Corp | Verfahren zur Polymerisation von alpha-Olefinen mit mindestens drei Kohlenstoffatomen |
| US3340241A (en) * | 1960-10-24 | 1967-09-05 | Montedison Spa | Process for producing elastomeric copolymers of ethylene with higher alpha-olefins |
| US3369011A (en) * | 1960-10-26 | 1968-02-13 | Montedison Spa | Process for producing amorphous copolymerizates of ethylene and higher alpha-olefin |
| US3441551A (en) * | 1961-05-01 | 1969-04-29 | Avisun Corp | Novel catalyst and olefin polymerization therewith |
| US3320227A (en) * | 1962-10-22 | 1967-05-16 | Solvay | Catalyst for the polymerization of olefins consisting of tin or lead tetrahydrocarbyls, a transition metal halide, a halide of a metal selected from the third and fifth groups and an ether |
| US3317498A (en) * | 1963-01-03 | 1967-05-02 | Phillips Petroleum Co | Aromatic ethers as catalyst adjuvants for production of crystalline polyolefins |
| DE1301085B (de) * | 1963-08-27 | 1969-08-14 | California Research Corp | Verfahren zur Herstellung von Mischpolymerisaten aus alpha-Olefinen und ªÏ-Halogen-alpefinen |
| US3219648A (en) * | 1964-01-08 | 1965-11-23 | Gulf Oil Corp | Polyolefin catalysts and processes |
| DE1495054B1 (de) * | 1964-02-21 | 1971-02-04 | Avisun Corp | Verfahren zur Herstellung von in Pentan unloeslichen Blockmischpolymerisaten aus AEthylen und Propylen |
| EP0177841A1 (de) * | 1984-09-26 | 1986-04-16 | Mitsubishi Petrochemical Co., Ltd. | Verfahren zur Herstellung von Olefinpolymeren |
| US4701505A (en) * | 1984-09-26 | 1987-10-20 | Mitsubishi Petrochemical Company Limited | Process for production of olefin polymers |
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