BE557029A - - Google Patents
Info
- Publication number
- BE557029A BE557029A BE557029DA BE557029A BE 557029 A BE557029 A BE 557029A BE 557029D A BE557029D A BE 557029DA BE 557029 A BE557029 A BE 557029A
- Authority
- BE
- Belgium
- Prior art keywords
- emi
- catalyst
- carbon atoms
- titanium tetrachloride
- hydrocarbon
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- -1 polypropylenes Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- JOZGELVITUSFFX-UHFFFAOYSA-N sodium;3-methanidylheptane Chemical compound [Na+].CCCCC([CH2-])CC JOZGELVITUSFFX-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Description
<EMI ID=1.1>
de polypropylènes au moyen d'un catalyseur constitué par un produit de réaction du tétrachlorure de titane avec un ou plusieurs dérivés organiques d'un métal alcalin et d'un hydrocarbure de 2 à 5 atomes de carbone.
Il a été maintenant trouvé que ce catalyseur peut Être obtenu à partir d'un hydrocarbure contenant de 6 à 8 atomes de carbone.
Ce catalyseur se prépare suivant la méthode décrite
<EMI ID=2.1>
Avec'le catalyseur de l'invention, on peut polymériser du polypropylène ou des mélanges gazeux ou liquides contenant du propylène dilué éventuellement par des gaz inertes.
Les produits obtenus ont les mêmes usages et sensiblement les mêmes propriétés que ceux obtenus avec les catalyseurs
<EMI ID=3.1>
Exemple.
On prépare du 2-éthyl-hexylsodium en faisant réagir
<EMI ID=4.1>
ensuite le catalyseur de polymérisation en prenant une solution de 2 g de tétrachlorure de titane dans 150 cm3 de pentane sec.
On y ajoute du 2-éthyl-hexylsodium en quantité correspondant à
1 g de sodium métallique en suspension dans du pentane sec.
Aussitôt que ce mélange est effectué, le tube de fer qui le contient est fermé et raccordé à une bonbonne de propylène.
On maintient une pression de 10 atmosphères et une température de 2090. Après 20 heures, on purge le tube par un courant d'azote. La masse réactionnelle est lavée à l'éthanol acidifié par de l'acide chlorhydrique et ensuite à l'eau. On obtient après séchage sous vide 15 g d'un polymère solide de poids molécu-
<EMI ID=5.1>
linité moyenne Cr = 45%.
Ces constantes sont déterminées comme il est indiqué
<EMI ID=6.1>
10 g de polymères sont extraits à chaud par de l'éther diéthylique. La fraction soluble recueillie pèse 3,4 g. Le poids moléculaire est 'de 32.000,. Le point de fusion n'est pas déterminé à cause de l'état amorphe du produit.
<EMI ID=7.1>
cristallinité Or = 23%.
Il est resté finalement 5,8 g de résidu de poids molé-
<EMI ID=8.1>
<EMI ID = 1.1>
polypropylenes by means of a catalyst consisting of a reaction product of titanium tetrachloride with one or more organic derivatives of an alkali metal and of a hydrocarbon of 2 to 5 carbon atoms.
It has now been found that this catalyst can be obtained from a hydrocarbon containing 6 to 8 carbon atoms.
This catalyst is prepared according to the method described
<EMI ID = 2.1>
With the catalyst of the invention, it is possible to polymerize polypropylene or gas or liquid mixtures containing propylene optionally diluted with inert gases.
The products obtained have the same uses and substantially the same properties as those obtained with the catalysts
<EMI ID = 3.1>
Example.
2-ethyl-hexylsodium is prepared by reacting
<EMI ID = 4.1>
then the polymerization catalyst by taking a solution of 2 g of titanium tetrachloride in 150 cm3 of dry pentane.
2-ethyl-hexylsodium is added to it in an amount corresponding to
1 g of metallic sodium suspended in dry pentane.
As soon as this mixture is carried out, the iron tube which contains it is closed and connected to a propylene cylinder.
A pressure of 10 atmospheres and a temperature of 2090 are maintained. After 20 hours, the tube is purged with a stream of nitrogen. The reaction mass is washed with ethanol acidified with hydrochloric acid and then with water. 15 g of a solid polymer of molecular weight are obtained after drying under vacuum.
<EMI ID = 5.1>
average linearity Cr = 45%.
These constants are determined as indicated
<EMI ID = 6.1>
10 g of polymers are extracted hot with diethyl ether. The soluble fraction collected weighs 3.4 g. The molecular weight is 32,000. The melting point is not determined due to the amorphous state of the product.
<EMI ID = 7.1>
Gold crystallinity = 23%.
In the end, 5.8 g of residue of molecular weight remained.
<EMI ID = 8.1>
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE362232X | 1956-06-08 | ||
| BE270457X | 1957-04-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE557029A true BE557029A (en) |
Family
ID=25661935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE557029D BE557029A (en) | 1956-06-08 |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE557029A (en) |
| CH (1) | CH362232A (en) |
| FR (1) | FR1182300A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009127559A1 (en) * | 2008-04-14 | 2009-10-22 | Basf Se | Soluble sodium alkyls, process for their preparation, and their use as initiators |
-
0
- BE BE557029D patent/BE557029A/fr unknown
-
1957
- 1957-06-04 CH CH362232D patent/CH362232A/en unknown
- 1957-06-07 FR FR1182300D patent/FR1182300A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009127559A1 (en) * | 2008-04-14 | 2009-10-22 | Basf Se | Soluble sodium alkyls, process for their preparation, and their use as initiators |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1182300A (en) | 1959-06-24 |
| CH362232A (en) | 1962-05-31 |
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