AU670076B2 - Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method - Google Patents
Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method Download PDFInfo
- Publication number
- AU670076B2 AU670076B2 AU38080/93A AU3808093A AU670076B2 AU 670076 B2 AU670076 B2 AU 670076B2 AU 38080/93 A AU38080/93 A AU 38080/93A AU 3808093 A AU3808093 A AU 3808093A AU 670076 B2 AU670076 B2 AU 670076B2
- Authority
- AU
- Australia
- Prior art keywords
- solution
- metallic substrate
- activating agent
- acid
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000002253 acid Substances 0.000 title claims abstract description 35
- 239000000758 substrate Substances 0.000 title claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 23
- 230000003213 activating effect Effects 0.000 title claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 title abstract description 15
- 239000002184 metal Substances 0.000 title abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 31
- 239000004593 Epoxy Substances 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 12
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 claims description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 150000003008 phosphonic acid esters Chemical class 0.000 claims description 3
- 240000003550 Eusideroxylon zwageri Species 0.000 claims 1
- SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 claims 1
- 238000000375 direct analysis in real time Methods 0.000 claims 1
- 238000012063 dual-affinity re-targeting Methods 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 17
- 238000011282 treatment Methods 0.000 abstract description 11
- 230000007797 corrosion Effects 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 6
- 239000007921 spray Substances 0.000 abstract description 6
- 239000003599 detergent Substances 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 239000008367 deionised water Substances 0.000 description 13
- 229910021641 deionized water Inorganic materials 0.000 description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 12
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 11
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 10
- 239000011541 reaction mixture Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 238000007654 immersion Methods 0.000 description 8
- NLBSQHGCGGFVJW-UHFFFAOYSA-N 2-carboxyethylphosphonic acid Chemical compound OC(=O)CCP(O)(O)=O NLBSQHGCGGFVJW-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 4
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical class CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 4
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 150000001845 chromium compounds Chemical class 0.000 description 4
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 229940043276 diisopropanolamine Drugs 0.000 description 3
- -1 fluoride compound Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000003009 phosphonic acids Chemical class 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011775 sodium fluoride Substances 0.000 description 2
- 235000013024 sodium fluoride Nutrition 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ASZZHBXPMOVHCU-UHFFFAOYSA-N 3,9-diazaspiro[5.5]undecane-2,4-dione Chemical compound C1C(=O)NC(=O)CC11CCNCC1 ASZZHBXPMOVHCU-UHFFFAOYSA-N 0.000 description 1
- VVXLFFIFNVKFBD-UHFFFAOYSA-N 4,4,4-trifluoro-1-phenylbutane-1,3-dione Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CC=C1 VVXLFFIFNVKFBD-UHFFFAOYSA-N 0.000 description 1
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101100537948 Mus musculus Trir gene Proteins 0.000 description 1
- 229920002732 Polyanhydride Polymers 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical class CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- RXCBCUJUGULOGC-UHFFFAOYSA-H dipotassium;tetrafluorotitanium;difluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Ti+4] RXCBCUJUGULOGC-UHFFFAOYSA-H 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229940104869 fluorosilicate Drugs 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000003178 glass ionomer cement Substances 0.000 description 1
- GBHRVZIGDIUCJB-UHFFFAOYSA-N hydrogenphosphite Chemical class OP([O-])[O-] GBHRVZIGDIUCJB-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- BFXAWOHHDUIALU-UHFFFAOYSA-M sodium;hydron;difluoride Chemical compound F.[F-].[Na+] BFXAWOHHDUIALU-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemically Coating (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/862,143 US5306526A (en) | 1992-04-02 | 1992-04-02 | Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method |
| US862143 | 1992-04-02 | ||
| PCT/US1993/002326 WO1993020258A1 (en) | 1992-04-02 | 1993-03-12 | Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU3808093A AU3808093A (en) | 1993-11-08 |
| AU670076B2 true AU670076B2 (en) | 1996-07-04 |
Family
ID=25337783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU38080/93A Ceased AU670076B2 (en) | 1992-04-02 | 1993-03-12 | Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method |
Country Status (13)
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5294265A (en) * | 1992-04-02 | 1994-03-15 | Ppg Industries, Inc. | Non-chrome passivation for metal substrates |
| DE19654642C2 (de) * | 1996-12-28 | 2003-01-16 | Chemetall Gmbh | Verfahren zur Behandlung metallischer Oberflächen mit einer wässerigen Lösung |
| US6096813A (en) * | 1997-09-24 | 2000-08-01 | Ppg Industries Ohio, Inc. | N-acyl amino acid compositions and their use as adhesion promoters |
| US5858282A (en) * | 1997-11-21 | 1999-01-12 | Ppg Industries, Inc. | Aqueous amine fluoride neutralizing composition for metal pretreatments containing organic resin and method |
| GB9821984D0 (en) * | 1998-10-08 | 1998-12-02 | Thorstone Business Man Ltd | Adhesive promotion |
| US6312812B1 (en) | 1998-12-01 | 2001-11-06 | Ppg Industries Ohio, Inc. | Coated metal substrates and methods for preparing and inhibiting corrosion of the same |
| US6440580B1 (en) | 1998-12-01 | 2002-08-27 | Ppg Industries Ohio, Inc. | Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same |
| US6410926B1 (en) | 1999-10-01 | 2002-06-25 | Ppg Industries Ohio, Inc. | Coating with optical taggent |
| US6488990B1 (en) * | 2000-10-06 | 2002-12-03 | Chemetall Gmbh | Process for providing coatings on a metallic surface |
| US6689831B1 (en) | 2000-11-01 | 2004-02-10 | Mcmillen Mark | Chromium-free, curable coating compositions for metal substrates |
| US6863738B2 (en) * | 2001-01-29 | 2005-03-08 | General Electric Company | Method for removing oxides and coatings from a substrate |
| US6750274B2 (en) | 2001-02-08 | 2004-06-15 | Ppg Industries Ohio. Inc. | Weldable coating of phosphated epoxy polymer, curing agent and electroconductive pigment |
| DE10114980A1 (de) * | 2001-03-27 | 2002-10-17 | Henkel Kgaa | Haftvermittler für Lacke und Klebstoffe auf Metallen |
| US6774168B2 (en) | 2001-11-21 | 2004-08-10 | Ppg Industries Ohio, Inc. | Adhesion promoting surface treatment or surface cleaner for metal substrates |
| US6749939B2 (en) | 2002-02-19 | 2004-06-15 | Ppg Industries, Ohio, Inc. | Composition having sealing and sound dampening properties and methods related thereto |
| US6841251B2 (en) * | 2002-02-19 | 2005-01-11 | Ppg Industries Ohio, Inc. | Composition having sealing and sound dampening properties and methods related thereto |
| US20040086718A1 (en) * | 2002-11-06 | 2004-05-06 | Pawlik Michael J | Corrosion and alkali-resistant compositions and methods for using the same |
| US7147897B2 (en) * | 2002-11-06 | 2006-12-12 | Ppg Industries Ohio, Inc. | Weldable compositions comprising a conductive pigment and silicon and methods for using the same |
| US7345101B2 (en) * | 2002-11-06 | 2008-03-18 | Ppg Industries Ohio, Inc. | Aqueous composition of reaction product of epoxy and phosphorus materials with curing agent |
| US20050043207A1 (en) * | 2003-06-30 | 2005-02-24 | Eric Aubay | Cleaning composition and method for removal of polysilicate residue |
| US7745010B2 (en) | 2005-08-26 | 2010-06-29 | Prc Desoto International, Inc. | Coating compositions exhibiting corrosion resistance properties, related coated substrates, and methods |
| WO2008134308A1 (en) * | 2007-04-27 | 2008-11-06 | Valspar Sourcing, Inc. | Crosslinkable imide polyester coating |
| CA3225412A1 (en) | 2007-10-11 | 2019-12-26 | Implantica Patent Ltd. | Implantable device for external urinary control |
| US8173221B2 (en) * | 2008-03-18 | 2012-05-08 | MCT Research & Development | Protective coatings for metals |
| US20120024703A1 (en) | 2010-07-28 | 2012-02-02 | Ppg Industries Ohio, Inc. | Compositions useful for electrocoating metal substrates and electrodeposition processes using the coatings |
| US8574396B2 (en) | 2010-08-30 | 2013-11-05 | United Technologies Corporation | Hydration inhibitor coating for adhesive bonds |
| US9080004B2 (en) | 2010-10-07 | 2015-07-14 | Prc-Desoto International, Inc. | Diethylene glycol monomethyl ether resistant coating |
| US20130146460A1 (en) | 2011-12-13 | 2013-06-13 | Ppg Industries Ohio, Inc. | Resin based post rinse for improved throwpower of electrodepositable coating compositions on pretreated metal substrates |
| CA2877087C (en) | 2012-06-18 | 2016-08-16 | Ppg Industries Ohio, Inc. | Dual-cure compositions useful for coating metal substrates and processes using the compositions |
| US20140255608A1 (en) | 2013-03-11 | 2014-09-11 | Ppg Industries Ohio, Inc. | Coatings that exhibit a tri-coat appearance, related coating methods and substrates |
| US20150072161A1 (en) | 2013-09-11 | 2015-03-12 | Prc-Desoto International, Inc. | Compositions comprising magnesium oxide and amino acid |
| EP3191302B1 (en) | 2014-09-08 | 2024-03-13 | MCT Holdings LTD | Silicate coatings |
| MX2017013713A (es) * | 2015-05-01 | 2018-03-02 | Novelis Inc | Proceso continuo de tratamiento previo de bobinas. |
| KR20200083652A (ko) | 2015-05-29 | 2020-07-08 | 피알시-데소토 인터내쇼날, 인코포레이티드 | 리튬 실리케이트를 부식 억제제로서 함유하는 경화성 필름-형성 조성물 및 다층 코팅된 금속 기재 |
| US11554385B2 (en) | 2015-11-17 | 2023-01-17 | Ppg Industries Ohio, Inc. | Coated substrates prepared with waterborne sealer and primer compositions |
| US20210292907A1 (en) * | 2016-08-12 | 2021-09-23 | Ppg Industries Ohio, Inc. | Pretreatment Composition |
| US10767073B2 (en) | 2016-10-18 | 2020-09-08 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing hydroxyl functional, branched acrylic polymers and multilayer composite coatings |
| US10370555B2 (en) | 2017-05-16 | 2019-08-06 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing hydroxyl functional acrylic polymers and bisurea compounds and multilayer composite coatings |
| KR102458569B1 (ko) | 2017-07-14 | 2022-10-24 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 반응성 작용성 중합체 및 폴리실록산 수지를 포함하는 경화성 필름-형성 조성물, 다층 복합체 코팅 및 이들의 사용 방법 |
| US10773243B2 (en) | 2017-09-07 | 2020-09-15 | Ppg Industries Ohio, Inc. | Thermolatent catalyst and its use in curable compositions |
| EP3480261A1 (en) | 2017-11-03 | 2019-05-08 | PPG Industries Ohio, Inc. | Aqueous coating compositions and processes of forming multi-component composite coatings on substrates |
| CN111556886B (zh) | 2017-12-22 | 2022-03-22 | Ppg工业俄亥俄公司 | 在外观和流挂控制性能方面提供益处的可热固化的成膜组合物 |
| US20200325289A1 (en) | 2019-04-15 | 2020-10-15 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing rheology modifiers comprising non-aqueous dispersions |
| US20240150587A1 (en) | 2021-03-02 | 2024-05-09 | Prc-Desoto International, Inc. | Corrosion inhibiting coatings comprising aluminum particles, magnesium oxide and an aluminum and/or iron compound |
| CN117098817A (zh) | 2021-03-02 | 2023-11-21 | Prc-迪索托国际公司 | 包括氧化镁和铝或铁化合物的腐蚀抑制涂层 |
| CN117377727A (zh) | 2021-03-05 | 2024-01-09 | Prc-迪索托国际公司 | 包括聚硫化物腐蚀抑制剂的涂层组合物 |
| EP4301817A1 (en) | 2021-03-05 | 2024-01-10 | PRC-Desoto International, Inc. | Corrosion inhibiting coating compositions |
| WO2022251804A1 (en) | 2021-05-25 | 2022-12-01 | Prc-Desoto International, Inc. | Composite structures comprising metal substrates |
| CA3218854A1 (en) | 2021-06-24 | 2022-12-29 | Elizabeth Anne FURAR | Systems and methods for coating multi-layered coated metal substrates |
| WO2024173767A1 (en) | 2023-02-16 | 2024-08-22 | Prc-Desoto International, Inc. | Compositions comprising magnesium oxide and rare earth metal oxide |
| WO2025064081A1 (en) | 2023-09-22 | 2025-03-27 | Ppg Industries Ohio, Inc. | Aqueous dispersions of particles, film-forming compositions and multi-layer coated substrates prepared therefrom, and methods of improving adhesion/cohesion of coating layers in multi-layer coated substrates |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4111722A (en) * | 1976-02-09 | 1978-09-05 | Oxy Metal Industries Corporation | Tannin treatment of aluminum with a fluoride cleaner |
| FR2443514A1 (fr) * | 1978-12-07 | 1980-07-04 | Nihon Parkerizing | Solution de traitement de surface et traitement de surface d'un substrat d'aluminium ou d'alliage d'aluminium |
| AU2884192A (en) * | 1991-10-29 | 1993-06-07 | Henkel Corporation | Treatment for the formation of a corrosion resistant film on metal surfaces |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US630246A (en) * | 1898-09-03 | 1899-08-01 | Frank S Loeb | Preparation of aluminium for electroplating. |
| NL129564C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1960-04-16 | 1900-01-01 | ||
| NL285361A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-11-13 | 1900-01-01 | ||
| US3482951A (en) * | 1967-07-19 | 1969-12-09 | Robertson Co H H | Porcelain enameled aluminum articles |
| FR2060416B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-09-05 | 1973-01-12 | Monsanto Co | |
| US4051110A (en) * | 1971-07-06 | 1977-09-27 | Petrolite Corporation | Methylene phosphonates of polymerized polyalkylenepolyamines |
| GB1441588A (en) * | 1972-10-04 | 1976-07-07 | Unilever Ltd | Rinse composition |
| US4122215A (en) * | 1976-12-27 | 1978-10-24 | Bell Telephone Laboratories, Incorporated | Electroless deposition of nickel on a masked aluminum surface |
| US4180603A (en) * | 1977-01-31 | 1979-12-25 | Oxy Metal Industries Corporation | Coating bath composition and method |
| LU77873A1 (fr) * | 1977-07-29 | 1979-03-26 | Centre Rech Metallurgique | Procede pour la preparation de la surface de produits en acier galvanise |
| GB2032963B (en) * | 1978-10-30 | 1982-09-29 | Dart Ind Inc | Non-chromate conversion coating solutions |
| US4312922A (en) * | 1980-01-11 | 1982-01-26 | Olin Corporation | Lubricated cupreous sheet comprising an organophosphonate layer and process therefor |
| CA1162504A (en) * | 1980-11-25 | 1984-02-21 | Mobuyuki Oda | Treating tin plated steel sheet with composition containing titanium or zirconium compounds |
| US4391652A (en) * | 1982-01-29 | 1983-07-05 | Chemical Systems, Inc. | Surface treatment for aluminum and aluminum alloys |
| GB8308003D0 (en) * | 1983-03-23 | 1983-04-27 | Albright & Wilson | Phosphonates |
| PL143722B1 (en) * | 1984-01-17 | 1988-03-31 | Ici Plc | Milk weighing balance |
| US4786336A (en) * | 1985-03-08 | 1988-11-22 | Amchem Products, Inc. | Low temperature seal for anodized aluminum surfaces |
| JPH0627358B2 (ja) * | 1985-03-11 | 1994-04-13 | 株式会社日立製作所 | 被覆鋼材とその製造方法 |
| GB8507048D0 (en) * | 1985-03-19 | 1985-04-24 | Int Paint Plc | Paint |
| AT386000B (de) * | 1985-06-20 | 1988-06-10 | Vianova Kunstharz Ag | Verfahren zur stabilisierung von aluminiumpigmenten |
| US4735649A (en) * | 1985-09-25 | 1988-04-05 | Monsanto Company | Gametocides |
| US4705703A (en) * | 1986-06-30 | 1987-11-10 | Nalco Chemical Company | Method of preventing corrosion of uncoated aluminum sheet or beverage cans in a brewery pasteurizer water system |
| JPS63109175A (ja) * | 1986-10-27 | 1988-05-13 | Kawasaki Steel Corp | 塗料密着性に優れたりん酸塩処理法 |
| JPS63219587A (ja) * | 1987-03-10 | 1988-09-13 | Kawasaki Steel Corp | 塗料密着性に優れた亜鉛系めつき鋼板の製造方法 |
| US4781984A (en) * | 1987-04-28 | 1988-11-01 | The Dow Chemical Company | Aromatic polyether resins having improved adhesion |
| US4777091A (en) * | 1987-04-28 | 1988-10-11 | The Dow Chemical Company | Metal substrates treated with aminophosphonic acid compounds and products resulting from coating such substrates |
| US4902535A (en) * | 1987-12-31 | 1990-02-20 | Air Products And Chemicals, Inc. | Method for depositing hard coatings on titanium or titanium alloys |
| DE3820650A1 (de) * | 1988-06-18 | 1989-12-21 | Henkel Kgaa | Verfahren zum verdichten von anodisierten oxidschichten auf aluminium und aluminiumlegierungen |
| US5034556A (en) * | 1989-04-03 | 1991-07-23 | Ppg Industries, Inc. | Reaction products of alpha-aminomethylene phosphonic acids and epoxy compounds and their use in coating compositions |
| US4992116A (en) * | 1989-04-21 | 1991-02-12 | Henkel Corporation | Method and composition for coating aluminum |
| US4988396A (en) * | 1989-04-26 | 1991-01-29 | Sanchem, Inc. | Corrosion resistant aluminum coating composition |
-
1992
- 1992-04-02 US US07/862,143 patent/US5306526A/en not_active Expired - Lifetime
-
1993
- 1993-03-12 JP JP5517468A patent/JP2843439B2/ja not_active Expired - Fee Related
- 1993-03-12 DE DE69304902T patent/DE69304902T2/de not_active Expired - Lifetime
- 1993-03-12 ES ES93907494T patent/ES2094533T3/es not_active Expired - Lifetime
- 1993-03-12 WO PCT/US1993/002326 patent/WO1993020258A1/en active IP Right Grant
- 1993-03-12 EP EP93907494A patent/EP0633949B1/en not_active Expired - Lifetime
- 1993-03-12 BR BR9306246A patent/BR9306246A/pt not_active IP Right Cessation
- 1993-03-12 AU AU38080/93A patent/AU670076B2/en not_active Ceased
- 1993-03-12 KR KR1019940703455A patent/KR0160819B1/ko not_active Expired - Fee Related
- 1993-03-12 DK DK93907494.4T patent/DK0633949T3/da active
- 1993-03-12 AT AT93907494T patent/ATE143063T1/de not_active IP Right Cessation
- 1993-03-12 CA CA002130114A patent/CA2130114C/en not_active Expired - Lifetime
- 1993-03-30 MX MX9301812A patent/MX9301812A/es unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4111722A (en) * | 1976-02-09 | 1978-09-05 | Oxy Metal Industries Corporation | Tannin treatment of aluminum with a fluoride cleaner |
| FR2443514A1 (fr) * | 1978-12-07 | 1980-07-04 | Nihon Parkerizing | Solution de traitement de surface et traitement de surface d'un substrat d'aluminium ou d'alliage d'aluminium |
| AU2884192A (en) * | 1991-10-29 | 1993-06-07 | Henkel Corporation | Treatment for the formation of a corrosion resistant film on metal surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| KR0160819B1 (ko) | 1999-01-15 |
| ATE143063T1 (de) | 1996-10-15 |
| EP0633949B1 (en) | 1996-09-18 |
| US5306526A (en) | 1994-04-26 |
| DK0633949T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1997-03-17 |
| DE69304902D1 (de) | 1996-10-24 |
| CA2130114A1 (en) | 1993-10-14 |
| DE69304902T2 (de) | 1997-04-03 |
| ES2094533T3 (es) | 1997-01-16 |
| AU3808093A (en) | 1993-11-08 |
| JP2843439B2 (ja) | 1999-01-06 |
| WO1993020258A1 (en) | 1993-10-14 |
| MX9301812A (es) | 1993-10-01 |
| EP0633949A1 (en) | 1995-01-18 |
| JPH07501585A (ja) | 1995-02-16 |
| CA2130114C (en) | 1999-12-21 |
| KR950701011A (ko) | 1995-02-20 |
| BR9306246A (pt) | 1998-06-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU670076B2 (en) | Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method | |
| EP1997934B1 (en) | Composition for metal surface treatment, metal surface treatment method, and metal material | |
| JP3375611B2 (ja) | 溶接可能被覆金属基板およびその作製および腐食防止方法 | |
| AU676030B2 (en) | Non-chrome passivation for metal substrates | |
| EP0932453B1 (en) | Chromium-free conversion coating and methods of use | |
| EP2223975A1 (en) | Surface-treating aqueous solution and treatment methods for forming corrosion-resistant coating film over zinc or zinc alloy deposit | |
| US4422886A (en) | Surface treatment for aluminum and aluminum alloys | |
| JP2003105554A (ja) | 耐白錆性に優れた表面処理鋼板及びその製造方法 | |
| JPH0215177A (ja) | 高耐食性表面処理鋼板の製造方法 | |
| EP1230422A1 (en) | Process and composition for treating metals | |
| US4391652A (en) | Surface treatment for aluminum and aluminum alloys | |
| JP2006161115A (ja) | 化成処理剤及び表面処理金属 | |
| US6607610B1 (en) | Polyphenolamine composition and method of use | |
| CA2303283C (en) | An aqueous amine fluoride neutralizing composition for metal pretreatments containing organic resin and method for metal pretreatment | |
| US5972433A (en) | Method for treatment of metal substrates using Mannich-derived polyethers | |
| US6248182B1 (en) | Mannich derivatives of epoxy-novolac resins and methods of using the same | |
| WO1995031587A1 (en) | A method for pre-treating aluminum materials prior to painting | |
| JP2554212B2 (ja) | 耐低温チッピング性に優れる自動車用表面処理鋼板 | |
| JP2004197179A (ja) | 非クロム型処理亜鉛系めっき鋼板の製造方法 | |
| JPH0564770A (ja) | 加工後耐食性に優れた有機被覆アルミニウム材料 | |
| MXPA98003016A (en) | Post-rinsing composition without chrome for metallic substrates fosfata | |
| JPH05293433A (ja) | 塗装後の性能に優れる表面処理鋼板 | |
| MXPA01005450A (en) | Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same | |
| JPH09267436A (ja) | ポリオレフィン被覆鋼材 |