AU609425B2 - Copper coated fibers - Google Patents
Copper coated fibers Download PDFInfo
- Publication number
- AU609425B2 AU609425B2 AU80537/87A AU8053787A AU609425B2 AU 609425 B2 AU609425 B2 AU 609425B2 AU 80537/87 A AU80537/87 A AU 80537/87A AU 8053787 A AU8053787 A AU 8053787A AU 609425 B2 AU609425 B2 AU 609425B2
- Authority
- AU
- Australia
- Prior art keywords
- fibers
- copper
- fiber
- bath
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000835 fiber Substances 0.000 title claims description 519
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 204
- 229910052802 copper Inorganic materials 0.000 title claims description 202
- 239000010949 copper Substances 0.000 title claims description 202
- 239000002131 composite material Substances 0.000 claims description 80
- 238000000034 method Methods 0.000 claims description 79
- 238000000576 coating method Methods 0.000 claims description 69
- 238000007747 plating Methods 0.000 claims description 67
- 229910052751 metal Inorganic materials 0.000 claims description 61
- 239000002184 metal Substances 0.000 claims description 60
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 53
- 239000011248 coating agent Substances 0.000 claims description 52
- 229910002804 graphite Inorganic materials 0.000 claims description 43
- 239000010439 graphite Substances 0.000 claims description 43
- 238000000151 deposition Methods 0.000 claims description 41
- 230000008569 process Effects 0.000 claims description 36
- 239000008187 granular material Substances 0.000 claims description 29
- 239000000853 adhesive Substances 0.000 claims description 27
- 230000001070 adhesive effect Effects 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 27
- 239000011159 matrix material Substances 0.000 claims description 27
- 230000008021 deposition Effects 0.000 claims description 25
- 230000001464 adherent effect Effects 0.000 claims description 18
- 229920001169 thermoplastic Polymers 0.000 claims description 17
- 239000004416 thermosoftening plastic Substances 0.000 claims description 17
- 238000003892 spreading Methods 0.000 claims description 15
- 230000007480 spreading Effects 0.000 claims description 15
- 239000011521 glass Substances 0.000 claims description 13
- 230000001235 sensitizing effect Effects 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000012736 aqueous medium Substances 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 5
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004413 injection moulding compound Substances 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 129
- 239000010410 layer Substances 0.000 description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 50
- -1 for example Substances 0.000 description 36
- 239000000203 mixture Substances 0.000 description 32
- 229920000049 Carbon (fiber) Polymers 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 239000004917 carbon fiber Substances 0.000 description 30
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 25
- 239000008367 deionised water Substances 0.000 description 24
- 229910021641 deionized water Inorganic materials 0.000 description 24
- 239000008188 pellet Substances 0.000 description 22
- 239000011162 core material Substances 0.000 description 21
- 238000009713 electroplating Methods 0.000 description 21
- 229920005989 resin Polymers 0.000 description 21
- 239000011347 resin Substances 0.000 description 21
- 238000005054 agglomeration Methods 0.000 description 16
- 230000002776 aggregation Effects 0.000 description 16
- 238000007772 electroless plating Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000000465 moulding Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 238000007731 hot pressing Methods 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 239000010408 film Substances 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 10
- 238000004626 scanning electron microscopy Methods 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 229910000365 copper sulfate Inorganic materials 0.000 description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 7
- 238000007596 consolidation process Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 229920000647 polyepoxide Polymers 0.000 description 7
- 238000004513 sizing Methods 0.000 description 7
- 239000001119 stannous chloride Substances 0.000 description 7
- 235000011150 stannous chloride Nutrition 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 6
- 235000011006 sodium potassium tartrate Nutrition 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 238000010923 batch production Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000012783 reinforcing fiber Substances 0.000 description 5
- 229920005992 thermoplastic resin Polymers 0.000 description 5
- 238000011179 visual inspection Methods 0.000 description 5
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000008098 formaldehyde solution Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000007733 ion plating Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920006254 polymer film Polymers 0.000 description 4
- 239000002952 polymeric resin Substances 0.000 description 4
- 229940074439 potassium sodium tartrate Drugs 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000011800 void material Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- YXOLAZRVSSWPPT-UHFFFAOYSA-N Morin Chemical compound OC1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 YXOLAZRVSSWPPT-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000009388 chemical precipitation Methods 0.000 description 3
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 3
- 235000007708 morin Nutrition 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
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- 238000002360 preparation method Methods 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000009827 uniform distribution Methods 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WJLYQKJAHSRCQL-UHFFFAOYSA-N [Na].CCOC(=S)SCC Chemical compound [Na].CCOC(=S)SCC WJLYQKJAHSRCQL-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
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- 238000005452 bending Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
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- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical group [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
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- 239000011780 sodium chloride Substances 0.000 description 2
- HHURSJAUVYNJBT-UHFFFAOYSA-M sodium;heptadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCOS([O-])(=O)=O HHURSJAUVYNJBT-UHFFFAOYSA-M 0.000 description 2
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- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
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- VYTBPJNGNGMRFH-UHFFFAOYSA-N acetic acid;azane Chemical compound N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O VYTBPJNGNGMRFH-UHFFFAOYSA-N 0.000 description 1
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- KULDXINYXFTXMO-UHFFFAOYSA-N bis(2-chloroethyl) (3-chloro-4-methyl-2-oxochromen-7-yl) phosphate Chemical compound C1=C(OP(=O)(OCCCl)OCCCl)C=CC2=C1OC(=O)C(Cl)=C2C KULDXINYXFTXMO-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
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- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940116901 diethyldithiocarbamate Drugs 0.000 description 1
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 1
- 238000007571 dilatometry Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- MGJURKDLIJVDEO-UHFFFAOYSA-N formaldehyde;hydrate Chemical compound O.O=C MGJURKDLIJVDEO-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000007431 microscopic evaluation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002402 nanowire electron scattering Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000007772 nodular growth Effects 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000765 poly(2-oxazolines) Polymers 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920000379 polypropylene carbonate Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004621 scanning probe microscopy Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VFWRNIOSEGGKQE-UHFFFAOYSA-N thiourea;1,3,5-triazine-2,4,6-triamine Chemical compound NC(N)=S.NC1=NC(N)=NC(N)=N1 VFWRNIOSEGGKQE-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D01F11/127—Metals
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemically Coating (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Woven Fabrics (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US92584286A | 1986-10-31 | 1986-10-31 | |
| US92584186A | 1986-10-31 | 1986-10-31 | |
| US92585186A | 1986-10-31 | 1986-10-31 | |
| US06/925,848 US4808481A (en) | 1986-10-31 | 1986-10-31 | Injection molding granules comprising copper coated fibers |
| US925842 | 1986-10-31 | ||
| US925841 | 1986-10-31 | ||
| US925848 | 1986-10-31 | ||
| US925851 | 1997-09-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU8053787A AU8053787A (en) | 1988-05-05 |
| AU609425B2 true AU609425B2 (en) | 1991-05-02 |
Family
ID=27506007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU80537/87A Ceased AU609425B2 (en) | 1986-10-31 | 1987-10-30 | Copper coated fibers |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0269850A1 (fi) |
| KR (1) | KR880005317A (fi) |
| AU (1) | AU609425B2 (fi) |
| BR (1) | BR8705811A (fi) |
| DK (1) | DK568787A (fi) |
| FI (1) | FI874781A (fi) |
| IL (1) | IL84284A (fi) |
| NO (1) | NO874527L (fi) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5045407A (en) * | 1989-12-22 | 1991-09-03 | General Electric Company | Silicon carbide fiber-reinforced titanium base composites having improved interface properties |
| DE19548422A1 (de) * | 1995-12-22 | 1997-09-11 | Hoechst Ag | Materialverbunde und ihre kontinuierliche Herstellung |
| JP3411774B2 (ja) * | 1997-02-14 | 2003-06-03 | リケンテクノス株式会社 | 導電性樹脂組成物 |
| KR100434443B1 (ko) * | 2001-05-21 | 2004-06-04 | (주)메디텍스 | 섬유원단에 금속을 차등 도금하는 방법 |
| US8137752B2 (en) | 2003-12-08 | 2012-03-20 | Syscom Advanced Materials, Inc. | Method and apparatus for the treatment of individual filaments of a multifilament yarn |
| EP3521492B1 (en) | 2007-07-16 | 2023-11-01 | Micrometal Technologies Inc. | Electrical shielding material composed of metallized stainless steel monofilament yarn |
| ITTO20110531A1 (it) | 2011-06-16 | 2012-12-17 | Telerie D Arte S R L | Sistema per la fabbricazione di fili tessili rivestiti con uno strato di un metallo prezioso, in particolare oro |
| US20140216942A1 (en) * | 2011-09-21 | 2014-08-07 | Applied Nanotech Holdings, Inc. | Carbon-Metal Thermal Management Substrates |
| WO2015057783A1 (en) | 2013-10-17 | 2015-04-23 | Rudinger Richard F | Post-extruded polymeric man-made synthetic fiber with polytetrafluoroethylene (ptfe) |
| US9469923B2 (en) | 2013-10-17 | 2016-10-18 | Richard F. Rudinger | Post-extruded polymeric man-made synthetic fiber with copper |
| US9488609B2 (en) * | 2014-02-06 | 2016-11-08 | The Boeing Company | Determination of anisotropic conduction characteristics |
| CN113372063B (zh) * | 2021-06-23 | 2022-06-07 | 北京民佳混凝土有限公司 | 一种耐热混凝土及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3495940A (en) * | 1967-09-28 | 1970-02-17 | Celanese Corp | Production of high temperature resistant continuous filaments |
| US3550247A (en) * | 1967-02-02 | 1970-12-29 | Courtaulds Ltd | Method for producing a metal composite |
| US4664971A (en) * | 1981-12-30 | 1987-05-12 | N.V. Bekaert S.A. | Plastic article containing electrically conductive fibers |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2877501A (en) * | 1952-12-24 | 1959-03-17 | Fiberfil Corp | Glass-reinforced thermoplastic injection molding compound and injection-molding process employing it |
| US2979424A (en) * | 1953-09-17 | 1961-04-11 | Owens Corning Fiberglass Corp | Metal coated glass fibers and method of making them |
| US2814162A (en) * | 1954-06-25 | 1957-11-26 | Ohio Commw Eng Co | Apparatus for production of metallized and bonded blown glass fibers |
| US3083550A (en) * | 1961-02-23 | 1963-04-02 | Alloyd Corp | Process of coating vitreous filaments |
| FR1589480A (fi) * | 1968-09-25 | 1970-03-31 | ||
| GB1325434A (en) * | 1969-08-14 | 1973-08-01 | Int Research & Dev Co Ltd | Current transfer brush |
| US3676916A (en) * | 1970-01-02 | 1972-07-18 | Monsanto Co | Method for preparing metal molding compositions |
| DE2739179A1 (de) * | 1977-08-31 | 1979-04-12 | Bayer Ag | Metallisiertes fasermaterial |
| DE2820502A1 (de) * | 1978-05-11 | 1979-11-15 | Bayer Ag | Metallisierte aramidfasern |
| DE2820525A1 (de) * | 1978-05-11 | 1979-11-15 | Bayer Ag | Metallisierte polycarbonatfasern |
| DE2937874A1 (de) * | 1979-09-19 | 1981-04-02 | Bayer Ag, 5090 Leverkusen | Vergoldete, metallisierte, textile flaechengebilde, garne und fasern, verfahren zu ihrer herstellung und verwendung des textilgutes bei der absorption und reflexion von mikrowellen |
| DE2944065A1 (de) * | 1979-10-31 | 1981-05-14 | Siemens AG, 1000 Berlin und 8000 München | Stromuebertragungsbuerste mit graphitfolien |
| DE3106506A1 (de) * | 1981-02-21 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Metallisierte kohlenstoffasern und verbundwerkstoffe, die diese fasern enthalten |
| JPS57185685A (en) * | 1981-05-09 | 1982-11-15 | Toho Beslon Co | Brush for electric machine and method of producing same |
| EP0088884B1 (en) * | 1982-03-16 | 1986-09-10 | Electro Metalloid Corporation | Yarns and tows comprising high strength metal coated fibers, process for their production, and uses thereof |
| DE3241513A1 (de) * | 1982-11-10 | 1984-05-10 | Bayer Ag, 5090 Leverkusen | Getemperte rovings, textile flaechengebilde und monofilamente aus vernickelten kohlenstoffasern |
| DE3301669A1 (de) * | 1983-01-20 | 1984-07-26 | Bayer Ag, 5090 Leverkusen | Blitzschutzverbundmaterial |
-
1987
- 1987-10-26 EP EP87115698A patent/EP0269850A1/en not_active Withdrawn
- 1987-10-26 IL IL84284A patent/IL84284A/xx not_active IP Right Cessation
- 1987-10-30 AU AU80537/87A patent/AU609425B2/en not_active Ceased
- 1987-10-30 BR BR8705811A patent/BR8705811A/pt not_active Application Discontinuation
- 1987-10-30 NO NO874527A patent/NO874527L/no unknown
- 1987-10-30 FI FI874781A patent/FI874781A/fi not_active Application Discontinuation
- 1987-10-30 DK DK568787A patent/DK568787A/da not_active Application Discontinuation
- 1987-10-31 KR KR870012197A patent/KR880005317A/ko not_active Application Discontinuation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3550247A (en) * | 1967-02-02 | 1970-12-29 | Courtaulds Ltd | Method for producing a metal composite |
| US3495940A (en) * | 1967-09-28 | 1970-02-17 | Celanese Corp | Production of high temperature resistant continuous filaments |
| US4664971A (en) * | 1981-12-30 | 1987-05-12 | N.V. Bekaert S.A. | Plastic article containing electrically conductive fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| IL84284A (en) | 1992-01-15 |
| NO874527L (no) | 1988-05-02 |
| DK568787A (da) | 1988-05-01 |
| AU8053787A (en) | 1988-05-05 |
| FI874781A (fi) | 1988-05-01 |
| EP0269850A1 (en) | 1988-06-08 |
| IL84284A0 (en) | 1988-03-31 |
| NO874527D0 (no) | 1987-10-30 |
| BR8705811A (pt) | 1988-05-31 |
| FI874781A0 (fi) | 1987-10-30 |
| KR880005317A (ko) | 1988-06-28 |
| DK568787D0 (da) | 1987-10-30 |
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