AU3154597A - Brominated polystyrene having improved thermal stability and color and process for the preparation thereof - Google Patents
Brominated polystyrene having improved thermal stability and color and process for the preparation thereofInfo
- Publication number
- AU3154597A AU3154597A AU31545/97A AU3154597A AU3154597A AU 3154597 A AU3154597 A AU 3154597A AU 31545/97 A AU31545/97 A AU 31545/97A AU 3154597 A AU3154597 A AU 3154597A AU 3154597 A AU3154597 A AU 3154597A
- Authority
- AU
- Australia
- Prior art keywords
- polystyrene
- solution
- bromination
- backbone
- reactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000004793 Polystyrene Substances 0.000 title abstract 11
- 229920002223 polystyrene Polymers 0.000 title abstract 11
- 238000000034 method Methods 0.000 title abstract 2
- 230000031709 bromination Effects 0.000 abstract 3
- 238000005893 bromination reaction Methods 0.000 abstract 3
- 239000000376 reactant Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000026030 halogenation Effects 0.000 abstract 2
- 238000005658 halogenation reaction Methods 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910001507 metal halide Inorganic materials 0.000 abstract 1
- 150000005309 metal halides Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/661,350 US5637650A (en) | 1996-06-14 | 1996-06-14 | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| US08661350 | 1996-06-14 | ||
| PCT/US1997/009598 WO1997047663A1 (en) | 1996-06-14 | 1997-05-30 | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU3154597A true AU3154597A (en) | 1998-01-07 |
Family
ID=24653227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU31545/97A Abandoned AU3154597A (en) | 1996-06-14 | 1997-05-30 | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US5637650A (enExample) |
| EP (1) | EP0906345B1 (enExample) |
| JP (2) | JP2000512328A (enExample) |
| AT (1) | ATE294191T1 (enExample) |
| AU (1) | AU3154597A (enExample) |
| CA (1) | CA2256530C (enExample) |
| DE (1) | DE69733136T2 (enExample) |
| GB (1) | GB2329897B (enExample) |
| WO (1) | WO1997047663A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5882551A (en) * | 1995-04-06 | 1999-03-16 | Ferro Corporation | Brominated syndiotactic polystyrene and the use thereof |
| US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| US6518368B2 (en) | 1996-06-14 | 2003-02-11 | Albemarle Corporation | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
| US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
| US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
| EP0928300B1 (en) * | 1996-09-26 | 2000-05-10 | Albemarle Corporation | Process for brominated styrenic polymers |
| US6133381A (en) * | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
| US6235831B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
| US6521714B2 (en) | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
| US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
| US6221614B1 (en) * | 1997-02-21 | 2001-04-24 | The Regents Of The University Of California | Removal of prions from blood, plasma and other liquids |
| US6146555A (en) * | 1998-01-19 | 2000-11-14 | Ferro Corporation | Brominated copolymer flame retardant additives having improved color characteristics and related method |
| US6313252B1 (en) | 1999-02-04 | 2001-11-06 | The Dow Chemical Company | Functionalized ethylene/vinyl or vinylidene aromatic interpolymers |
| MXPA06013323A (es) * | 2004-05-20 | 2007-02-02 | Albemarle Corp | Polimeros estirenicos anionicos bromados, en forma de pellas y su preparacion y uso. |
| KR20070116239A (ko) * | 2005-03-31 | 2007-12-07 | 알베마를 코포레이션 | 촉매 회수를 이용한 개선된 중합체 할로겐화 공정 |
| EP1896512B1 (en) * | 2005-06-30 | 2016-10-26 | Albemarle Corporation | Brominated styrenic polymers and their preparation |
| CN101341174B (zh) * | 2005-12-21 | 2011-08-31 | 雅宝公司 | 溴化阴离子苯乙烯系聚合物及其制备 |
| CA2657939C (en) | 2006-07-20 | 2015-10-27 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| CN101541495A (zh) * | 2006-11-28 | 2009-09-23 | 雅宝公司 | 将溴化阴离子苯乙烯类聚合物转换成便于储存、运输和使用的更硬并更大的形态 |
| ES2708852T3 (es) * | 2007-06-07 | 2019-04-11 | Albemarle Corp | Aductos, aductos y oligómeros, o aductos, oligómeros y polímeros de bajo peso molecular, y su preparación |
| US8993684B2 (en) | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
| KR101536032B1 (ko) | 2008-06-06 | 2015-07-10 | 알베마를 코포레이션 | 저분자량의 브롬화 중합체, 이들의 제조 방법 및 열가소성 배합물에서 이들의 용도 |
| EP2373697A1 (en) * | 2008-12-02 | 2011-10-12 | Albemarle Corporation | Bromination of telomer mixtures derived from toluene and styrene |
| KR20110110096A (ko) * | 2008-12-02 | 2011-10-06 | 알베마를 코포레이션 | 톨루엔 및 스티렌 유도 텔로머 분포물 및 이로부터 생성되는 브롬화된 난연제 |
| JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
| JP2012510562A (ja) | 2008-12-02 | 2012-05-10 | アルベマール・コーポレーシヨン | 分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用 |
| JP2012525483A (ja) | 2009-05-01 | 2012-10-22 | アルベマール・コーポレーシヨン | ペレット化された低分子量臭素化芳香族ポリマー組成物 |
| JO3059B1 (ar) | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
| JP5848555B2 (ja) * | 2011-09-08 | 2016-01-27 | 三菱エンジニアリングプラスチックス株式会社 | ポリエステル樹脂組成物及び成形体 |
| JP5848556B2 (ja) * | 2011-09-08 | 2016-01-27 | 三菱エンジニアリングプラスチックス株式会社 | ポリエステル樹脂組成物及び成形体 |
| US11021425B2 (en) | 2018-10-12 | 2021-06-01 | International Business Machines Corporation | Polybrominated diphenyl-based flame retardant compounds |
| CN119529143B (zh) * | 2025-01-23 | 2025-04-08 | 山东东信新材料科技股份有限公司 | 一种溴化聚苯乙烯的制备方法 |
Family Cites Families (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1890772A (en) | 1930-01-28 | 1932-12-13 | Du Pont | Chlorination of meta styrene |
| US2199026A (en) | 1937-04-01 | 1940-04-30 | Du Pont | Chlorinated aromatic resins |
| US2823201A (en) | 1952-03-10 | 1958-02-11 | Dow Chemical Co | Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same |
| US3009906A (en) | 1957-05-09 | 1961-11-21 | Dow Chemical Co | Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens |
| US3050476A (en) | 1958-12-08 | 1962-08-21 | Koppers Co Inc | Method of making a self extinguishing expandable polymer of styrene by bromination |
| US3039977A (en) | 1959-12-03 | 1962-06-19 | Koppers Co Inc | Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension |
| US3132045A (en) | 1961-10-26 | 1964-05-05 | Dow Chemical Co | Method of impregnating film materials with ammonium bromide |
| NL128916C (enExample) | 1965-02-18 | 1900-01-01 | ||
| US3506741A (en) | 1966-01-10 | 1970-04-14 | Phillips Petroleum Co | Halogenated polymers and block copolymers produced therefrom |
| US3534012A (en) | 1969-05-01 | 1970-10-13 | Dow Chemical Co | Anionic polymerization of nuclear halogenated styrenes |
| CH584731A5 (enExample) | 1973-12-17 | 1977-02-15 | Ciba Geigy Ag | |
| US3959398A (en) | 1974-06-03 | 1976-05-25 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
| US4028486A (en) | 1974-06-03 | 1977-06-07 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
| US3932542A (en) | 1974-08-26 | 1976-01-13 | Great Lakes Chemical Corporation | Process for preparation of 2,5-dibromo-p-xylene |
| US4178327A (en) | 1974-12-19 | 1979-12-11 | The Dow Chemical Company | Ar-halo-ar(t-alkyl)styrenes and polymers thereof |
| DE2515473C3 (de) | 1975-04-09 | 1987-01-22 | Basf Ag, 6700 Ludwigshafen | Flammwidrige, lineare Polyester |
| CA1054161A (en) | 1975-08-22 | 1979-05-08 | Herbert Naarmann | Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds |
| DE2645711C3 (de) | 1976-10-09 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| DE2703419B1 (de) | 1977-01-28 | 1978-02-02 | Basf Ag | Flammwidrig ausgeruestete polyamid- formmassen |
| FR2413409A1 (fr) * | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
| DE3061057D1 (en) | 1979-05-07 | 1982-12-16 | Ciba Geigy Ag | A process for the preparation of brominated products of polystyrene |
| DE3006448A1 (de) | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen |
| DE3025666C2 (de) | 1980-07-07 | 1983-01-20 | Chemische Fabrik Kalk GmbH, 5000 Köln | Polymeres Pentabromstyrol, Verfahren zur Herstellung und Verwendung |
| US4352909A (en) * | 1980-08-20 | 1982-10-05 | Ferro Corporation | Process for the bromination of polystyrenes |
| US4389517A (en) | 1982-04-02 | 1983-06-21 | The Dow Chemical Company | Hydrogenation of phenylacetylene prior to styrene polymerization |
| US4554326A (en) | 1983-04-01 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4513116A (en) | 1983-04-01 | 1985-04-23 | Exxon Research And Engineering Co. | Process for the manufacture of halogenated polymers |
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| US4548995A (en) | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| JPS6060161A (ja) | 1983-08-08 | 1985-04-06 | ザ ダウ ケミカル カンパニ− | 重合体の処理中に放出されたハロゲンおよび酸の中和方法 |
| EP0150332A3 (en) | 1983-12-26 | 1987-08-19 | Mitsubishi Kasei Corporation | Process for producing a chloromethylated polymer |
| JPS6134723A (ja) | 1984-07-26 | 1986-02-19 | Teijin Ltd | 磁気記録媒体及びその製造法 |
| US4650832A (en) | 1984-09-17 | 1987-03-17 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| EP0201411A3 (en) * | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Brominated polymers of alkenyl aromatic compounds |
| IL79499A0 (en) | 1986-07-23 | 1986-10-31 | Yeda Res & Dev | Production of crystalline tribromostyrene |
| JP2543510B2 (ja) | 1986-12-12 | 1996-10-16 | 三菱瓦斯化学株式会社 | 難燃性ポリアミド樹脂組成物 |
| US4879353A (en) | 1987-01-28 | 1989-11-07 | Great Lakes Chemical Corporation | Bromination of polystyrene using bromine as the reaction solvent |
| DE3779747T2 (de) * | 1987-01-28 | 1993-01-07 | Great Lakes Chemical Corp | Aromatische bromierung von polystyrol mit einer bromverbindung als reaktionsloesungsmittel. |
| US4835222A (en) | 1987-02-19 | 1989-05-30 | The Dow Chemical Company | Alkylation of vinyl aromatic polymer |
| US4832873A (en) | 1987-10-09 | 1989-05-23 | Great Lakes Chemical Corporation | Process for producing polybrominated higher alkylbenzenes |
| JPH02215807A (ja) | 1989-02-17 | 1990-08-28 | Nippon Kayaku Co Ltd | 臭素化ポリスチレンの製造方法 |
| JPH0320708A (ja) | 1989-03-03 | 1991-01-29 | Olympus Optical Co Ltd | 自動合焦装置 |
| NL8901054A (nl) | 1989-04-27 | 1990-11-16 | Gen Electric | Polymeermengsel met polyester, glasvezels, vlamvertragend middel en vulmiddel; daaruit gevormde voorwerpen. |
| US5112896A (en) | 1989-06-06 | 1992-05-12 | Ferro Corporation | High-impact polystyrene containing low molecular weight brominated polystyrene |
| US5112897A (en) | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| US5112898A (en) | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| WO1991013915A1 (en) * | 1990-03-16 | 1991-09-19 | Great Lakes Chemical Corporation | Process for purifying brominated polystyrene |
| US5194482A (en) | 1990-08-23 | 1993-03-16 | Ferro Corporation | Flame retardant resin composition containing styrenic polymers |
| US5235000A (en) | 1990-12-10 | 1993-08-10 | Ethyl Corporation | Preparation, storage, and usage of bromine chloride |
| IL99130A (en) | 1991-08-08 | 1998-04-05 | Bromine Compounds Ltd | Preparation of tribromo (B) bromoethyl (benzene in a high degree of purity) |
| JP3020708B2 (ja) | 1992-02-07 | 2000-03-15 | 帝人株式会社 | ポリエチレンテレフタレート樹脂組成物 |
| JP2718851B2 (ja) | 1992-04-07 | 1998-02-25 | 帝人化成株式会社 | ブロモ化スチレンの乳化重合法 |
| US5326837A (en) | 1992-11-20 | 1994-07-05 | Mobil Oil Corporation | Catalyst systems for syndiospecific polymerization of styrenes |
| JP3359695B2 (ja) | 1993-05-14 | 2002-12-24 | 帝人化成株式会社 | ポリスチレン臭素化反応溶液の精製方法 |
| JP3359698B2 (ja) | 1993-06-15 | 2002-12-24 | 帝人化成株式会社 | 臭素化ポリスチレンの製造方法 |
| US5304618A (en) * | 1993-07-22 | 1994-04-19 | Great Lakes Chemical Corporation | Polymers of brominated styrene |
| JP3471086B2 (ja) | 1994-08-12 | 2003-11-25 | 帝人化成株式会社 | 臭素化ポリスチレンの製造方法 |
| IT1271048B (it) * | 1994-10-27 | 1997-05-26 | Caffaro Spa Ind Chim | Procedimento per la preparazione di polimeri alifatici clorurati |
| CN1076366C (zh) | 1995-03-10 | 2001-12-19 | 钟渊化学工业株式会社 | 阻燃性聚对苯二甲酸乙二醇酯类树脂组合物 |
| JPH11503475A (ja) * | 1995-04-06 | 1999-03-26 | フェロー コーポレイション | シンジオタクティック形臭化スチレン重合体並びにその製造及び使用方法 |
| JPH0977937A (ja) | 1995-09-12 | 1997-03-25 | Idemitsu Petrochem Co Ltd | プリント配線板用プリプレグ及びプリント配線用基板 |
| US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
| US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
| US5723549A (en) | 1996-06-14 | 1998-03-03 | Ferro Corporation | Process for the preparation of brominated polystyrene having improved color characteristics |
| EP0928300B1 (en) | 1996-09-26 | 2000-05-10 | Albemarle Corporation | Process for brominated styrenic polymers |
| US5767203A (en) | 1996-09-26 | 1998-06-16 | Albemarle Corporation | Process for brominated styrenic polymers |
| US5677390A (en) | 1996-09-26 | 1997-10-14 | Albemarle Corporation | Process for brominating polystyrenic resins |
| US5686538A (en) | 1996-09-26 | 1997-11-11 | Albemarle Corporation | Process for brominating polystyrenic resins |
| JPH10130325A (ja) | 1996-10-31 | 1998-05-19 | Teijin Chem Ltd | ハロゲン化されたスチレン重合物の製法 |
| DE69832913T2 (de) | 1997-05-07 | 2006-09-14 | Albemarle Corp. | Bromierte Polystyrolharze |
-
1996
- 1996-06-14 US US08/661,350 patent/US5637650A/en not_active Expired - Lifetime
-
1997
- 1997-02-07 US US08/796,277 patent/US5726252A/en not_active Ceased
- 1997-05-30 DE DE69733136T patent/DE69733136T2/de not_active Revoked
- 1997-05-30 GB GB9827416A patent/GB2329897B/en not_active Expired - Fee Related
- 1997-05-30 WO PCT/US1997/009598 patent/WO1997047663A1/en not_active Ceased
- 1997-05-30 EP EP97926887A patent/EP0906345B1/en not_active Revoked
- 1997-05-30 AT AT97926887T patent/ATE294191T1/de not_active IP Right Cessation
- 1997-05-30 CA CA002256530A patent/CA2256530C/en not_active Expired - Fee Related
- 1997-05-30 JP JP10501668A patent/JP2000512328A/ja active Pending
- 1997-05-30 AU AU31545/97A patent/AU3154597A/en not_active Abandoned
-
1999
- 1999-07-19 US US09/356,734 patent/USRE37902E1/en not_active Expired - Lifetime
-
2008
- 2008-02-12 JP JP2008030178A patent/JP2008133484A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP0906345A1 (en) | 1999-04-07 |
| US5726252A (en) | 1998-03-10 |
| GB2329897A (en) | 1999-04-07 |
| GB2329897B (en) | 2001-01-10 |
| WO1997047663A1 (en) | 1997-12-18 |
| JP2008133484A (ja) | 2008-06-12 |
| GB9827416D0 (en) | 1999-02-03 |
| DE69733136T2 (de) | 2006-03-02 |
| ATE294191T1 (de) | 2005-05-15 |
| USRE37902E1 (en) | 2002-11-05 |
| DE69733136D1 (de) | 2005-06-02 |
| JP2000512328A (ja) | 2000-09-19 |
| CA2256530C (en) | 2006-09-12 |
| CA2256530A1 (en) | 1997-12-18 |
| EP0906345B1 (en) | 2005-04-27 |
| US5637650A (en) | 1997-06-10 |
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