AU2011278216A1 - Miniature reference electrode - Google Patents
Miniature reference electrode Download PDFInfo
- Publication number
- AU2011278216A1 AU2011278216A1 AU2011278216A AU2011278216A AU2011278216A1 AU 2011278216 A1 AU2011278216 A1 AU 2011278216A1 AU 2011278216 A AU2011278216 A AU 2011278216A AU 2011278216 A AU2011278216 A AU 2011278216A AU 2011278216 A1 AU2011278216 A1 AU 2011278216A1
- Authority
- AU
- Australia
- Prior art keywords
- electrolyte
- electrode
- membrane
- acid
- reference electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000012528 membrane Substances 0.000 claims abstract description 63
- 239000003792 electrolyte Substances 0.000 claims abstract description 56
- 229920000767 polyaniline Polymers 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 6
- 150000002500 ions Chemical class 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims 1
- 229920005596 polymer binder Polymers 0.000 abstract 1
- 239000002491 polymer binding agent Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 229910052709 silver Inorganic materials 0.000 description 6
- 239000004332 silver Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229920001410 Microfiber Polymers 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 239000003658 microfiber Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000557 Nafion® Polymers 0.000 description 4
- 229910021607 Silver chloride Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 3
- 229910000367 silver sulfate Inorganic materials 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WZTQWXKHLAJTRC-UHFFFAOYSA-N benzyl 2-amino-6,7-dihydro-4h-[1,3]thiazolo[5,4-c]pyridine-5-carboxylate Chemical compound C1C=2SC(N)=NC=2CCN1C(=O)OCC1=CC=CC=C1 WZTQWXKHLAJTRC-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 238000001566 impedance spectroscopy Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910000457 iridium oxide Inorganic materials 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/301—Reference electrodes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Fuel Cell (AREA)
- Secondary Cells (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1003007A FR2962806B1 (fr) | 2010-07-16 | 2010-07-16 | Electrode de reference miniature |
| FR1003007 | 2010-07-16 | ||
| PCT/FR2011/000416 WO2012007660A1 (fr) | 2010-07-16 | 2011-07-12 | Electrode de reference miniature |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2011278216A1 true AU2011278216A1 (en) | 2013-02-07 |
Family
ID=43629484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2011278216A Abandoned AU2011278216A1 (en) | 2010-07-16 | 2011-07-12 | Miniature reference electrode |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20130105308A1 (https=) |
| EP (1) | EP2593781B1 (https=) |
| JP (1) | JP5758490B2 (https=) |
| CN (1) | CN103119428B (https=) |
| AU (1) | AU2011278216A1 (https=) |
| BR (1) | BR112013001139A2 (https=) |
| ES (1) | ES2461542T3 (https=) |
| FR (1) | FR2962806B1 (https=) |
| WO (1) | WO2012007660A1 (https=) |
| ZA (1) | ZA201300208B (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6344682B2 (ja) * | 2014-03-27 | 2018-06-20 | 国立大学法人北海道大学 | 平板型三電極式電気化学センサ及びその製造方法 |
| EP3213360A4 (en) * | 2014-10-29 | 2018-06-20 | pHase2 Microtechnologies Inc. | Polymeric electrode films |
| PE20221207A1 (es) * | 2019-11-08 | 2022-08-11 | Commw Scient Ind Res Org | Electrodo de referencia de estado solido resistente a las interferencias |
| US11549882B2 (en) * | 2020-02-21 | 2023-01-10 | The Regents Of The University Of Michigan | Reference electrode and electrochemical monitoring system |
| US11973200B2 (en) * | 2020-12-04 | 2024-04-30 | GM Global Technology Operations LLC | Reference electrode assembly and method of manufacturing the same |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6475956A (en) * | 1987-09-18 | 1989-03-22 | Bridgestone Corp | Enzyme electrode |
| US5316649A (en) * | 1991-03-05 | 1994-05-31 | The United States Of America As Represented By The United States Department Of Energy | High frequency reference electrode |
| US5250163A (en) * | 1991-11-27 | 1993-10-05 | The Ohio State University Research Foundation | Proton concentration sensor/modulator for sulfonated and hydroxylated polyaniline electrodes |
| JPH07229868A (ja) * | 1994-02-21 | 1995-08-29 | Matsushita Electric Works Ltd | 参照電極 |
| WO2000066652A1 (en) * | 1999-04-30 | 2000-11-09 | University Of Connecticut | Membranes, membrane electrode assemblies and fuel cells employing same, and process for preparing |
| JP2001004581A (ja) * | 1999-06-24 | 2001-01-12 | Sentan Kagaku Gijutsu Incubation Center:Kk | 微小参照電極 |
| JP3906071B2 (ja) * | 2000-12-27 | 2007-04-18 | 日東電工株式会社 | 導電性ポリアニリン組成物、そのフィルム及びそれらの製造方法 |
| US6863800B2 (en) * | 2002-02-01 | 2005-03-08 | Abbott Laboratories | Electrochemical biosensor strip for analysis of liquid samples |
| CA2486790A1 (en) * | 2002-05-23 | 2003-12-04 | Columbian Chemicals Company | Sulfonated conducting polymer-grafted carbon material for fuel cell applications |
| US8728289B2 (en) * | 2005-12-15 | 2014-05-20 | Medtronic, Inc. | Monolithic electrodes and pH transducers |
| ATE546852T1 (de) * | 2007-01-22 | 2012-03-15 | Commissariat Energie Atomique | Referenzelektrode, herstellungsverfahren und batterie damit |
| US20100033160A1 (en) * | 2008-08-09 | 2010-02-11 | Nikolai Kocherginsky | Measurements of Redox Potential and Concentration of Redox Active Substances |
-
2010
- 2010-07-16 FR FR1003007A patent/FR2962806B1/fr not_active Expired - Fee Related
-
2011
- 2011-07-12 AU AU2011278216A patent/AU2011278216A1/en not_active Abandoned
- 2011-07-12 BR BR112013001139A patent/BR112013001139A2/pt not_active IP Right Cessation
- 2011-07-12 ES ES11749465.8T patent/ES2461542T3/es active Active
- 2011-07-12 CN CN201180044160.0A patent/CN103119428B/zh not_active Expired - Fee Related
- 2011-07-12 EP EP11749465.8A patent/EP2593781B1/fr not_active Not-in-force
- 2011-07-12 JP JP2013519125A patent/JP5758490B2/ja not_active Expired - Fee Related
- 2011-07-12 US US13/809,831 patent/US20130105308A1/en not_active Abandoned
- 2011-07-12 WO PCT/FR2011/000416 patent/WO2012007660A1/fr not_active Ceased
-
2013
- 2013-01-09 ZA ZA2013/00208A patent/ZA201300208B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2962806B1 (fr) | 2012-09-28 |
| CN103119428B (zh) | 2014-11-26 |
| EP2593781A1 (fr) | 2013-05-22 |
| BR112013001139A2 (pt) | 2016-05-17 |
| JP2013531252A (ja) | 2013-08-01 |
| US20130105308A1 (en) | 2013-05-02 |
| FR2962806A1 (fr) | 2012-01-20 |
| WO2012007660A9 (fr) | 2012-03-22 |
| JP5758490B2 (ja) | 2015-08-05 |
| WO2012007660A1 (fr) | 2012-01-19 |
| EP2593781B1 (fr) | 2014-04-09 |
| ZA201300208B (en) | 2013-09-25 |
| ES2461542T3 (es) | 2014-05-20 |
| CN103119428A (zh) | 2013-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK4 | Application lapsed section 142(2)(d) - no continuation fee paid for the application |