AU2005292828B2 - Method and apparatus for producing synthesis gas - Google Patents
Method and apparatus for producing synthesis gas Download PDFInfo
- Publication number
- AU2005292828B2 AU2005292828B2 AU2005292828A AU2005292828A AU2005292828B2 AU 2005292828 B2 AU2005292828 B2 AU 2005292828B2 AU 2005292828 A AU2005292828 A AU 2005292828A AU 2005292828 A AU2005292828 A AU 2005292828A AU 2005292828 B2 AU2005292828 B2 AU 2005292828B2
- Authority
- AU
- Australia
- Prior art keywords
- reactor
- low temperature
- steam reforming
- gas
- temperature steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000003786 synthesis reaction Methods 0.000 title claims description 39
- 230000015572 biosynthetic process Effects 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 13
- 239000007789 gas Substances 0.000 claims description 109
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 68
- 238000007254 oxidation reaction Methods 0.000 claims description 56
- 230000003647 oxidation Effects 0.000 claims description 48
- 238000000629 steam reforming Methods 0.000 claims description 48
- 230000003197 catalytic effect Effects 0.000 claims description 47
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 40
- 239000001301 oxygen Substances 0.000 claims description 40
- 229910052760 oxygen Inorganic materials 0.000 claims description 40
- 229930195733 hydrocarbon Natural products 0.000 claims description 33
- 150000002430 hydrocarbons Chemical class 0.000 claims description 33
- 229910052799 carbon Inorganic materials 0.000 claims description 32
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 31
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 19
- 239000003345 natural gas Substances 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 238000006477 desulfuration reaction Methods 0.000 claims description 12
- 230000023556 desulfurization Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 5
- -1 or naphtha Substances 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 239000003915 liquefied petroleum gas Substances 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 description 27
- 238000002485 combustion reaction Methods 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-BJUDXGSMSA-N oxygen-15 atom Chemical compound [15O] QVGXLLKOCUKJST-BJUDXGSMSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004298971A JP4781652B2 (ja) | 2004-10-13 | 2004-10-13 | 合成ガスの製法および製造装置 |
| JP2004-298971 | 2004-10-13 | ||
| PCT/JP2005/018880 WO2006041133A1 (ja) | 2004-10-13 | 2005-10-13 | 合成ガスの製法および製造装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2005292828A1 AU2005292828A1 (en) | 2006-04-20 |
| AU2005292828B2 true AU2005292828B2 (en) | 2010-12-16 |
Family
ID=36148420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2005292828A Ceased AU2005292828B2 (en) | 2004-10-13 | 2005-10-13 | Method and apparatus for producing synthesis gas |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7867411B2 (enExample) |
| EP (1) | EP1808409A4 (enExample) |
| JP (1) | JP4781652B2 (enExample) |
| AU (1) | AU2005292828B2 (enExample) |
| BR (1) | BRPI0516111A (enExample) |
| WO (1) | WO2006041133A1 (enExample) |
| ZA (1) | ZA200703432B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070237710A1 (en) * | 2006-04-05 | 2007-10-11 | Genkin Eugene S | Reforming apparatus and method for syngas generation |
| AU2008242937A1 (en) * | 2007-04-18 | 2008-10-30 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Hydrogen production process |
| NZ560757A (en) * | 2007-10-28 | 2010-07-30 | Lanzatech New Zealand Ltd | Improved carbon capture in microbial fermentation of industrial gases to ethanol |
| US8617270B2 (en) * | 2008-12-03 | 2013-12-31 | Kellogg Brown & Root Llc | Systems and methods for improving ammonia synthesis efficiency |
| US20100187479A1 (en) * | 2009-01-23 | 2010-07-29 | Carbona Oy | Process and apparatus for reforming of heavy and light hydrocarbons from product gas of biomass gasification |
| US20100327231A1 (en) * | 2009-06-26 | 2010-12-30 | Noah Whitmore | Method of producing synthesis gas |
| ITMI20131564A1 (it) * | 2013-09-23 | 2015-03-24 | Rivoira S P A | Sistema per la generazione di endogas |
| MY177060A (en) * | 2014-04-08 | 2020-09-03 | Haldor Tops?E As | A process for heating an atr |
| RU2664063C1 (ru) * | 2017-08-08 | 2018-08-14 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ переработки природного/попутного газа в синтез-газ автотермическим риформингом |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61122102A (ja) * | 1984-11-20 | 1986-06-10 | Jgc Corp | 炭化水素の水蒸気改質法 |
| JPH06219706A (ja) * | 1993-01-26 | 1994-08-09 | Mitsubishi Gas Chem Co Inc | 断熱リホーマー反応器 |
| US6110979A (en) * | 1997-12-23 | 2000-08-29 | Air Products And Chemicals, Inc. | Utilization of synthesis gas produced by mixed conducting membranes |
| JP2004203722A (ja) * | 2002-12-25 | 2004-07-22 | Tongrae Cho | 天然ガス改質方法及び天然ガス改質装置 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2942958A (en) * | 1953-07-03 | 1960-06-28 | Kellogg M W Co | Process for the conversion of a normally gaseous hydrocarbon to carbon monoxide and hydrogen |
| US3264066A (en) * | 1962-05-01 | 1966-08-02 | Pullman Inc | Production of hydrogen |
| JPH10273301A (ja) * | 1997-03-28 | 1998-10-13 | Daido Hoxan Inc | 水素製造装置 |
| US6267912B1 (en) * | 1997-04-25 | 2001-07-31 | Exxon Research And Engineering Co. | Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas |
| GB9714744D0 (en) * | 1997-07-15 | 1997-09-17 | Ici Plc | Methanol |
| DE69925052T2 (de) * | 1998-01-21 | 2006-03-02 | Haldor Topsoe A/S | Verfahren zur Herstellung von wasserstoffreichem Gas |
| DK173897B1 (da) * | 1998-09-25 | 2002-02-04 | Topsoe Haldor As | Fremgangsmåde til autotermisk reforming af et carbonhydridfødemateriale indeholdende højere carbonhydrider |
| US6221280B1 (en) * | 1998-10-19 | 2001-04-24 | Alliedsignal Inc. | Catalytic partial oxidation of hydrocarbon fuels to hydrogen and carbon monoxide |
| US6726850B1 (en) * | 2000-01-14 | 2004-04-27 | Sebastian C. Reyes | Catalytic partial oxidation using staged oxygen addition |
| AU2001236974A1 (en) * | 2000-02-15 | 2001-08-27 | Syntroleum Corporation | System and method for preparing a synthesis gas stream and converting hydrocarbons |
| US20040077496A1 (en) * | 2002-07-26 | 2004-04-22 | Shizhong Zhao | Catalyst |
| US6977067B2 (en) * | 2003-02-12 | 2005-12-20 | Engelhard Corporation | Selective removal of olefins from hydrocarbon feed streams |
| AU2003903283A0 (en) * | 2003-06-26 | 2003-07-10 | H.A.C. Technologies Pty Ltd | Reformate assisted combustion |
| US7449167B2 (en) * | 2004-07-08 | 2008-11-11 | Air Products And Chemicals, Inc. | Catalyst and process for improving the adiabatic steam-reforming of natural gas |
| US7261751B2 (en) * | 2004-08-06 | 2007-08-28 | Conocophillips Company | Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile |
| US7585339B2 (en) * | 2004-09-15 | 2009-09-08 | Haldor Topsoe A/S | Process for reforming ethanol to hydrogen-rich products |
-
2004
- 2004-10-13 JP JP2004298971A patent/JP4781652B2/ja not_active Expired - Fee Related
-
2005
- 2005-10-13 US US11/577,152 patent/US7867411B2/en not_active Expired - Fee Related
- 2005-10-13 WO PCT/JP2005/018880 patent/WO2006041133A1/ja not_active Ceased
- 2005-10-13 EP EP05793616A patent/EP1808409A4/en not_active Withdrawn
- 2005-10-13 AU AU2005292828A patent/AU2005292828B2/en not_active Ceased
- 2005-10-13 BR BRPI0516111-8A patent/BRPI0516111A/pt not_active IP Right Cessation
-
2007
- 2007-04-26 ZA ZA200703432A patent/ZA200703432B/xx unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61122102A (ja) * | 1984-11-20 | 1986-06-10 | Jgc Corp | 炭化水素の水蒸気改質法 |
| JPH06219706A (ja) * | 1993-01-26 | 1994-08-09 | Mitsubishi Gas Chem Co Inc | 断熱リホーマー反応器 |
| US6110979A (en) * | 1997-12-23 | 2000-08-29 | Air Products And Chemicals, Inc. | Utilization of synthesis gas produced by mixed conducting membranes |
| JP2004203722A (ja) * | 2002-12-25 | 2004-07-22 | Tongrae Cho | 天然ガス改質方法及び天然ガス改質装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006041133A1 (ja) | 2006-04-20 |
| US20070295937A1 (en) | 2007-12-27 |
| JP2006111477A (ja) | 2006-04-27 |
| EP1808409A4 (en) | 2011-05-18 |
| JP4781652B2 (ja) | 2011-09-28 |
| EP1808409A1 (en) | 2007-07-18 |
| ZA200703432B (en) | 2008-08-27 |
| US7867411B2 (en) | 2011-01-11 |
| BRPI0516111A (pt) | 2008-08-26 |
| AU2005292828A1 (en) | 2006-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |