AU2005286955B2 - Reactor and process for steam reforming - Google Patents

Reactor and process for steam reforming Download PDF

Info

Publication number
AU2005286955B2
AU2005286955B2 AU2005286955A AU2005286955A AU2005286955B2 AU 2005286955 B2 AU2005286955 B2 AU 2005286955B2 AU 2005286955 A AU2005286955 A AU 2005286955A AU 2005286955 A AU2005286955 A AU 2005286955A AU 2005286955 B2 AU2005286955 B2 AU 2005286955B2
Authority
AU
Australia
Prior art keywords
membrane
hydrogen
tube
gas
distributed combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2005286955A
Other languages
English (en)
Other versions
AU2005286955A1 (en
Inventor
Erik Edwin Engwall
Yi Hua Ma
Ivan Pietrovich Mardilovich
Andreas Nicholas Matzakos
Scott Lee Wellington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Worcester Polytechnic Institute
Original Assignee
Worcester Polytechnic Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Worcester Polytechnic Institute filed Critical Worcester Polytechnic Institute
Publication of AU2005286955A1 publication Critical patent/AU2005286955A1/en
Application granted granted Critical
Publication of AU2005286955B2 publication Critical patent/AU2005286955B2/en
Assigned to WORCESTER POLYTECHNIC INSTITUTE reassignment WORCESTER POLYTECHNIC INSTITUTE Alteration of Name(s) of Applicant(s) under S113 Assignors: WORCESTER POLYTECHIC INSTITUTE
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02232—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C01B3/505—Membranes containing palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Electrochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
AU2005286955A 2004-09-21 2005-09-19 Reactor and process for steam reforming Ceased AU2005286955B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US61168204P 2004-09-21 2004-09-21
US60/611,682 2004-09-21
PCT/US2005/033295 WO2006034103A1 (en) 2004-09-21 2005-09-19 Reactor and process for steam reforming

Publications (2)

Publication Number Publication Date
AU2005286955A1 AU2005286955A1 (en) 2006-03-30
AU2005286955B2 true AU2005286955B2 (en) 2009-06-11

Family

ID=35677491

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2005286955A Ceased AU2005286955B2 (en) 2004-09-21 2005-09-19 Reactor and process for steam reforming

Country Status (7)

Country Link
EP (1) EP1791631A1 (https=)
JP (1) JP2008513339A (https=)
AU (1) AU2005286955B2 (https=)
CA (1) CA2580279A1 (https=)
NO (1) NO20071531L (https=)
TW (1) TW200624376A (https=)
WO (1) WO2006034103A1 (https=)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITPG20060028A1 (it) * 2006-04-18 2006-07-18 Leonardo Valentini Apparecchiatura per la scissione termofisica catalitica dell'ammoniaca liquida nei costituenti azoto ed idrogeno allo stato gassoso
JP4805735B2 (ja) * 2006-06-29 2011-11-02 Ｊｘ日鉱日石エネルギー株式会社 間接内部改質型固体酸化物形燃料電池
JP4805736B2 (ja) * 2006-06-29 2011-11-02 Ｊｘ日鉱日石エネルギー株式会社 間接内部改質型固体酸化物形燃料電池
ES2476801T3 (es) * 2007-02-20 2014-07-15 Shell Internationale Research Maatschappij B.V. Un método para reacondicionar una membrana de separación de gases
US8048199B2 (en) 2007-02-20 2011-11-01 Shell Oil Company Method of making a leak stable gas separation membrane system
FR2914395B1 (fr) * 2007-03-30 2009-11-20 Inst Francais Du Petrole Nouveau reacteur echangeur compact utilisant un bruleur poreux
JP2010523315A (ja) 2007-04-05 2010-07-15 ウスター ポリテクニック インスティチュート 多孔質アノード酸化層を有する複合構造および製造方法
EP2103586A1 (en) 2008-03-20 2009-09-23 Bp Oil International Limited Process for converting methane into ethane in a membrane reactor
WO2011075845A1 (en) * 2009-12-22 2011-06-30 Airscience Technologies System and process for the production of hydrogen from raw gas using a nanoparticle ceria based catalyst
EP2552571B1 (en) 2010-03-26 2018-12-26 Shell Oil Company Method for forming a supported gas separation membrane
US8652239B2 (en) 2010-05-03 2014-02-18 Worcester Polytechnic Institute High permeance sulfur tolerant Pd/Cu alloy membranes
WO2012073783A1 (ja) * 2010-12-01 2012-06-07 Jx日鉱日石金属株式会社 Ｐｄ又はＰｄを主成分とする合金の表面処理剤、及び銅表面の表面皮膜層構造
JP5672548B2 (ja) * 2011-04-07 2015-02-18 有限会社アイエンジ 水素回収装置
JP5850329B2 (ja) * 2012-02-28 2016-02-03 株式会社リコー 流体浄化装置
DE102012016561B4 (de) * 2012-08-22 2019-05-16 Airbus Defence and Space GmbH Luftfahrzeug-Brennstoffzellensystem sowie Verwendung desselben
EP3245459A4 (en) * 2015-01-14 2018-07-18 Thermax Limited System for improved hydrogen distribution in a metal hydride reactor
WO2017146589A1 (en) * 2016-02-25 2017-08-31 Hydrogen Mem-Tech As Hydrogen production from natural gas in combination with injection of co2 for enhanced oil recovery
JP7261235B2 (ja) * 2017-12-08 2023-04-19 トプソー・アクチエゼルスカベット 合成ガス製造のための系および方法
US11492255B2 (en) 2020-04-03 2022-11-08 Saudi Arabian Oil Company Steam methane reforming with steam regeneration
US11322766B2 (en) 2020-05-28 2022-05-03 Saudi Arabian Oil Company Direct hydrocarbon metal supported solid oxide fuel cell
US11639290B2 (en) 2020-06-04 2023-05-02 Saudi Arabian Oil Company Dry reforming of methane with carbon dioxide at elevated pressure
US11583824B2 (en) * 2020-06-18 2023-02-21 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11492254B2 (en) 2020-06-18 2022-11-08 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11999619B2 (en) 2020-06-18 2024-06-04 Saudi Arabian Oil Company Hydrogen production with membrane reactor
US12220666B2 (en) 2021-01-12 2025-02-11 Saudi Arabian Oil Company Ultrathin membrane fabrication
US12258272B2 (en) 2021-08-12 2025-03-25 Saudi Arabian Oil Company Dry reforming of methane using a nickel-based bi-metallic catalyst
US11578016B1 (en) 2021-08-12 2023-02-14 Saudi Arabian Oil Company Olefin production via dry reforming and olefin synthesis in a vessel
US11787759B2 (en) 2021-08-12 2023-10-17 Saudi Arabian Oil Company Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel
US11718575B2 (en) 2021-08-12 2023-08-08 Saudi Arabian Oil Company Methanol production via dry reforming and methanol synthesis in a vessel
US11617981B1 (en) 2022-01-03 2023-04-04 Saudi Arabian Oil Company Method for capturing CO2 with assisted vapor compression
CN118765212A (zh) * 2022-02-28 2024-10-11 日本碍子株式会社 反应器组件和分离膜组件

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217506A (en) * 1990-08-10 1993-06-08 Bend Research, Inc. Hydrogen-permeable composite metal membrane and uses thereof
US5393325A (en) * 1990-08-10 1995-02-28 Bend Research, Inc. Composite hydrogen separation metal membrane
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
WO2002066144A2 (fr) * 2001-02-19 2002-08-29 Compagnie D'etude Des Techniques De L'hydrogene (Ceth) Structures composites de membranes selectivement permeables a l'hydrogene et processeurs de gaz combustibles en faisant usage
WO2004022480A2 (en) * 2002-09-05 2004-03-18 Shell Internationale Research Maatschappij B.V. Apparatus and process for production of high purity hydrogen
WO2004098751A1 (en) * 2003-05-02 2004-11-18 Worcester Polytechnic Institute Composite gas separation modules having high tamman temperature intermediate layers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5139541A (en) * 1990-08-10 1992-08-18 Bend Research, Inc. Hydrogen-permeable composite metal membrane
JPH04346824A (ja) * 1991-05-21 1992-12-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH0585702A (ja) * 1991-09-30 1993-04-06 Mitsubishi Heavy Ind Ltd 水素分離膜の製造方法
JP3117276B2 (ja) * 1992-04-09 2000-12-11 三菱重工業株式会社 水素分離膜
JP3621785B2 (ja) * 1996-07-12 2005-02-16 トヨタ自動車株式会社 水素分離構造体
JP2001286742A (ja) * 2000-04-10 2001-10-16 Mitsubishi Heavy Ind Ltd 水素分離膜
JP2002219341A (ja) * 2001-01-30 2002-08-06 Kobe Steel Ltd 水素選択透過膜支持用基材および水素選択透過部材
DE10135390A1 (de) * 2001-07-25 2003-02-20 Fraunhofer Ges Forschung Metallische Lösungs-Diffusions-Membran sowie Verfahren zur Herstellung
EP1606040A2 (en) * 2003-03-21 2005-12-21 Worcester Polytechnic Institute Composite gas separations modules having intermediate metal layers

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5217506A (en) * 1990-08-10 1993-06-08 Bend Research, Inc. Hydrogen-permeable composite metal membrane and uses thereof
US5393325A (en) * 1990-08-10 1995-02-28 Bend Research, Inc. Composite hydrogen separation metal membrane
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
WO2002066144A2 (fr) * 2001-02-19 2002-08-29 Compagnie D'etude Des Techniques De L'hydrogene (Ceth) Structures composites de membranes selectivement permeables a l'hydrogene et processeurs de gaz combustibles en faisant usage
WO2004022480A2 (en) * 2002-09-05 2004-03-18 Shell Internationale Research Maatschappij B.V. Apparatus and process for production of high purity hydrogen
WO2004098751A1 (en) * 2003-05-02 2004-11-18 Worcester Polytechnic Institute Composite gas separation modules having high tamman temperature intermediate layers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
EDLUND D J et al: 'The relationship between inter-metallic diffusion and flux decline in composite-metal membranes: implications for achieving long membrane lifetime', JOURNAL OF MEMBRANE SCIENCE, ELSEVIER SCINENTIFIC PUBLICATIONS COMPANY. *
SHU J et al: 'Structurally stable composite Pd-Ag alloy membranes: Introduction of a diffusion barrier'. THIN SOLID FILMS, ELSEVIER-SEQUIOA S.A LAUSANNE, CH, vol. 286, no. 1, 30 September 1996, pages 72- 79, XP004049419, ISSN: 00040-6090 *

Also Published As

Publication number Publication date
WO2006034103A1 (en) 2006-03-30
EP1791631A1 (en) 2007-06-06
TW200624376A (en) 2006-07-16
NO20071531L (no) 2007-06-20
AU2005286955A1 (en) 2006-03-30
JP2008513339A (ja) 2008-05-01
CA2580279A1 (en) 2006-03-30

Similar Documents

Publication Publication Date Title
AU2005286955B2 (en) Reactor and process for steam reforming
AU2005287034B2 (en) Membrane enhanced reactor
AU2005286952B2 (en) Membrane steam reformer
JP4782423B2 (ja) 高純度水素の製造装置及び方法
KR101807112B1 (ko) 쉘-앤-튜브형 천연가스 개질용 반응기 및 이를 이용한 합성가스 또는 수소가스의 제조방법
JP5265833B2 (ja) 熱的化学反応の高い生産速度を得るための方法および装置
US6090312A (en) Reactor-membrane permeator process for hydrocarbon reforming and water gas-shift reactions
Zhang et al. High-purity COx-free H2 generation from NH3 via the ultra permeable and highly selective Pd membranes
US6652830B2 (en) Catalysts reactors and methods of producing hydrogen via the water-gas shift reaction
JP5366556B2 (ja) 酸化反応器および酸化方法
JP2004502623A (ja) 熱交換膜反応装置による発電
Xia et al. Innovative steam methane reforming for coproducing CO‐free hydrogen and syngas in proton conducting membrane reactor
Li et al. Development of palladium-alloy membranes for hydrogen separation and purification
AU2478801A (en) Catalytic monolith made of ceria and titania
RU2292237C1 (ru) Катализатор, способ его приготовления и способ получения синтез-газа
JP2007527305A (ja) 膜装置、および膜を調製する方法、および水素を生成する方法
KR20230096280A (ko) 암모니아 분해 반응에 의해 수소를 생산하는 수소 분리막 반응기를 포함하는 수소 생산시스템
JPH04325402A (ja) 燃料電池用水素製造方法及び装置並びに供給方法
KR20210079909A (ko) 프리리포머(pre-reformer) 및 분리막 리포머를 이용한 수소 생산 장치 및 공정
KR20220063531A (ko) 원통형 또는 튜브형 지지체 상에 분말 입자들이 순차적으로 적층되어 결정화된 적층막의 제조방법
TWI473760B (zh) 膜管複合體及利用該複合體之高純度氫氣產生裝置
Iaquaniello et al. Palladium-based selective membranes for hydrogen production
She Composite palladium membranes: synthesis, separation and reaction

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired