AU2003253026B2 - Use of metal complex compounds as oxidation catalysts - Google Patents
Use of metal complex compounds as oxidation catalysts Download PDFInfo
- Publication number
- AU2003253026B2 AU2003253026B2 AU2003253026A AU2003253026A AU2003253026B2 AU 2003253026 B2 AU2003253026 B2 AU 2003253026B2 AU 2003253026 A AU2003253026 A AU 2003253026A AU 2003253026 A AU2003253026 A AU 2003253026A AU 2003253026 B2 AU2003253026 B2 AU 2003253026B2
- Authority
- AU
- Australia
- Prior art keywords
- substituted
- alkyl
- unsubstituted
- hydrogen
- alkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- -1 metal complex compounds Chemical class 0.000 title claims description 133
- 239000003054 catalyst Substances 0.000 title claims description 41
- 238000007254 oxidation reaction Methods 0.000 title claims description 23
- 230000003647 oxidation Effects 0.000 title claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 140
- 229910052739 hydrogen Inorganic materials 0.000 claims description 114
- 239000001257 hydrogen Substances 0.000 claims description 112
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 60
- 229910052757 nitrogen Inorganic materials 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 55
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 55
- 150000002431 hydrogen Chemical class 0.000 claims description 52
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 50
- 238000005406 washing Methods 0.000 claims description 44
- 239000003446 ligand Substances 0.000 claims description 43
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Natural products C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 43
- 125000003118 aryl group Chemical group 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 37
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 32
- 125000001424 substituent group Chemical group 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical class C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 30
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 229910052736 halogen Inorganic materials 0.000 claims description 27
- 150000002367 halogens Chemical class 0.000 claims description 27
- 239000011572 manganese Substances 0.000 claims description 27
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 24
- 238000004061 bleaching Methods 0.000 claims description 24
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 22
- 239000000975 dye Substances 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- 150000001768 cations Chemical class 0.000 claims description 19
- 125000005842 heteroatom Chemical group 0.000 claims description 18
- 150000002978 peroxides Chemical class 0.000 claims description 18
- 239000007844 bleaching agent Substances 0.000 claims description 17
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical class C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 16
- 125000003725 azepanyl group Chemical class 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 15
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical group [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 14
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 14
- 229910052748 manganese Inorganic materials 0.000 claims description 13
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 13
- 239000004753 textile Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 150000004696 coordination complex Chemical class 0.000 claims description 8
- 230000000249 desinfective effect Effects 0.000 claims description 8
- 150000002696 manganese Chemical class 0.000 claims description 8
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 239000012459 cleaning agent Substances 0.000 claims description 7
- 239000000645 desinfectant Substances 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
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- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 150000002505 iron Chemical class 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical group [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
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- 125000001624 naphthyl group Chemical group 0.000 claims description 2
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- 229940095064 tartrate Drugs 0.000 claims description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 2
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 description 44
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 18
- 238000005160 1H NMR spectroscopy Methods 0.000 description 17
- 239000002253 acid Substances 0.000 description 17
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- 159000000000 sodium salts Chemical class 0.000 description 10
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 9
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- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
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- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/68—One oxygen atom attached in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Pyrrole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405591 | 2002-07-11 | ||
| EP02405591.5 | 2002-07-11 | ||
| PCT/EP2003/007121 WO2004007657A1 (en) | 2002-07-11 | 2003-07-03 | Use of metal complex compounds as oxidation catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2003253026A1 AU2003253026A1 (en) | 2004-02-02 |
| AU2003253026B2 true AU2003253026B2 (en) | 2009-05-14 |
Family
ID=30011302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003253026A Ceased AU2003253026B2 (en) | 2002-07-11 | 2003-07-03 | Use of metal complex compounds as oxidation catalysts |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7494964B2 (enExample) |
| EP (1) | EP1521820B1 (enExample) |
| JP (1) | JP4643259B2 (enExample) |
| KR (1) | KR101018716B1 (enExample) |
| CN (1) | CN1306017C (enExample) |
| AR (1) | AR040480A1 (enExample) |
| AT (1) | ATE321117T1 (enExample) |
| AU (1) | AU2003253026B2 (enExample) |
| BR (1) | BR0312694B1 (enExample) |
| DE (1) | DE60304200T2 (enExample) |
| ES (1) | ES2259771T3 (enExample) |
| MX (1) | MXPA05000483A (enExample) |
| TW (1) | TWI311924B (enExample) |
| WO (1) | WO2004007657A1 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002088289A2 (en) * | 2001-04-30 | 2002-11-07 | Ciba Specialty Chemicals Holding Inc. | Use of metal complex compounds as oxidation catalysts |
| CN1708579A (zh) * | 2002-10-29 | 2005-12-14 | 西巴特殊化学品控股有限公司 | 金属配位化合物作为用分子氧或空气进行氧化的催化剂的应用 |
| GB2394720A (en) * | 2002-10-30 | 2004-05-05 | Reckitt Benckiser Nv | Metal complex compounds in dishwasher formulations |
| GB2409207B (en) * | 2003-12-20 | 2006-08-09 | Reckitt Benckiser Nv | Use of metal complex compounds as oxidation catalysts |
| EP1703977A1 (en) * | 2004-01-12 | 2006-09-27 | Ciba SC Holding AG | Use of a composition comprising metal complex compounds and polyphosphonates as catalysts for oxidations |
| EP1740306A1 (en) * | 2004-04-29 | 2007-01-10 | CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement | Use of metal complexes having bispyridylpyrimidine or bispyridyltriazine ligands as catalysts for reactions with peroxy compounds for bleaching coloured stains on hard surfaces |
| DE102004024816A1 (de) * | 2004-05-17 | 2005-12-15 | Henkel Kgaa | Bleichverstärkerkombination für den Einsatz in Wasch- und Reinigungsmitteln |
| EP1747259A1 (de) * | 2004-05-17 | 2007-01-31 | Henkel Kommanditgesellschaft auf Aktien | Waschmittel mit gegebenenfalls in situ erzeugtem bleichverstärkendem übergangsmetallkomplex |
| EP1879548A2 (en) * | 2005-05-13 | 2008-01-23 | Ciba Specialty Chemicals Holding Inc. | Process for coloring keratin fibers comprising metal complexes |
| WO2009109533A1 (en) * | 2008-03-07 | 2009-09-11 | Basf Se | Bleach catalysts and their use as teeth whitening agents |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| TR201905689T4 (tr) * | 2008-04-09 | 2019-05-21 | Basf Se | Hidrazit bileşiklerinin oksidasyon katalizörleri olarak kullanımı. |
| WO2010020583A1 (en) * | 2008-08-20 | 2010-02-25 | Basf Se | Improved bleach process |
| DE102008045207A1 (de) * | 2008-08-30 | 2010-03-04 | Clariant International Limited | Bleichkatalysatormischungen bestehend aus Mangansalzen und Oxalsäure oder deren Salze |
| US8415443B2 (en) * | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| PL2477740T3 (pl) * | 2009-09-18 | 2015-06-30 | Weylchem Lamotte | Sposób wytwarzania mostkowych manganowych kompleksów triazacyklononanu |
| TWI551551B (zh) * | 2010-04-30 | 2016-10-01 | 三菱瓦斯化學股份有限公司 | 過氧化物活性化劑以及土壤及／或地下水之淨化方法 |
| MX2012015285A (es) | 2010-06-28 | 2013-02-07 | Basf Se | Composicion blanqueadora libre de metal. |
| AU2011344415B2 (en) | 2010-12-13 | 2016-05-26 | Basf Se | Bleach catalysts |
| CN104145012A (zh) | 2011-10-25 | 2014-11-12 | 巴斯夫欧洲公司 | 丙烯酸酯共聚物作为抗污垢再沉积剂和去污剂在洗衣过程中的用途 |
| RU2014120925A (ru) | 2011-10-25 | 2015-12-10 | Басф Се | Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки |
| US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
| WO2014193915A1 (en) * | 2013-05-28 | 2014-12-04 | Sigma-Aldrich Co. Llc | Manganese complexes and use thereof for preparing thin films |
| KR20160105790A (ko) | 2013-11-27 | 2016-09-07 | 바스프 에스이 | 세탁 방법에서 오염물 방출제로서의 랜덤 공중합체 |
| WO2017076771A1 (en) | 2015-11-03 | 2017-05-11 | Basf Se | Bleach catalysts |
| EP3176157A1 (en) | 2015-12-01 | 2017-06-07 | Basf Se | Bleach catalysts |
| WO2017182295A1 (en) | 2016-04-18 | 2017-10-26 | Basf Se | Liquid cleaning compositions |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| EP3372663A1 (en) | 2017-03-10 | 2018-09-12 | Basf Se | Bleach catalysts |
| CN111875624B (zh) * | 2020-06-06 | 2022-06-14 | 桂林理工大学 | 一种基于bteb的四核锌配合物的制备、结构和荧光应用 |
| CN120731240A (zh) | 2023-02-21 | 2025-09-30 | 巴斯夫欧洲公司 | 改性的烷氧基化聚亚烷基亚胺或改性的烷氧基化多胺 |
| WO2024175409A1 (en) | 2023-02-21 | 2024-08-29 | Basf Se | Modified hyperbranched alkoxylated polyalkylene imines |
| CN120769877A (zh) | 2023-02-21 | 2025-10-10 | 巴斯夫欧洲公司 | 改性的烷氧基化聚亚烷基亚胺或改性的烷氧基化多胺 |
| CN120882779A (zh) | 2023-03-13 | 2025-10-31 | 巴斯夫欧洲公司 | 烷氧基化含氮聚合物及其用途 |
| WO2024231110A1 (en) | 2023-05-05 | 2024-11-14 | Basf Se | Biodegradable polyol propoxylates, their preparation, uses, and compositions comprising them |
| WO2024256175A1 (en) | 2023-06-13 | 2024-12-19 | Basf Se | Stabilized cleaning compositions comprising edds and enzymes and their use |
| WO2025125117A1 (en) | 2023-12-15 | 2025-06-19 | Basf Se | Biodegradable propoxylated ethylenediamines, their preparation, uses, and compositions comprising them |
| WO2025131888A1 (en) | 2023-12-19 | 2025-06-26 | Basf Se | Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines |
| WO2025180874A1 (en) | 2024-02-27 | 2025-09-04 | Basf Se | Substituted 1,3-dioxolane sulfates and their use |
| WO2025195856A1 (en) | 2024-03-19 | 2025-09-25 | Basf Se | Compositions of guerbet alkyl sulfates and their use |
| WO2025202032A1 (en) | 2024-03-26 | 2025-10-02 | Basf Se | Biodegradable alkoxylated polyols, their preparation, uses, and compositions comprising them |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH082878B2 (ja) * | 1988-02-12 | 1996-01-17 | 富士写真フイルム株式会社 | ４’−アルコキシ−２，２’：６’，２〃−デルピリジン誘導体及びその金属錯体 |
| FR2677766B1 (fr) * | 1991-06-14 | 1994-11-10 | Asulab Sa | Capteur de mesure de la quantite d'un composant en solution. |
| JP3852044B2 (ja) * | 1999-05-10 | 2006-11-29 | 独立行政法人科学技術振興機構 | 三脚型（トリポーダル）ピリジルアミン配位子を用いたアルキルパーオキソ単核鉄（ｉｉｉ）錯体のエポキシ化触媒 |
| GB9930248D0 (en) * | 1999-12-22 | 2000-02-09 | Johnson Matthey Plc | Surface cleaner |
| EP1217056A1 (en) * | 2000-12-21 | 2002-06-26 | Johnson Matthey Public Limited Company | Photocatalytic material |
| WO2002088289A2 (en) * | 2001-04-30 | 2002-11-07 | Ciba Specialty Chemicals Holding Inc. | Use of metal complex compounds as oxidation catalysts |
-
2003
- 2003-07-03 WO PCT/EP2003/007121 patent/WO2004007657A1/en not_active Ceased
- 2003-07-03 ES ES03763699T patent/ES2259771T3/es not_active Expired - Lifetime
- 2003-07-03 MX MXPA05000483A patent/MXPA05000483A/es active IP Right Grant
- 2003-07-03 KR KR1020057000337A patent/KR101018716B1/ko not_active Expired - Fee Related
- 2003-07-03 AT AT03763699T patent/ATE321117T1/de not_active IP Right Cessation
- 2003-07-03 JP JP2004520474A patent/JP4643259B2/ja not_active Expired - Fee Related
- 2003-07-03 EP EP03763699A patent/EP1521820B1/en not_active Expired - Lifetime
- 2003-07-03 BR BRPI0312694-3B1A patent/BR0312694B1/pt not_active IP Right Cessation
- 2003-07-03 DE DE60304200T patent/DE60304200T2/de not_active Expired - Lifetime
- 2003-07-03 CN CNB038164892A patent/CN1306017C/zh not_active Expired - Fee Related
- 2003-07-03 AU AU2003253026A patent/AU2003253026B2/en not_active Ceased
- 2003-07-03 US US10/520,841 patent/US7494964B2/en not_active Expired - Fee Related
- 2003-07-09 TW TW092118692A patent/TWI311924B/zh not_active IP Right Cessation
- 2003-07-10 AR AR20030102484A patent/AR040480A1/es active IP Right Grant
Non-Patent Citations (1)
| Title |
|---|
| See reference of WO 2004/007657 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60304200D1 (de) | 2006-05-11 |
| JP2005532158A (ja) | 2005-10-27 |
| KR101018716B1 (ko) | 2011-03-04 |
| CN1668730A (zh) | 2005-09-14 |
| US20060100123A1 (en) | 2006-05-11 |
| JP4643259B2 (ja) | 2011-03-02 |
| BR0312694A (pt) | 2005-04-26 |
| EP1521820B1 (en) | 2006-03-22 |
| ATE321117T1 (de) | 2006-04-15 |
| MXPA05000483A (es) | 2005-03-23 |
| TW200404605A (en) | 2004-04-01 |
| TWI311924B (en) | 2009-07-11 |
| AR040480A1 (es) | 2005-04-06 |
| ES2259771T3 (es) | 2006-10-16 |
| AU2003253026A1 (en) | 2004-02-02 |
| KR20050017091A (ko) | 2005-02-21 |
| DE60304200T2 (de) | 2006-08-17 |
| WO2004007657A1 (en) | 2004-01-22 |
| EP1521820A1 (en) | 2005-04-13 |
| CN1306017C (zh) | 2007-03-21 |
| BR0312694B1 (pt) | 2013-11-05 |
| US7494964B2 (en) | 2009-02-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC1 | Assignment before grant (sect. 113) |
Owner name: BASF SE Free format text: FORMER APPLICANT(S): CIBA HOLDING INC. |
|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |