AR040480A1 - Uso de compuestos de complejos metalicos como catalizadores de oxidacion - Google Patents
Uso de compuestos de complejos metalicos como catalizadores de oxidacionInfo
- Publication number
- AR040480A1 AR040480A1 AR20030102484A ARP030102484A AR040480A1 AR 040480 A1 AR040480 A1 AR 040480A1 AR 20030102484 A AR20030102484 A AR 20030102484A AR P030102484 A ARP030102484 A AR P030102484A AR 040480 A1 AR040480 A1 AR 040480A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkylene
- r14r15r16
- substituted
- formula
- nr14r15
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- -1 METAL COMPLEX COMPOUNDS Chemical class 0.000 title 1
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 abstract 6
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 150000002431 hydrogen Chemical class 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/68—One oxygen atom attached in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Pyrrole Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Uso de compuestos de complejos metálicos de fórmula principal [LnMemXp]zYq en donde Me es manganeso, titanio, hierro, cobalto, níquel o cobre, X es un radical de puente o coordinante, n y m son, cada uno en forma independiente del otro, un entero que tiene un valor de desde 1 a 8, p es un entero que tiene un valor de desde 0 a 32, z es la carga del complejo metálico, Y es un contraión, q = z/ (carga Y), y L es un ligando de fórmula (1) en donde R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 y R11 son, cada uno en forma independiente de los otros, hidrógenos; arilo o alquilo C1-18 no sustituido o sustituido; ciano; halógeno; nitro; -COOR12 o -SO3R12, en donde R12 es, en cada caso, hidrógeno, un catión o arilo o alquilo C1-18 no sustituido o sustituido; - SR13, -SO2R13 u -OR13, en donde R13 es, en cada caso, hidrógeno, o arilo o alquilo C1-18 no sustituido o sustituido; -NR14R15; -(alquileno C1-6)-NR14R15; -N(+)R14R15R16; -(alquileno C1-6)-N(+)R14R15R16; -N(R13)-(alquileno C1-6)-NR14R15; -N[(alquileno C1-6)-NR14R15]2; -N(R13)-(alquileno C1-6)-N(+)R14R15R16; -N[(alquileno C1-6)-N(+)R14R15R16]2; -N(R13)-N-R14R15 o -N(R13)-N(+)R14R15R16 en donde R13 es como se define antes, y R14, R15 y R16 son, cada uno en forma independientemente del o los otros, hidrógeno, o arilo o alquilo C1-18 no sustituido o sustituido, o R14 y R15 junto con el átomo de nitrógeno que los une forman un anillo de 5, 6 ó 7 miembros, no sustituido o sustituido, que en forma opcional puede contener otros heteroátomos; con la condición que (i) por lo menos uno de los sustituyentes R1 a R11 contenga un átomo de nitrógeno cuaternizado que no esté directamente ligado a uno de los tres anillos piridina, A, B o C; y que (ii) Y no sea I(-) ni Cl(-) en el caso que Me sea Mn(II), R1 a R5 y R7 a R11 sean hidrógeno y R6 sea una fórmula (2) como catalizadores para reacciones de oxidación, y los nuevos compuestos de complejos metálicos de fórmula principal, los nuevos ligandos de fórmula (1) y sus materiales iniciales.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405591 | 2002-07-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR040480A1 true AR040480A1 (es) | 2005-04-06 |
Family
ID=30011302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AR20030102484A AR040480A1 (es) | 2002-07-11 | 2003-07-10 | Uso de compuestos de complejos metalicos como catalizadores de oxidacion |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US7494964B2 (es) |
| EP (1) | EP1521820B1 (es) |
| JP (1) | JP4643259B2 (es) |
| KR (1) | KR101018716B1 (es) |
| CN (1) | CN1306017C (es) |
| AR (1) | AR040480A1 (es) |
| AT (1) | ATE321117T1 (es) |
| AU (1) | AU2003253026B2 (es) |
| BR (1) | BR0312694B1 (es) |
| DE (1) | DE60304200T2 (es) |
| ES (1) | ES2259771T3 (es) |
| MX (1) | MXPA05000483A (es) |
| TW (1) | TWI311924B (es) |
| WO (1) | WO2004007657A1 (es) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE60211884T2 (de) * | 2001-04-30 | 2006-11-23 | Ciba Speciality Chemicals Holding Inc. | Verwendung von metallkomplexverbindungen als oxidationskatalysatoren |
| KR20050059312A (ko) * | 2002-10-29 | 2005-06-17 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 분자 산소 또는 공기를 사용한 산화반응에 대한 촉매로서금속 착물 화합물의 용도 |
| GB2394720A (en) * | 2002-10-30 | 2004-05-05 | Reckitt Benckiser Nv | Metal complex compounds in dishwasher formulations |
| GB2409207B (en) * | 2003-12-20 | 2006-08-09 | Reckitt Benckiser Nv | Use of metal complex compounds as oxidation catalysts |
| EP1703977A1 (en) * | 2004-01-12 | 2006-09-27 | Ciba SC Holding AG | Use of a composition comprising metal complex compounds and polyphosphonates as catalysts for oxidations |
| JP2007534479A (ja) * | 2004-04-29 | 2007-11-29 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 硬質表面上の着色した汚れを漂白するためのパーオキシ化合物を用いた反応の触媒としての、ビスピリジルピリミジン又はビスピリジルトリアジン配位子を有する金属錯体の使用 |
| WO2005116179A1 (de) * | 2004-05-17 | 2005-12-08 | Henkel Kommanditgesellschaft Auf Aktien | Waschmittel mit gegebenenfalls in situ erzeugtem bleichverstärkendem übergangsmetallkomplex |
| DE102004024816A1 (de) * | 2004-05-17 | 2005-12-15 | Henkel Kgaa | Bleichverstärkerkombination für den Einsatz in Wasch- und Reinigungsmitteln |
| US7682404B2 (en) * | 2005-05-13 | 2010-03-23 | Ciba Specialty Chemicals Corporation | Coloring keratin fibers with metal complexes |
| WO2009109533A1 (en) * | 2008-03-07 | 2009-09-11 | Basf Se | Bleach catalysts and their use as teeth whitening agents |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| US8492324B2 (en) | 2008-04-09 | 2013-07-23 | Basf Se | Use of metal hydrazide complex compounds as oxidation catalysts |
| WO2010020583A1 (en) * | 2008-08-20 | 2010-02-25 | Basf Se | Improved bleach process |
| DE102008045207A1 (de) * | 2008-08-30 | 2010-03-04 | Clariant International Limited | Bleichkatalysatormischungen bestehend aus Mangansalzen und Oxalsäure oder deren Salze |
| US8415443B2 (en) * | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| PL2477740T3 (pl) * | 2009-09-18 | 2015-06-30 | Weylchem Lamotte | Sposób wytwarzania mostkowych manganowych kompleksów triazacyklononanu |
| TWI551551B (zh) * | 2010-04-30 | 2016-10-01 | 三菱瓦斯化學股份有限公司 | 過氧化物活性化劑以及土壤及／或地下水之淨化方法 |
| JP5878528B2 (ja) | 2010-06-28 | 2016-03-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 金属を含まない漂白用組成物 |
| KR101912962B1 (ko) | 2010-12-13 | 2018-10-29 | 바스프 에스이 | 표백 촉매 |
| WO2013060708A1 (en) | 2011-10-25 | 2013-05-02 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| RU2014120926A (ru) | 2011-10-25 | 2015-12-10 | Басф Се | Применение акрилатных сополимеров в качестве средств против повторного осаждения загрязнений и грязеотталкивающих средств в процессах стирки |
| EP2978786A1 (en) | 2013-03-27 | 2016-02-03 | Basf Se | Block copolymers as soil release agents in laundry processes |
| WO2014193915A1 (en) * | 2013-05-28 | 2014-12-04 | Sigma-Aldrich Co. Llc | Manganese complexes and use thereof for preparing thin films |
| BR112016011665A2 (pt) | 2013-11-27 | 2017-09-19 | Basf Se | Copolímero aleatório, uso de um copolímero aleatório, e, detergente |
| WO2017076771A1 (en) | 2015-11-03 | 2017-05-11 | Basf Se | Bleach catalysts |
| EP3176157A1 (en) | 2015-12-01 | 2017-06-07 | Basf Se | Bleach catalysts |
| WO2017182295A1 (en) | 2016-04-18 | 2017-10-26 | Basf Se | Liquid cleaning compositions |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| EP3372663A1 (en) | 2017-03-10 | 2018-09-12 | Basf Se | Bleach catalysts |
| CN111875624B (zh) * | 2020-06-06 | 2022-06-14 | 桂林理工大学 | 一种基于bteb的四核锌配合物的制备、结构和荧光应用 |
| WO2024175407A1 (en) | 2023-02-21 | 2024-08-29 | Basf Se | Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines |
| WO2024175409A1 (en) | 2023-02-21 | 2024-08-29 | Basf Se | Modified hyperbranched alkoxylated polyalkylene imines |
| WO2024175401A1 (en) | 2023-02-21 | 2024-08-29 | Basf Se | Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines |
| WO2024188713A1 (en) | 2023-03-13 | 2024-09-19 | Basf Se | Alkoxylated nitrogen containing polymers and their use |
| WO2024231110A1 (en) | 2023-05-05 | 2024-11-14 | Basf Se | Biodegradable polyol propoxylates, their preparation, uses, and compositions comprising them |
| WO2024256175A1 (en) | 2023-06-13 | 2024-12-19 | Basf Se | Stabilized cleaning compositions comprising edds and enzymes and their use |
| WO2025125117A1 (en) | 2023-12-15 | 2025-06-19 | Basf Se | Biodegradable propoxylated ethylenediamines, their preparation, uses, and compositions comprising them |
| WO2025131888A1 (en) | 2023-12-19 | 2025-06-26 | Basf Se | Modified alkoxylated polyalkylene imines or modified alkoxylated polyamines |
| WO2025180874A1 (en) | 2024-02-27 | 2025-09-04 | Basf Se | Substituted 1,3-dioxolane sulfates and their use |
| WO2025195856A1 (en) | 2024-03-19 | 2025-09-25 | Basf Se | Compositions of guerbet alkyl sulfates and their use |
| WO2025202032A1 (en) | 2024-03-26 | 2025-10-02 | Basf Se | Biodegradable alkoxylated polyols, their preparation, uses, and compositions comprising them |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH082878B2 (ja) * | 1988-02-12 | 1996-01-17 | 富士写真フイルム株式会社 | ４’−アルコキシ−２，２’：６’，２〃−デルピリジン誘導体及びその金属錯体 |
| FR2677766B1 (fr) * | 1991-06-14 | 1994-11-10 | Asulab Sa | Capteur de mesure de la quantite d'un composant en solution. |
| JP3852044B2 (ja) * | 1999-05-10 | 2006-11-29 | 独立行政法人科学技術振興機構 | 三脚型（トリポーダル）ピリジルアミン配位子を用いたアルキルパーオキソ単核鉄（ｉｉｉ）錯体のエポキシ化触媒 |
| GB9930248D0 (en) * | 1999-12-22 | 2000-02-09 | Johnson Matthey Plc | Surface cleaner |
| EP1217056A1 (en) * | 2000-12-21 | 2002-06-26 | Johnson Matthey Public Limited Company | Photocatalytic material |
| DE60211884T2 (de) * | 2001-04-30 | 2006-11-23 | Ciba Speciality Chemicals Holding Inc. | Verwendung von metallkomplexverbindungen als oxidationskatalysatoren |
-
2003
- 2003-07-03 BR BRPI0312694-3B1A patent/BR0312694B1/pt not_active IP Right Cessation
- 2003-07-03 AT AT03763699T patent/ATE321117T1/de not_active IP Right Cessation
- 2003-07-03 AU AU2003253026A patent/AU2003253026B2/en not_active Ceased
- 2003-07-03 EP EP03763699A patent/EP1521820B1/en not_active Expired - Lifetime
- 2003-07-03 ES ES03763699T patent/ES2259771T3/es not_active Expired - Lifetime
- 2003-07-03 KR KR1020057000337A patent/KR101018716B1/ko not_active Expired - Fee Related
- 2003-07-03 MX MXPA05000483A patent/MXPA05000483A/es active IP Right Grant
- 2003-07-03 WO PCT/EP2003/007121 patent/WO2004007657A1/en not_active Ceased
- 2003-07-03 CN CNB038164892A patent/CN1306017C/zh not_active Expired - Fee Related
- 2003-07-03 US US10/520,841 patent/US7494964B2/en not_active Expired - Fee Related
- 2003-07-03 JP JP2004520474A patent/JP4643259B2/ja not_active Expired - Fee Related
- 2003-07-03 DE DE60304200T patent/DE60304200T2/de not_active Expired - Lifetime
- 2003-07-09 TW TW092118692A patent/TWI311924B/zh not_active IP Right Cessation
- 2003-07-10 AR AR20030102484A patent/AR040480A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| KR101018716B1 (ko) | 2011-03-04 |
| ES2259771T3 (es) | 2006-10-16 |
| JP4643259B2 (ja) | 2011-03-02 |
| AU2003253026A1 (en) | 2004-02-02 |
| BR0312694A (pt) | 2005-04-26 |
| CN1306017C (zh) | 2007-03-21 |
| KR20050017091A (ko) | 2005-02-21 |
| WO2004007657A1 (en) | 2004-01-22 |
| DE60304200T2 (de) | 2006-08-17 |
| US7494964B2 (en) | 2009-02-24 |
| MXPA05000483A (es) | 2005-03-23 |
| AU2003253026B2 (en) | 2009-05-14 |
| US20060100123A1 (en) | 2006-05-11 |
| DE60304200D1 (de) | 2006-05-11 |
| TW200404605A (en) | 2004-04-01 |
| JP2005532158A (ja) | 2005-10-27 |
| BR0312694B1 (pt) | 2013-11-05 |
| TWI311924B (en) | 2009-07-11 |
| ATE321117T1 (de) | 2006-04-15 |
| EP1521820A1 (en) | 2005-04-13 |
| EP1521820B1 (en) | 2006-03-22 |
| CN1668730A (zh) | 2005-09-14 |
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