AU2003250201B2 - Highly stereoregular polypropylene with improved properties - Google Patents
Highly stereoregular polypropylene with improved properties Download PDFInfo
- Publication number
- AU2003250201B2 AU2003250201B2 AU2003250201A AU2003250201A AU2003250201B2 AU 2003250201 B2 AU2003250201 B2 AU 2003250201B2 AU 2003250201 A AU2003250201 A AU 2003250201A AU 2003250201 A AU2003250201 A AU 2003250201A AU 2003250201 B2 AU2003250201 B2 AU 2003250201B2
- Authority
- AU
- Australia
- Prior art keywords
- film
- sheet according
- propylene polymer
- equal
- electron donor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001155 polypropylene Polymers 0.000 title claims description 32
- -1 polypropylene Polymers 0.000 title claims description 18
- 239000004743 Polypropylene Substances 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 22
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 18
- 239000011949 solid catalyst Substances 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 14
- 238000009826 distribution Methods 0.000 claims description 12
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 9
- 150000003254 radicals Chemical class 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 150000003890 succinate salts Chemical class 0.000 claims description 7
- 235000007586 terpenes Nutrition 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 150000004756 silanes Chemical class 0.000 claims description 5
- 235000011044 succinic acid Nutrition 0.000 claims description 5
- 150000003444 succinic acids Chemical class 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 3
- 150000005840 aryl radicals Chemical class 0.000 claims description 3
- 239000000571 coke Substances 0.000 claims description 3
- 150000003377 silicon compounds Chemical class 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 238000010828 elution Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
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- 239000004215 Carbon black (E152) Substances 0.000 description 4
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 229910010066 TiC14 Inorganic materials 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229940078552 o-xylene Drugs 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 description 3
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MQHNKCZKNAJROC-UHFFFAOYSA-N dipropyl phthalate Chemical compound CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 150000002690 malonic acid derivatives Chemical class 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- POXXQVSKWJPZNO-UHFFFAOYSA-N 1-o-ethyl 2-o-(2-methylpropyl) benzene-1,2-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC(C)C POXXQVSKWJPZNO-UHFFFAOYSA-N 0.000 description 1
- ABYCGAKJMGFSPY-UHFFFAOYSA-N 2-hexan-3-yloxycarbonylbenzoic acid Chemical compound CCCC(CC)OC(=O)C1=CC=CC=C1C(O)=O ABYCGAKJMGFSPY-UHFFFAOYSA-N 0.000 description 1
- DUAYDERMVQWIJD-UHFFFAOYSA-N 2-n,2-n,6-trimethyl-1,3,5-triazine-2,4-diamine Chemical compound CN(C)C1=NC(C)=NC(N)=N1 DUAYDERMVQWIJD-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- KYZHGEFMXZOSJN-UHFFFAOYSA-N benzoic acid isobutyl ester Natural products CC(C)COC(=O)C1=CC=CC=C1 KYZHGEFMXZOSJN-UHFFFAOYSA-N 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- YCYHZGIPKZHEEL-UHFFFAOYSA-N diethyl 2,3-bis(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)(C)C)C(CC(C)(C)C)C(=O)OCC YCYHZGIPKZHEEL-UHFFFAOYSA-N 0.000 description 1
- ZEKAIFREAFGGIC-UHFFFAOYSA-N diethyl 2,3-bis(2-ethylbutyl)butanedioate Chemical compound CCOC(=O)C(CC(CC)CC)C(CC(CC)CC)C(=O)OCC ZEKAIFREAFGGIC-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- FITPXUCDWCINLG-UHFFFAOYSA-N diethyl 2,3-bis(cyclohexylmethyl)butanedioate Chemical compound C1CCCCC1CC(C(=O)OCC)C(C(=O)OCC)CC1CCCCC1 FITPXUCDWCINLG-UHFFFAOYSA-N 0.000 description 1
- OTUNNRWESSPIBH-UHFFFAOYSA-N diethyl 2,3-bis(trimethylsilyl)butanedioate Chemical compound CCOC(=O)C([Si](C)(C)C)C([Si](C)(C)C)C(=O)OCC OTUNNRWESSPIBH-UHFFFAOYSA-N 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- UIZHEHICSUOPQL-UHFFFAOYSA-N diethyl 2,3-dibenzylbutanedioate Chemical compound C=1C=CC=CC=1CC(C(=O)OCC)C(C(=O)OCC)CC1=CC=CC=C1 UIZHEHICSUOPQL-UHFFFAOYSA-N 0.000 description 1
- CXKANZAMPQTLBJ-UHFFFAOYSA-N diethyl 2,3-dicyclohexylbutanedioate Chemical compound C1CCCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 CXKANZAMPQTLBJ-UHFFFAOYSA-N 0.000 description 1
- ISOWAXIPBFLPIC-UHFFFAOYSA-N diethyl 2,3-dicyclopentylbutanedioate Chemical compound C1CCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCC1 ISOWAXIPBFLPIC-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- NWPWRAWAUYIELB-UHFFFAOYSA-N ethyl 4-methylbenzoate Chemical compound CCOC(=O)C1=CC=C(C)C=C1 NWPWRAWAUYIELB-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical compound CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02017287 | 2002-08-01 | ||
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| US41699102P | 2002-10-08 | 2002-10-08 | |
| US60/416,991 | 2002-10-08 | ||
| PCT/EP2003/008491 WO2004013193A2 (en) | 2002-08-01 | 2003-07-30 | Highly stereoregular polypropylene with improved properties |
Publications (2)
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| AU2003250201A1 AU2003250201A1 (en) | 2004-02-23 |
| AU2003250201B2 true AU2003250201B2 (en) | 2008-12-11 |
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| AU2003250201A Expired - Fee Related AU2003250201B2 (en) | 2002-08-01 | 2003-07-30 | Highly stereoregular polypropylene with improved properties |
Country Status (12)
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| US (2) | US7112642B2 (https=) |
| EP (1) | EP1527106A2 (https=) |
| JP (1) | JP2005534761A (https=) |
| KR (1) | KR20050033639A (https=) |
| CN (1) | CN100564399C (https=) |
| AU (1) | AU2003250201B2 (https=) |
| BR (1) | BR0306195B1 (https=) |
| CA (1) | CA2492939A1 (https=) |
| IL (1) | IL166300A (https=) |
| PL (1) | PL374508A1 (https=) |
| RU (1) | RU2325404C2 (https=) |
| WO (1) | WO2004013193A2 (https=) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2248679T3 (es) * | 2001-06-27 | 2006-03-16 | Borealis Technology Oy | Resina polimerica de propileno con propiedades mejoradas. |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| AU2005291326A1 (en) | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| US8513366B2 (en) * | 2005-03-17 | 2013-08-20 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| EP1726602A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| EP1726603A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| DE602006004987D1 (de) * | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
| EP1886806B1 (en) | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| ATE462189T1 (de) | 2006-09-25 | 2010-04-15 | Borealis Tech Oy | Koaxiales kabel |
| EP1939230B1 (en) | 2006-12-28 | 2009-03-04 | Borealis Technology Oy | Process for the manufacture of branched polypropylene |
| MX2009003471A (es) * | 2006-12-29 | 2009-04-15 | Fina Technology | Sistema de catalizador de polimerizacion que contiene succinato usando n-butilmetildimeto-xisilano para la preparacion de resinas de grado de pelicula de polipropileno. |
| EP1964948A1 (en) * | 2007-02-28 | 2008-09-03 | Total Petrochemicals Research Feluy | Polypropylene fibers and spunbond nonwoven with improved properties. |
| RU2457290C2 (ru) * | 2007-03-26 | 2012-07-27 | Курарей Ко., Лтд. | Полипропиленовые волокна, способы их получения и их применение |
| CN102186889B (zh) * | 2008-08-21 | 2013-11-06 | 陶氏环球技术有限责任公司 | 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 |
| EP2194070B1 (en) * | 2008-12-03 | 2012-08-22 | Süd-Chemie IP GmbH & Co. KG | Electron donor composition for a solid catalyst, solid catalyst composition used in the polymerisation of alpha-olefins, and process for the production of a polymer consisting of alpha-olefin units using the solid catalyst composition |
| KR101769275B1 (ko) | 2009-06-19 | 2017-08-18 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 내충격성 프로필렌 중합체 조성물의 제조 방법 |
| RU2525402C2 (ru) * | 2009-08-13 | 2014-08-10 | Чайна Петролеум Энд Кемикал Корпорейшн | Каталитический компонент для полимеризации олефинов и катализатор, включающий таковой |
| CN102372797A (zh) * | 2010-08-12 | 2012-03-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| US9969820B2 (en) | 2011-07-01 | 2018-05-15 | Basell Poliolefine Italia S.R.L. | Polypropylene films and sheets |
| JP6076328B2 (ja) * | 2012-02-20 | 2017-02-08 | サンアロマー株式会社 | シート成形用ポリプロピレン系樹脂組成物 |
| US9464178B2 (en) | 2012-10-31 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
| US9453093B2 (en) | 2012-10-31 | 2016-09-27 | Exxonmobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9522968B2 (en) | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| US20160046737A1 (en) * | 2013-03-15 | 2016-02-18 | Braskem America, Inc. | Propylene polymer resins |
| JP6235805B2 (ja) * | 2013-06-17 | 2017-11-22 | サンアロマー株式会社 | 二軸延伸フィルム用ポリプロピレン樹脂組成物 |
| JP6216887B2 (ja) | 2013-08-14 | 2017-10-18 | ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ | 低温における耐衝撃性が改善されたプロピレン組成物 |
| WO2015024887A1 (en) | 2013-08-21 | 2015-02-26 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| MX2016001705A (es) | 2013-08-21 | 2016-05-18 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| EP2853563B1 (en) | 2013-09-27 | 2016-06-15 | Borealis AG | Films suitable for BOPP processing from polymers with high XS and high Tm |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| US10519259B2 (en) | 2013-10-24 | 2019-12-31 | Borealis Ag | Low melting PP homopolymer with high content of regioerrors and high molecular weight |
| CA2927448C (en) | 2013-11-22 | 2017-01-17 | Borealis Ag | Low emission propylene homopolymer with high melt flow |
| ES2680589T3 (es) | 2013-11-22 | 2018-09-10 | Borealis Ag | Homopolímero de propileno de baja emisión |
| EP3077426B1 (en) | 2013-12-04 | 2022-10-05 | Borealis AG | Phthalate-free pp homopolymers for meltblown fibers |
| KR101873134B1 (ko) | 2013-12-18 | 2018-06-29 | 보레알리스 아게 | 향상된 강성/인성 균형을 가진 bopp 필름 |
| US9745431B2 (en) | 2013-12-18 | 2017-08-29 | Borealis Ag | BOPP film having low shrinkage |
| CN105829364B (zh) | 2014-01-17 | 2017-11-10 | 博里利斯股份公司 | 用于制备丙烯/1‑丁烯共聚物的方法 |
| BR112016017227B1 (pt) | 2014-02-06 | 2021-06-29 | Borealis Ag | Copolímero de propileno heterofásico, película não orientada, recipiente, e uso de um copolímero de propileno heterofásico |
| JP2017508032A (ja) | 2014-02-06 | 2017-03-23 | ボレアリス エージー | 高衝撃強さを有する軟質コポリマー |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| EP2947118B1 (en) | 2014-05-20 | 2017-11-29 | Borealis AG | Polypropylene composition for automotive interior applications |
| CN106574057A (zh) | 2014-06-25 | 2017-04-19 | 埃克森美孚化学专利公司 | 高熔体强度聚丙烯以及用于保持熔体强度的挤出方法 |
| EP3309183A1 (en) | 2016-10-14 | 2018-04-18 | SABIC Global Technologies B.V. | Polypropylene for use in bopp applications |
| EP3652221B1 (en) | 2017-07-13 | 2021-08-11 | ExxonMobil Chemical Patents Inc. | Process to produce strain hardened polypropylene |
| JP7780918B2 (ja) * | 2021-11-05 | 2025-12-05 | 住友化学株式会社 | プロピレン系重合体組成物、プロピレン系重合体組成物の製造方法、および、二軸延伸フィルム |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| WO2002030998A1 (en) * | 2000-10-13 | 2002-04-18 | Basell Technology Company B.V. | Catalyst components for the polymerization of olefins |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE363977B (https=) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4820772A (en) * | 1987-04-20 | 1989-04-11 | Chisso Corporation | Polyolefin composition |
| IT1246614B (it) * | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| US5286791A (en) * | 1992-05-29 | 1994-02-15 | Himont Incorporated | Impact modified graft copolymer compositions containing broad molecular weight distribution polypropylene |
| IT1260497B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Polimeri cristallini del propilene aventi migliorata processabilita' allo stato e processo per la loro preparazione |
| US7074871B2 (en) * | 1992-05-29 | 2006-07-11 | Basell Poliolefine Italia S.R.L. | Crystalline polymers of propylene having improved processability in the molten state and process for their preparation |
| IT1271420B (it) * | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| CN1213099C (zh) * | 1997-04-24 | 2005-08-03 | 三井化学株式会社 | 结晶性聚丙烯树脂组合物 |
| US6204335B1 (en) * | 1997-09-12 | 2001-03-20 | Eastman Chemical Company | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
| JP4864176B2 (ja) * | 1999-02-19 | 2012-02-01 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | ポリオレフィン製造 |
| DE60104238T2 (de) * | 2000-02-02 | 2005-07-28 | Basell Poliolefine Italia S.P.A. | Komponente und katalysatoren für polymerisation von olefinen |
| JP4206645B2 (ja) | 2001-03-27 | 2009-01-14 | 株式会社プライムポリマー | 結晶性ポリプロピレン樹脂組成物およびそれから製造されるシート |
| JP4485797B2 (ja) | 2001-12-24 | 2010-06-23 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ジアステレオアイソマーの分離 |
-
2003
- 2003-07-30 RU RU2005105593A patent/RU2325404C2/ru not_active IP Right Cessation
- 2003-07-30 KR KR1020057001697A patent/KR20050033639A/ko not_active Ceased
- 2003-07-30 CN CNB038185423A patent/CN100564399C/zh not_active Expired - Fee Related
- 2003-07-30 AU AU2003250201A patent/AU2003250201B2/en not_active Expired - Fee Related
- 2003-07-30 BR BR0306195A patent/BR0306195B1/pt active IP Right Grant
- 2003-07-30 US US10/522,957 patent/US7112642B2/en not_active Expired - Lifetime
- 2003-07-30 PL PL37450803A patent/PL374508A1/xx unknown
- 2003-07-30 WO PCT/EP2003/008491 patent/WO2004013193A2/en not_active Ceased
- 2003-07-30 CA CA 2492939 patent/CA2492939A1/en not_active Abandoned
- 2003-07-30 EP EP20030766382 patent/EP1527106A2/en not_active Ceased
- 2003-07-30 JP JP2004525402A patent/JP2005534761A/ja not_active Withdrawn
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- 2005-01-13 IL IL166300A patent/IL166300A/en not_active IP Right Cessation
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2006
- 2006-08-01 US US11/496,924 patent/US7772346B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| WO2002030998A1 (en) * | 2000-10-13 | 2002-04-18 | Basell Technology Company B.V. | Catalyst components for the polymerization of olefins |
Also Published As
| Publication number | Publication date |
|---|---|
| US20060264585A1 (en) | 2006-11-23 |
| CN100564399C (zh) | 2009-12-02 |
| US7772346B2 (en) | 2010-08-10 |
| KR20050033639A (ko) | 2005-04-12 |
| CN1675254A (zh) | 2005-09-28 |
| PL374508A1 (en) | 2005-10-31 |
| BR0306195B1 (pt) | 2012-12-25 |
| RU2325404C2 (ru) | 2008-05-27 |
| WO2004013193A3 (en) | 2004-03-25 |
| US20060009594A1 (en) | 2006-01-12 |
| WO2004013193A2 (en) | 2004-02-12 |
| US7112642B2 (en) | 2006-09-26 |
| RU2005105593A (ru) | 2005-07-20 |
| AU2003250201A1 (en) | 2004-02-23 |
| CA2492939A1 (en) | 2004-02-12 |
| IL166300A0 (en) | 2006-01-15 |
| EP1527106A2 (en) | 2005-05-04 |
| IL166300A (en) | 2008-12-29 |
| BR0306195A (pt) | 2004-10-19 |
| JP2005534761A (ja) | 2005-11-17 |
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