AU2001285789A1 - Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins - Google Patents
Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefinsInfo
- Publication number
- AU2001285789A1 AU2001285789A1 AU2001285789A AU8578901A AU2001285789A1 AU 2001285789 A1 AU2001285789 A1 AU 2001285789A1 AU 2001285789 A AU2001285789 A AU 2001285789A AU 8578901 A AU8578901 A AU 8578901A AU 2001285789 A1 AU2001285789 A1 AU 2001285789A1
- Authority
- AU
- Australia
- Prior art keywords
- bis
- hydrogen
- aryliminepyridine
- olefins
- metal atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyridine Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00305543 | 2000-06-30 | ||
EP00305543 | 2000-06-30 | ||
PCT/EP2001/007419 WO2002000339A2 (en) | 2000-06-30 | 2001-06-28 | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001285789A1 true AU2001285789A1 (en) | 2002-01-08 |
Family
ID=8173092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001285789A Abandoned AU2001285789A1 (en) | 2000-06-30 | 2001-06-28 | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
Country Status (13)
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6710006B2 (en) * | 2000-02-09 | 2004-03-23 | Shell Oil Company | Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins |
US6534691B2 (en) * | 2000-07-18 | 2003-03-18 | E. I. Du Pont De Nemours And Company | Manufacturing process for α-olefins |
US7037988B2 (en) * | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
ES2272770T3 (es) * | 2001-08-01 | 2007-05-01 | Shell Internationale Research Maatschappij B.V. | Ligandos y sistemas cataliticos derivados de ellos para oligomerizacion de etileno a alfa-olefinas lineales. |
US6911506B2 (en) | 2001-12-10 | 2005-06-28 | Chevron Phillips Chemical Company Lp | Catalyst composition and olefin polymerization using same |
ES2324030T3 (es) * | 2002-09-25 | 2009-07-29 | Shell Internationale Research Maatschappij B.V. | Procedimiento para producir un oligomero de alfa-olefina lineal usando un intercambiador de calor. |
ATE327826T1 (de) * | 2002-09-25 | 2006-06-15 | Shell Int Research | Katalysatorsysteme für die ethylen- oligomerisierung zu linearen alpha-olefinen |
US7045632B2 (en) * | 2003-03-04 | 2006-05-16 | Chevron Phillips Chemical Company, Lp | Composition and method for a hexadentate ligand and bimetallic complex for polymerization of olefins |
US20050014983A1 (en) * | 2003-07-07 | 2005-01-20 | De Boer Eric Johannes Maria | Process for producing linear alpha olefins |
US7081506B2 (en) * | 2003-10-23 | 2006-07-25 | Fina Technology, Inc. | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components |
US7034157B2 (en) * | 2003-10-23 | 2006-04-25 | Fina Technology, Inc. | Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins |
US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
US7384886B2 (en) | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US20050187098A1 (en) | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
US7429684B2 (en) | 2004-02-27 | 2008-09-30 | Exxonmobile Research And Engineering Company | Process for oligomerization of ethylene to linear α-olefins |
JP5065886B2 (ja) | 2004-03-24 | 2012-11-07 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 遷移金属錯体 |
DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
GB0412432D0 (en) * | 2004-06-03 | 2004-07-07 | Clements Roger | Carbonation of a liquid |
US7442819B2 (en) * | 2004-07-09 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
AR049714A1 (es) * | 2004-07-13 | 2006-08-30 | Shell Int Research | Proceso de preparacion de alfa olefinas lineales |
US7456284B2 (en) * | 2004-12-10 | 2008-11-25 | Chevron Phillips Chemical Company Lp | Methods for producing a hexadentate bimetallic complex |
US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
US7129304B1 (en) | 2005-07-21 | 2006-10-31 | Chevron Phillips Chemical Company Lp | Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
WO2007021955A2 (en) * | 2005-08-11 | 2007-02-22 | E. I. Du Pont De Nemours And Company | NITRO SUBSTITUTED α-OLEFIN SYNTHESIS CATALYSTS |
DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
US7378537B2 (en) | 2006-07-25 | 2008-05-27 | Chevron Phillips Chemical Company Lp | Olefin oligomerization catalysts and methods of using same |
DE102007017903A1 (de) * | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
CN102712715B (zh) * | 2010-01-21 | 2014-10-29 | 巴塞尔聚烯烃股份有限公司 | 在低聚催化剂存在下制备乙烯共聚物组合物的方法 |
EP2552974A1 (en) | 2010-03-29 | 2013-02-06 | E.I. Du Pont De Nemours And Company | Production of alpha-olefins |
US20140088275A1 (en) * | 2011-05-12 | 2014-03-27 | Basell Polyolefine Gmbh | Process for the manufacture of a mixed catalyst system for the copolymerization of ethylene with c1-c12 alpha-olefins |
US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
ES2624430T3 (es) * | 2013-02-11 | 2017-07-14 | Linde Ag | Método de purificación de un compuesto crudo de PNPNH |
CN106432357B (zh) * | 2015-08-10 | 2019-03-08 | 中国科学院化学研究所 | 苯代-2,9-二亚胺吡啶并环庚烷铁和钴配合物催化剂及其制备方法与应用 |
US10513473B2 (en) | 2015-09-18 | 2019-12-24 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
US10519077B2 (en) | 2015-09-18 | 2019-12-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
CN105712927B (zh) * | 2016-01-21 | 2017-12-01 | 合肥工业大学 | 一种钴配合物制备及其合成方法 |
US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
US10604457B2 (en) | 2016-12-29 | 2020-03-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
US20180186708A1 (en) | 2016-12-29 | 2018-07-05 | Chevron Phillips Chemical Company Lp | Ethylene Oligomerization Processes |
WO2018125826A1 (en) | 2016-12-29 | 2018-07-05 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
US10407360B2 (en) | 2017-12-22 | 2019-09-10 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
AR124330A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124323A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124328A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | Un catalizador de oligomerización, método de preparación y proceso para usar el catalizador |
AR124321A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124322A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124326A1 (es) * | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124325A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124333A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124329A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124331A1 (es) | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124324A1 (es) * | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
AR124332A1 (es) * | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
US20240400473A1 (en) | 2023-04-27 | 2024-12-05 | Chevron Phillips Chemical Company Lp | Catalyst system and ethylene oligomerization process for the preparation of linear alpha olefins |
WO2024227723A2 (en) * | 2023-05-02 | 2024-11-07 | Topsoe A/S | Process and plant for producing synthetic paraffinic kerosene as jet fuel |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
US6103946A (en) | 1997-07-15 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Manufacture of α-olefins |
GB9819847D0 (en) * | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
-
2001
- 2001-06-27 GC GCP20011458 patent/GC0000291A/en active
- 2001-06-28 CA CA002413469A patent/CA2413469A1/en not_active Abandoned
- 2001-06-28 DE DE60109773T patent/DE60109773T2/de not_active Expired - Fee Related
- 2001-06-28 EP EP01965049A patent/EP1294482B1/en not_active Expired - Lifetime
- 2001-06-28 BR BR0112143-0A patent/BR0112143A/pt not_active Application Discontinuation
- 2001-06-28 JP JP2002505112A patent/JP2004501876A/ja not_active Withdrawn
- 2001-06-28 AT AT01965049T patent/ATE291963T1/de not_active IP Right Cessation
- 2001-06-28 AU AU2001285789A patent/AU2001285789A1/en not_active Abandoned
- 2001-06-28 WO PCT/EP2001/007419 patent/WO2002000339A2/en active IP Right Grant
- 2001-06-28 US US09/894,680 patent/US6683187B2/en not_active Expired - Fee Related
- 2001-06-28 CN CNB018120911A patent/CN1178916C/zh not_active Expired - Fee Related
- 2001-06-28 MY MYPI20013091 patent/MY133984A/en unknown
-
2003
- 2003-01-08 ZA ZA200300193A patent/ZA200300193B/en unknown
Also Published As
Publication number | Publication date |
---|---|
ZA200300193B (en) | 2003-11-13 |
US6683187B2 (en) | 2004-01-27 |
CA2413469A1 (en) | 2002-01-03 |
GC0000291A (en) | 2006-11-01 |
DE60109773T2 (de) | 2006-04-13 |
CN1440311A (zh) | 2003-09-03 |
JP2004501876A (ja) | 2004-01-22 |
DE60109773D1 (de) | 2005-05-04 |
ATE291963T1 (de) | 2005-04-15 |
US20020028941A1 (en) | 2002-03-07 |
EP1294482B1 (en) | 2005-03-30 |
WO2002000339A3 (en) | 2002-05-10 |
MY133984A (en) | 2007-11-30 |
EP1294482A2 (en) | 2003-03-26 |
BR0112143A (pt) | 2003-05-06 |
WO2002000339A2 (en) | 2002-01-03 |
CN1178916C (zh) | 2004-12-08 |
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