ATE480510T1 - Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen - Google Patents

Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen

Info

Publication number
ATE480510T1
ATE480510T1 AT05723816T AT05723816T ATE480510T1 AT E480510 T1 ATE480510 T1 AT E480510T1 AT 05723816 T AT05723816 T AT 05723816T AT 05723816 T AT05723816 T AT 05723816T AT E480510 T1 ATE480510 T1 AT E480510T1
Authority
AT
Austria
Prior art keywords
oxidation
aeoobic
primary
catalyst system
aldehydes
Prior art date
Application number
AT05723816T
Other languages
English (en)
Inventor
Setrak Tanielyan
Robert Augustine
Indra Prakash
Kenneth Furlong
Handley Jackson
Original Assignee
Nutrasweet Property Holdings I
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nutrasweet Property Holdings I filed Critical Nutrasweet Property Holdings I
Application granted granted Critical
Publication of ATE480510T1 publication Critical patent/ATE480510T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/006—Catalysts comprising hydrides, coordination complexes or organic compounds comprising organic radicals, e.g. TEMPO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
AT05723816T 2004-02-26 2005-02-24 Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen ATE480510T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US54783704P 2004-02-26 2004-02-26
PCT/US2005/006112 WO2005082825A1 (en) 2004-02-26 2005-02-24 Catalyst system for aeorobic oxidation of primary and secondary alcohols.

Publications (1)

Publication Number Publication Date
ATE480510T1 true ATE480510T1 (de) 2010-09-15

Family

ID=34910946

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05723816T ATE480510T1 (de) 2004-02-26 2005-02-24 Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen

Country Status (8)

Country Link
US (1) US7351867B2 (de)
EP (1) EP1718590B1 (de)
JP (1) JP5094381B2 (de)
KR (1) KR20060129510A (de)
AT (1) ATE480510T1 (de)
DE (1) DE602005023413D1 (de)
ES (1) ES2347576T3 (de)
WO (1) WO2005082825A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1666441A1 (de) * 2004-12-03 2006-06-07 Daiso Co., Ltd. Verfahren zur Oxidation von primären und sekundären Alkoholen
US7030279B1 (en) * 2004-12-23 2006-04-18 Degussa Ag Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals
JP4925050B2 (ja) * 2007-02-22 2012-04-25 独立行政法人科学技術振興機構 カルボニル化合物の製法
RU2514962C2 (ru) * 2007-11-26 2014-05-10 Дублин Инститьют Оф Текнолоджи Интеллекчуал Проперти Лимитед Органосилановые композиции для покрытий и их использование
CN101632941B (zh) * 2008-07-22 2011-08-24 郑州大学 一种分子氧选择氧化醇制备醛或酮的催化剂及其应用
CZ2009835A3 (cs) * 2009-12-11 2011-06-22 Contipro C A.S. Zpusob prípravy derivátu kyseliny hyaluronové oxidovaného v poloze 6 glukosaminové cásti polysacharidu selektivne na aldehyd a zpusob jeho modifikace
CN103772082B (zh) 2010-07-26 2016-01-20 华东师范大学 一种氧气氧化醇制备醛或酮的方法
CN101914000B (zh) * 2010-08-18 2013-02-27 北京航空航天大学 一种无催化反应制备醛或酮的方法
CN102391084A (zh) * 2011-09-28 2012-03-28 南京大学 催化氧化苯甲醇制备苯甲醛的方法
FR2984889B1 (fr) * 2011-12-22 2017-02-24 Roquette Freres Procede ameliore d'oxydation selective du 5-hydromethyl furaldehyde
JP6014486B2 (ja) * 2011-12-26 2016-10-25 公益財団法人相模中央化学研究所 ビス（アセチルアセトナト）オキソバナジウム（ｉｖ）を用いたファルネサールの製造方法
JP6002572B2 (ja) * 2011-12-26 2016-10-05 公益財団法人相模中央化学研究所 ビス（アセチルアセトナト）ジオキソモリブデン（ｖｉ）を用いたファルネサールの製造方法
KR101459378B1 (ko) * 2013-03-06 2014-11-07 서울과학기술대학교 산학협력단 신규한 복핵 Fe 착화합물, 이를 포함하는 자성 물질 및 알코올 산화반응 촉매
US10005718B2 (en) 2014-02-07 2018-06-26 Sumitomo Chemical Company, Limited Catalyst, and method for producing oxidation product
SG11201807445TA (en) 2016-03-01 2018-09-27 Kuraray Co Method of producing dialdehyde compound
KR102146324B1 (ko) 2016-06-02 2020-08-21 에보니크 오퍼레이션즈 게엠베하 전극 물질을 제조하는 방법
EP3500547B1 (de) * 2016-08-16 2023-10-11 Organofuel Sweden AB Umwandlung von alkoholen in lineare und verzweigte funktionalisierte alkane
US11001659B1 (en) 2016-09-06 2021-05-11 Evonik Operations Gmbh Method for the improved oxidation of secondary amine groups
CN110368928B (zh) * 2019-07-29 2022-05-17 陕西科技大学 一种用于苯甲醇氧化合成苯甲醛的催化剂及其制备方法和应用
CN111085267B (zh) * 2019-11-18 2022-11-25 湖北大学 一种聚合物负载Cu/TEMPO催化剂及其制备方法与应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5973209A (en) * 1997-07-11 1999-10-26 The Nutrasweet Company Method for preparing 3, 3-dimethybutyraldehyde
US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
US5905175A (en) 1998-05-20 1999-05-18 The Nutrasweet Company Synthesis and purification of 3,3-dimethylbutyraldehyde via oxidation of 1-chloro-3,3-dimethylbutane with dimethyl sulfoxide
US6825384B1 (en) * 2004-01-29 2004-11-30 The Nutrasweet Company Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant

Also Published As

Publication number Publication date
EP1718590B1 (de) 2010-09-08
US7351867B2 (en) 2008-04-01
WO2005082825A1 (en) 2005-09-09
JP5094381B2 (ja) 2012-12-12
US20070078284A1 (en) 2007-04-05
JP2007525522A (ja) 2007-09-06
EP1718590A1 (de) 2006-11-08
EP1718590A4 (de) 2008-02-27
KR20060129510A (ko) 2006-12-15
ES2347576T3 (es) 2010-11-02
DE602005023413D1 (de) 2010-10-21

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