ATE309186T1 - Chirale liganden, ihre übergangsmetallkomplexe und die anwendung dieser in asymmetrischen reaktionen - Google Patents

Chirale liganden, ihre übergangsmetallkomplexe und die anwendung dieser in asymmetrischen reaktionen

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Publication number
ATE309186T1
ATE309186T1 AT00961346T AT00961346T ATE309186T1 AT E309186 T1 ATE309186 T1 AT E309186T1 AT 00961346 T AT00961346 T AT 00961346T AT 00961346 T AT00961346 T AT 00961346T AT E309186 T1 ATE309186 T1 AT E309186T1
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Austria
Prior art keywords
chiral ligands
asymmetric
ligands
transition metal
metal complexes
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Application number
AT00961346T
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English (en)
Inventor
Xumu Zhang
Dengming Xiao
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Penn State Res Found
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Publication of ATE309186T1 publication Critical patent/ATE309186T1/de

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    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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AT00961346T 1999-08-23 2000-08-22 Chirale liganden, ihre übergangsmetallkomplexe und die anwendung dieser in asymmetrischen reaktionen ATE309186T1 (de)

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US6750373B2 (en) 2001-05-18 2004-06-15 Shell Oil Company One-step production of 1, 3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst
TW593239B (en) * 2001-06-04 2004-06-21 Kevin Dale Allen One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a phospholanoalkane ligand
DE10150335A1 (de) * 2001-10-15 2003-04-24 Degussa Neue chirale Liganden und deren Übergangsmetallkomplexe sowie deren katalytische Anwendung
US20040072680A1 (en) * 2002-04-26 2004-04-15 The Penn State Research Foundation Chiral phosphorus cyclic compounds for transition metal-catalyzed asymmetric reactions
CA2500107A1 (en) 2002-09-26 2004-04-08 Shell Internationale Research Maatschappij B.V. Process for the production of primary alcohols
CN100363319C (zh) * 2002-09-26 2008-01-23 国际壳牌研究有限公司 利用双齿二膦组合物使烯属不饱和化合物加氢甲酰化的方法
US8461072B2 (en) * 2002-10-25 2013-06-11 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin oligomerizations
US20040147762A1 (en) * 2002-11-06 2004-07-29 Xumu Zhang Asymmetric reductive amination of ketones
CN101952298B (zh) * 2007-12-12 2015-06-17 麻省理工学院 用于过渡金属催化的交联偶合反应的配体及其使用方法
KR101245065B1 (ko) * 2008-04-17 2013-03-18 유나이티드 포스포러스 리미티드 이민의 수소화
CN102807463A (zh) * 2011-06-01 2012-12-05 同济大学 一种经过渡金属催化合成手性含硫化合物的方法
WO2014109712A1 (en) * 2013-01-11 2014-07-17 Nanayng Technological University PALLADIUM-CATALYZED ASYMMETRIC (HETERO)ARYLATION AND VINYLATION OF KETONE ENOLATES TO PRODUCE TERTIARY STEREOCENTERS AT ALPHA(α)-POSITION
WO2016119758A1 (zh) * 2015-01-30 2016-08-04 四川海思科制药有限公司 一种手性的2-[1-环丙基乙基]-6-异丙基-苯酚的制备方法
PT108303A (pt) 2015-03-20 2016-09-20 Sapec Agro S A Processo de produção de (s)-metolacloro
CN108218726B (zh) * 2016-12-14 2020-08-18 浙江省化工研究院有限公司 一种制备(s)-mea胺醚的方法
CN109180514A (zh) * 2018-07-03 2019-01-11 浙江禾本科技有限公司 一种旋光性甲霜灵的合成方法
CN111875474B (zh) * 2020-07-30 2022-10-04 浙江工业大学 一种(r,e)-4-苯基丁基-3-烯-2-醇衍生物的制备方法
CN114644614B (zh) * 2021-04-21 2023-03-28 黄冈中有生物科技有限公司 一种左旋烟碱的制备方法

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ATE259819T1 (de) * 1996-06-14 2004-03-15 Penn State Res Found Durch übergangsmetallkomplexe mit zyklischen chiralen liganden katalysierte asymmetrische synthese

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JP4837857B2 (ja) 2011-12-14
WO2001014299A1 (en) 2001-03-01
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EP1206427B1 (de) 2005-11-09
AU7330900A (en) 2001-03-19
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US6525210B1 (en) 2003-02-25
HK1046267A1 (zh) 2003-01-03
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