ATE234825T1 - Verfahren zur direktoxidation von olefinen zu olefinoxiden - Google Patents

Verfahren zur direktoxidation von olefinen zu olefinoxiden

Info

Publication number
ATE234825T1
ATE234825T1 AT99964088T AT99964088T ATE234825T1 AT E234825 T1 ATE234825 T1 AT E234825T1 AT 99964088 T AT99964088 T AT 99964088T AT 99964088 T AT99964088 T AT 99964088T AT E234825 T1 ATE234825 T1 AT E234825T1
Authority
AT
Austria
Prior art keywords
titanium
olefin
catalyst
direct oxidation
silica
Prior art date
Application number
AT99964088T
Other languages
German (de)
English (en)
Inventor
Robert G Bowman
Howard W Clark
Alex Kuperman
George E Hartwell
Garmt R Meima
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE234825T1 publication Critical patent/ATE234825T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/50Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT99964088T 1998-12-16 1999-12-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden ATE234825T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11242998P 1998-12-16 1998-12-16
PCT/US1999/028699 WO2000035893A1 (en) 1998-12-16 1999-12-07 Process for the direct oxidation of olefins to olefin oxides

Publications (1)

Publication Number Publication Date
ATE234825T1 true ATE234825T1 (de) 2003-04-15

Family

ID=22343859

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99964088T ATE234825T1 (de) 1998-12-16 1999-12-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden

Country Status (12)

Country Link
US (1) US6646142B1 (enExample)
EP (1) EP1140883B1 (enExample)
JP (1) JP2002532482A (enExample)
KR (1) KR20010082357A (enExample)
CN (1) CN1172921C (enExample)
AT (1) ATE234825T1 (enExample)
AU (1) AU756230B2 (enExample)
BR (1) BR9917025B1 (enExample)
DE (1) DE69906136T2 (enExample)
ES (1) ES2190280T3 (enExample)
ID (1) ID29813A (enExample)
WO (1) WO2000035893A1 (enExample)

Families Citing this family (34)

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US6562986B2 (en) * 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
BR0016486A (pt) 1999-12-09 2002-11-26 Dow Chemical Co Processo para ativar ou regenerar um catalisador de hidro-oxidação
DE60109704D1 (de) 2000-10-25 2005-05-04 Mitsubishi Chem Corp Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
US6281369B1 (en) 2000-12-07 2001-08-28 Arco Chemical Technology, L.P. Epoxidation catalyst and process
US6310224B1 (en) 2001-01-19 2001-10-30 Arco Chemical Technology, L.P. Epoxidation catalyst and process
DE60210087T2 (de) 2001-08-01 2007-03-08 Dow Global Technologies, Inc., Midland Verfahren zur standzeitverlängerung eines hydrooxidationskatalysators
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
US7256149B2 (en) * 2004-02-24 2007-08-14 Lyondell Chemical Technology, L.P. Catalyst regeneration process
EP1735095A1 (en) * 2004-04-01 2006-12-27 Dow Gloval Technologies Inc. Hydro-oxidation of hydrocarbons using catalyst prepared by microwave heating
US7273826B2 (en) * 2005-07-26 2007-09-25 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US7615654B2 (en) * 2005-10-20 2009-11-10 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7432384B2 (en) * 2005-10-25 2008-10-07 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7365217B2 (en) * 2006-01-25 2008-04-29 Lyondell Chemical Technology, L.P. Oxidation process
US7238817B1 (en) 2006-02-22 2007-07-03 Lyondell Chemical Technology, L.P. Direct epoxidation process
MY145792A (en) * 2006-11-17 2012-04-30 Dow Global Technologies Inc Hydro-oxidation process using a catalyst prepared from a gold cluster complex
US7381675B1 (en) 2006-12-19 2008-06-03 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst
US7563740B2 (en) * 2006-12-19 2009-07-21 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7696367B2 (en) * 2007-04-10 2010-04-13 Lyondell Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US7387981B1 (en) 2007-06-28 2008-06-17 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst and process
US20090042718A1 (en) * 2007-08-10 2009-02-12 Kaminsky Mark P Direct epoxidation catalyst and process
US7453003B1 (en) 2007-08-29 2008-11-18 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst and process
US7648936B2 (en) * 2008-01-29 2010-01-19 Lyondell Chemical Technology, L.P. Spray-dried transition metal zeolite and its use
WO2011145487A1 (en) * 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing olefin oxide
WO2011145486A1 (en) * 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing olefin oxide
CN103121983B (zh) * 2011-11-18 2015-01-07 中国石油化工股份有限公司 氯丙烯环氧化反应的方法
CN107960063B (zh) * 2015-08-28 2021-08-24 利安德化学技术有限公司 环氧化工艺及其使用的催化剂
KR101992075B1 (ko) * 2015-12-02 2019-06-21 라이온델 케미칼 테크놀로지, 엘.피. 브루카이트형 티타늄을 함유한 촉매
CN109721568A (zh) * 2017-10-27 2019-05-07 中国石油化工股份有限公司 一种固体酸催化氧化烯烃的方法
WO2021067224A1 (en) * 2019-09-30 2021-04-08 Dow Global Technologies Llc Metallosilicate catalyst regeneration
CN111716841B (zh) * 2020-06-10 2022-03-29 南通纺织丝绸产业技术研究院 一种防丙烯口罩及其制备方法
EP4163274A4 (en) * 2020-07-10 2023-12-13 China Petroleum & Chemical Corporation PROCESS FOR PREPARING PROPYLENE OXIDE BY DIRECT EPOXIDATION OF PROPYLENE
CN113912571B (zh) * 2020-07-10 2023-12-05 中国石油化工股份有限公司 丙烯直接环氧化以制备环氧丙烷的方法
CN115999529B (zh) * 2022-12-26 2025-02-07 中国科学技术大学 一种催化剂及制备方法以及催化甲醇制备环氧乙烷的方法

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US6255499B1 (en) 1999-04-08 2001-07-03 The Dow Chemical Company Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst
BR0011158B1 (pt) 1999-04-08 2011-06-14 mÉtodo para preparar um catalisador e composiÇço de catalisador compreendendo ouro sobre um suporte contendo titÂnio.
BR0016486A (pt) 1999-12-09 2002-11-26 Dow Chemical Co Processo para ativar ou regenerar um catalisador de hidro-oxidação

Also Published As

Publication number Publication date
JP2002532482A (ja) 2002-10-02
DE69906136D1 (de) 2003-04-24
BR9917025A (pt) 2001-09-25
CN1172921C (zh) 2004-10-27
US6646142B1 (en) 2003-11-11
AU756230B2 (en) 2003-01-09
WO2000035893A1 (en) 2000-06-22
EP1140883A1 (en) 2001-10-10
BR9917025B1 (pt) 2010-10-19
EP1140883B1 (en) 2003-03-19
CN1330644A (zh) 2002-01-09
ES2190280T3 (es) 2003-07-16
ID29813A (id) 2001-10-11
KR20010082357A (ko) 2001-08-29
AU2040100A (en) 2000-07-03
DE69906136T2 (de) 2004-01-08

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