ATE234825T1 - Verfahren zur direktoxidation von olefinen zu olefinoxiden - Google Patents

Verfahren zur direktoxidation von olefinen zu olefinoxiden

Info

Publication number
ATE234825T1
ATE234825T1 AT99964088T AT99964088T ATE234825T1 AT E234825 T1 ATE234825 T1 AT E234825T1 AT 99964088 T AT99964088 T AT 99964088T AT 99964088 T AT99964088 T AT 99964088T AT E234825 T1 ATE234825 T1 AT E234825T1
Authority
AT
Austria
Prior art keywords
titanium
olefin
catalyst
direct oxidation
silica
Prior art date
Application number
AT99964088T
Other languages
English (en)
Inventor
Robert G Bowman
Howard W Clark
Alex Kuperman
George E Hartwell
Garmt R Meima
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE234825T1 publication Critical patent/ATE234825T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT99964088T 1998-12-16 1999-12-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden ATE234825T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11242998P 1998-12-16 1998-12-16
PCT/US1999/028699 WO2000035893A1 (en) 1998-12-16 1999-12-07 Process for the direct oxidation of olefins to olefin oxides

Publications (1)

Publication Number Publication Date
ATE234825T1 true ATE234825T1 (de) 2003-04-15

Family

ID=22343859

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99964088T ATE234825T1 (de) 1998-12-16 1999-12-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden

Country Status (12)

Country Link
US (1) US6646142B1 (de)
EP (1) EP1140883B1 (de)
JP (1) JP2002532482A (de)
KR (1) KR20010082357A (de)
CN (1) CN1172921C (de)
AT (1) ATE234825T1 (de)
AU (1) AU756230B2 (de)
BR (1) BR9917025B1 (de)
DE (1) DE69906136T2 (de)
ES (1) ES2190280T3 (de)
ID (1) ID29813A (de)
WO (1) WO2000035893A1 (de)

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US6562986B2 (en) * 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
AU770334B2 (en) 1999-12-09 2004-02-19 Dow Global Technologies Inc. Activation and regeneration of a hydro-oxidation catalyst
EP1201301B1 (de) * 2000-10-25 2005-03-30 Mitsubishi Chemical Corporation Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
US6281369B1 (en) † 2000-12-07 2001-08-28 Arco Chemical Technology, L.P. Epoxidation catalyst and process
US6310224B1 (en) * 2001-01-19 2001-10-30 Arco Chemical Technology, L.P. Epoxidation catalyst and process
BR0211796A (pt) 2001-08-01 2004-08-03 Dow Global Technologies Inc Método para aumentar a vida útil de um catalisador de hidro-oxidação
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
US7256149B2 (en) * 2004-02-24 2007-08-14 Lyondell Chemical Technology, L.P. Catalyst regeneration process
WO2005102525A1 (en) * 2004-04-01 2005-11-03 Dow Global Technologies Inc. Hydro-oxidation of hydrocarbons using catalyst prepared by microwave heating
US7273826B2 (en) * 2005-07-26 2007-09-25 Lyondell Chemical Technology, L.P. Epoxidation catalyst
US7615654B2 (en) * 2005-10-20 2009-11-10 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7432384B2 (en) * 2005-10-25 2008-10-07 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7365217B2 (en) * 2006-01-25 2008-04-29 Lyondell Chemical Technology, L.P. Oxidation process
US7238817B1 (en) 2006-02-22 2007-07-03 Lyondell Chemical Technology, L.P. Direct epoxidation process
CN101534941B (zh) * 2006-11-17 2012-07-18 陶氏环球技术公司 使用由金簇配合物制备的催化剂的氢化-氧化方法
US7563740B2 (en) * 2006-12-19 2009-07-21 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7381675B1 (en) 2006-12-19 2008-06-03 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst
US7696367B2 (en) * 2007-04-10 2010-04-13 Lyondell Chemical Technology, L.P. Direct epoxidation process using a mixed catalyst system
US7387981B1 (en) 2007-06-28 2008-06-17 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst and process
US20090042718A1 (en) * 2007-08-10 2009-02-12 Kaminsky Mark P Direct epoxidation catalyst and process
US7453003B1 (en) 2007-08-29 2008-11-18 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst and process
US7648936B2 (en) * 2008-01-29 2010-01-19 Lyondell Chemical Technology, L.P. Spray-dried transition metal zeolite and its use
WO2011145486A1 (en) * 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing olefin oxide
WO2011145487A1 (en) * 2010-05-17 2011-11-24 Sumitomo Chemical Company, Limited Method for producing olefin oxide
CN103121983B (zh) * 2011-11-18 2015-01-07 中国石油化工股份有限公司 氯丙烯环氧化反应的方法
WO2017040121A1 (en) 2015-08-28 2017-03-09 Lyondell Chemical Technology, L.P. Epoxidation processes and catalysts for use therein
JP6646747B2 (ja) * 2015-12-02 2020-02-14 ライオンデル ケミカル テクノロジー、エル．ピー． ブルッカイト型チタニウムを含有する触媒
CN109721568A (zh) * 2017-10-27 2019-05-07 中国石油化工股份有限公司 一种固体酸催化氧化烯烃的方法
CN111716841B (zh) * 2020-06-10 2022-03-29 南通纺织丝绸产业技术研究院 一种防丙烯口罩及其制备方法
US20230339875A1 (en) * 2020-07-10 2023-10-26 China Petroleum & Chemical Corporation Method for preparing propylene oxide by means of direct epoxidation of propylene
CN113912571B (zh) * 2020-07-10 2023-12-05 中国石油化工股份有限公司 丙烯直接环氧化以制备环氧丙烷的方法

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Also Published As

Publication number Publication date
AU756230B2 (en) 2003-01-09
US6646142B1 (en) 2003-11-11
KR20010082357A (ko) 2001-08-29
WO2000035893A1 (en) 2000-06-22
ID29813A (id) 2001-10-11
BR9917025A (pt) 2001-09-25
CN1172921C (zh) 2004-10-27
AU2040100A (en) 2000-07-03
EP1140883A1 (de) 2001-10-10
ES2190280T3 (es) 2003-07-16
CN1330644A (zh) 2002-01-09
DE69906136D1 (de) 2003-04-24
DE69906136T2 (de) 2004-01-08
JP2002532482A (ja) 2002-10-02
BR9917025B1 (pt) 2010-10-19
EP1140883B1 (de) 2003-03-19

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