ATE219091T1 - Hochwirksame kationische ruthenium und osmiumkomplexe für die metathesereaktionen - Google Patents
Hochwirksame kationische ruthenium und osmiumkomplexe für die metathesereaktionenInfo
- Publication number
- ATE219091T1 ATE219091T1 AT98965675T AT98965675T ATE219091T1 AT E219091 T1 ATE219091 T1 AT E219091T1 AT 98965675 T AT98965675 T AT 98965675T AT 98965675 T AT98965675 T AT 98965675T AT E219091 T1 ATE219091 T1 AT E219091T1
- Authority
- AT
- Austria
- Prior art keywords
- metathesis
- reactions
- catalysts
- types
- olefins
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical class [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- -1 acyclic dienes Chemical class 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000010535 acyclic diene metathesis reaction Methods 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 239000012018 catalyst precursor Substances 0.000 abstract 2
- 238000005649 metathesis reaction Methods 0.000 abstract 2
- 229910052762 osmium Inorganic materials 0.000 abstract 2
- 150000004291 polyenes Chemical class 0.000 abstract 2
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 2
- 238000007152 ring opening metathesis polymerisation reaction Methods 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 1
- 238000005865 alkene metathesis reaction Methods 0.000 abstract 1
- 125000000860 allenylidene group Chemical group [*]=C=C=C([H])[H] 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000005686 cross metathesis reaction Methods 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97121228A EP0921129A1 (de) | 1997-12-03 | 1997-12-03 | Hochwirksame kationische Ruthenium- und Osmiumkomplexe für die Olefinmetathese-Reaktionen |
| PCT/EP1998/007364 WO1999028330A1 (en) | 1997-12-03 | 1998-11-17 | Highly active cationic ruthenium and osmium complexes for olefin metathesis reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE219091T1 true ATE219091T1 (de) | 2002-06-15 |
Family
ID=8227727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT98965675T ATE219091T1 (de) | 1997-12-03 | 1998-11-17 | Hochwirksame kationische ruthenium und osmiumkomplexe für die metathesereaktionen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6590048B1 (de) |
| EP (2) | EP0921129A1 (de) |
| JP (1) | JP2001525330A (de) |
| AT (1) | ATE219091T1 (de) |
| CA (1) | CA2312755A1 (de) |
| DE (1) | DE69806053T2 (de) |
| WO (1) | WO1999028330A1 (de) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6900347B2 (en) | 1998-09-01 | 2005-05-31 | Tilliechem, Inc. | Impurity inhibition in olefin metathesis reactions |
| US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
| US7507854B2 (en) | 1998-09-01 | 2009-03-24 | Materia, Inc. | Impurity reduction in Olefin metathesis reactions |
| ATE438462T1 (de) | 1998-09-10 | 2009-08-15 | Univ New Orleans Foundation | Katalysatorkomplex mit phenylindenyliden-ligand |
| EP1240122A1 (de) * | 1999-12-21 | 2002-09-18 | Sasol Technology (Proprietary) Limited | Metatheseverfahren zur umsetzung von olefinen mit kurzen kette in olefinen mit langeren kette |
| WO2002020535A1 (en) * | 2000-09-05 | 2002-03-14 | California Institute Of Technology | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
| DE10113963A1 (de) * | 2001-03-22 | 2002-09-26 | Haarmann & Reimer Gmbh | Verfahren zur Herstellung von 15-Pentadecanolid |
| BE1014952A3 (nl) * | 2001-10-03 | 2004-07-06 | Ineos Nv | Katalysator op basis van schiffse base ruthenium of osmium complexen, de vervaardiging en het gebruik daarvan in olefine metathese, atrp en kharasch reacties. |
| ATE405133T1 (de) * | 2002-02-11 | 2008-08-15 | Dartmouth College | Systeme und verfahren zum ändern einer eis-objekt grenzfläche |
| JP4011022B2 (ja) * | 2002-03-11 | 2007-11-21 | 独立行政法人科学技術振興機構 | 高分子固定化アレンルテニウム錯体とその触媒並びにこれを用いた有機合成反応方法 |
| US6939982B2 (en) * | 2002-05-15 | 2005-09-06 | The Trustees Of Boston College | Recyclable chiral metathesis catalysts |
| US7094898B2 (en) * | 2003-05-29 | 2006-08-22 | University Of Ottawa | Ruthenium compounds, their production and use |
| DE10344690A1 (de) * | 2003-09-25 | 2005-04-14 | Basf Ag | Verfahren zur Herstellung von 1,7-Octadien und dessen Verwendung |
| ZA200700170B (en) * | 2004-06-09 | 2008-05-28 | Uti Limited Partnership | Transition metal carbene complexes containing a cationi substituent as catalysts of olefin metathesis reactions |
| US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
| WO2009124853A1 (en) * | 2008-04-11 | 2009-10-15 | F. Hoffmann-La Roche Ag | New ruthenium complexes as catalysts for metathesis reactions |
| FR2939331B1 (fr) | 2008-12-10 | 2012-08-10 | Inst Francais Du Petrole | Composition catalytique et procede de metathese de corps gras insature |
| JP5454764B2 (ja) * | 2009-03-09 | 2014-03-26 | 国立大学法人 千葉大学 | ビアリール化合物を製造する方法 |
| US8863345B2 (en) * | 2009-12-18 | 2014-10-21 | Colgate-Palmolive Company | Oral care implement having a closed-loop arrangement of cleaning elements |
| US8656638B2 (en) * | 2010-03-25 | 2014-02-25 | Cheryl D. Stevenson | Compounds and processes that generate cyclopropenes and substituted cyclopropenes on demand |
| CN103974772B (zh) * | 2011-10-21 | 2017-03-29 | 阿朗新科德国有限责任公司 | 包括钌或锇卡宾络合物和末端烯烃的催化剂组合物及其用于氢化丁腈橡胶的用途 |
| WO2013056461A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| CN103987755B (zh) * | 2011-11-29 | 2016-08-17 | 埃克森美孚化学专利公司 | 通过开环交叉复分解的乙烯基封端聚合物的官能化 |
| US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
| EP2778154A1 (de) | 2013-03-13 | 2014-09-17 | Evonik Industries AG | In situ Generierung von Ruthenium-Katalysatoren zur Olefin-Metathese |
| EP2933274A1 (de) | 2014-04-16 | 2015-10-21 | Evonik Degussa GmbH | Verfahren zur Herstellung von Polymeren mittels ringöffnender Polymerisation |
| CN111655740B (zh) | 2017-12-08 | 2022-10-18 | 阿朗新科德国有限责任公司 | 用钌络合物催化剂制备丁腈橡胶的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996004289A1 (en) * | 1992-04-03 | 1996-02-15 | California Institute Of Technology | High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof |
| US5312940A (en) * | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| DE4447066A1 (de) * | 1994-12-29 | 1996-07-04 | Hoechst Ag | Heterocyclische Carbene enthaltende Metallkomplexverbindungen |
| US5831108A (en) * | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| US5936100A (en) * | 1996-12-16 | 1999-08-10 | Studiengesellschaft Kohle Mbh | Synthesis of functionalized macrocycles by ring closing metathesis |
-
1997
- 1997-12-03 EP EP97121228A patent/EP0921129A1/de not_active Withdrawn
-
1998
- 1998-11-17 US US09/555,652 patent/US6590048B1/en not_active Expired - Fee Related
- 1998-11-17 AT AT98965675T patent/ATE219091T1/de not_active IP Right Cessation
- 1998-11-17 EP EP98965675A patent/EP1037897B1/de not_active Expired - Lifetime
- 1998-11-17 CA CA002312755A patent/CA2312755A1/en not_active Abandoned
- 1998-11-17 JP JP2000523222A patent/JP2001525330A/ja active Pending
- 1998-11-17 WO PCT/EP1998/007364 patent/WO1999028330A1/en active IP Right Grant
- 1998-11-17 DE DE69806053T patent/DE69806053T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6590048B1 (en) | 2003-07-08 |
| CA2312755A1 (en) | 1999-06-10 |
| DE69806053T2 (de) | 2003-01-23 |
| JP2001525330A (ja) | 2001-12-11 |
| EP1037897A1 (de) | 2000-09-27 |
| EP1037897B1 (de) | 2002-06-12 |
| EP0921129A1 (de) | 1999-06-09 |
| DE69806053D1 (de) | 2002-07-18 |
| WO1999028330A1 (en) | 1999-06-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |