AR111756A1 - 4-difluorometilbenzoilamidas de acción herbicida - Google Patents

4-difluorometilbenzoilamidas de acción herbicida

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AR111756A1
AR111756A1 ARP180101176A ARP180101176A AR111756A1 AR 111756 A1 AR111756 A1 AR 111756A1 AR P180101176 A ARP180101176 A AR P180101176A AR P180101176 A ARP180101176 A AR P180101176A AR 111756 A1 AR111756 A1 AR 111756A1
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alkyl
halogen
cycloalkyl
heterocyclyl
phenyl
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Machettira Anu Bheemaiah Dr
Rosinger Christopher Hugh Dr
Gatzweiler Elmar Dr
Dietrich Hansjrg Dr
Waldraff Christian Dr
Tiebes Jrg Dr
Ahrens Hartmut Dr
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Bayer Cropscience Ag
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • C07C317/14Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/24Thiols, sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
    • C07C321/28Sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D255/00Heterocyclic compounds containing rings having three nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D249/00 - C07D253/00
    • C07D255/02Heterocyclic compounds containing rings having three nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D249/00 - C07D253/00 not condensed with other rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D257/00Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D257/04Five-membered rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D257/00Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D257/04Five-membered rings
    • C07D257/06Five-membered rings with nitrogen atoms directly attached to the ring carbon atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D271/00Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
    • C07D271/02Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D271/041,2,3-Oxadiazoles; Hydrogenated 1,2,3-oxadiazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D271/00Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
    • C07D271/02Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D271/061,2,4-Oxadiazoles; Hydrogenated 1,2,4-oxadiazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
  • Burglar Alarm Systems (AREA)

Abstract

Se describen benzoilamidas como herbicidas. Reivindicación 1: Benzoilamidas de la fórmula (1) y sus sales Salze, en donde los símbolos e índices tienen los siguientes significados: Q significa un radical (Q1), (Q2), (Q3) ó (Q4) seleccionado del grupo de fórmulas (2); X significa alquilo C₁₋₆, cicloalquilo C₃₋₆ o halógeno; R significa alquilo C₁₋₆, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, alquil C₁₋₆-O-alquilo C₁₋₆; Rᵃ significa hidrógeno, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, cicloalquilo C₃₋₆, halógeno-cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, halógeno-cicloalquil C₃₋₆-alquilo C₁₋₆, R¹(O)C-alquilo C₁₋₆, R¹O(O)C-alquilo C₁₋₆, (R¹)₂N(O)C-alquilo C₁₋₆, NC-alquilo C₁₋₆, R¹O-alquilo C₁₋₆, R¹(O)CO-alquilo C₁₋₆, R²(O)₂SO-alquilo C₁₋₆, (R¹)₂N-alquilo C₁₋₆, R¹(O)C(R¹)N-alquilo C₁₋₆, R²(O)₂S(R¹)N-alquilo C₁₋₆, R²(O)ₙS-alquilo C₁₋₆, R¹O(O)₂S-alquilo C₁₋₆, (R¹)₂N(O)₂S-alquilo C₁₋₆, R¹(O)C, R¹O(O)C, (R¹)₂N(O)C, R¹O, (R¹)₂N, R²O(O)C(R¹)N, (R¹)₂N(O)C(R¹)N, R²(O)₂S, o en cada caso bencilo sustituido con s radicales del grupo compuesto por metilo, etilo, metoxi, nitro, trifluorometilo y halógeno; RX significa alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, en donde los últimos seis radicales previamente mencionados están sustituidos en cada caso con s radicales del grupo compuesto por nitro, ciano, (R⁶)₃Si, (R⁵O)₂(O)P, R²(O)ₙS, (R¹)₂N, R¹O, R¹(O)C, R¹O(O)C, R¹(O)CO, R²O(O)CO, R¹(O)C(R¹)N, R²(O)₂S(R¹)N, cicloalquilo C₃₋₆, heteroarilo, heterociclilo y fenilo, en donde los últimos cuatro radicales mencionados están sustituidos con s radicales del grupo compuesto por alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆ y halógeno y en donde el heterociclilo lleva n grupos oxo, o RX es cicloalquilo C₃₋₇, heteroarilo, heterociclilo o fenilo, en donde los cuatro radicales previamente mencionados están sustituidos en cada caso con s radicales del grupo compuesto por halógeno, nitro, ciano, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, cicloalquilo C₃₋₆, alquil C₁₋₆-S(O)ₙ, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆ y alcoxi C₁₋₆-alquilo C₁₋₄; RY significa hidrógeno, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, cicloalquilo C₃₋₇, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquinil C₂₋₆-oxi, ciano, nitro, metilsulfenilo, metilsulfinilo, metilsulfonilo, acetilamino, benzoilamino, metoxicarbonilo, etoxicarbonilo, metoxicarbonilmetilo, etoxicarbonilmetilo, benzoilo, metilcarbonilo, piperidinilcarbonilo, trifluorometilocarbonilo, halógeno, amino, aminocarbonilo, metilaminocarbonilo, dimetilaminocarbonilo, metoximetilo o heteroarilo, heterociclilo o fenilo sustituidos en cada caso con s radicales del grupo compuesto por alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆ y halógeno y en donde el heterociclilo lleva n grupos oxo; RZ significa hidrógeno, alquilo C₁₋₆, R¹O-alquilo C₁₋₆, R’CH₂, cicloalquilo C₃₋₇, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, R¹O, R¹(H)N, metoxicarbonilo, etoxicarbonilo, metilcarbonilo, dimetilamino, trifluorometilocarbonilo, acetilamino, metilsulfenilo, metilsulfinilo, metilsulfonilo o heteroarilo, heterociclilo, bencilo o fenilo sustituidos en cada caso con s radicales del grupo compuesto por halógeno, nitro, ciano, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, cicloalquilo C₃₋₆, alquil C₁₋₆-S(O)ₙ, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆ y alcoxi C₁₋₆-alquilo C₁₋₄, en donde el heterociclilo lleva n grupos oxo; R¹ significa hidrógeno, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, cicloalquilo C₃₋₆, cicloalquenilo C₃₋₆, halógeno-cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, alquil C₁₋₆-O-alquilo C₁₋₆, cicloalquil-alquil C₁₋₆-O-alquilo C₁₋₆, fenilo, fenil-alquilo C₁₋₆, heteroarilo, heteroaril-alquilo C₁₋₆, heterociclilo, heterociclil-alquilo C₁₋₆, fenil-O-alquilo C₁₋₆, heteroaril-O-alquilo C₁₋₆, heterociclil-O-alquilo C₁₋₆, fenil-N(R³)-alquilo C₁₋₆, heteroaril-N(R³)-alquilo C₁₋₆, heterociclil-N(R³)-alquilo C₁₋₆, fenil-S(O)ₙ-alquilo C₁₋₆, heteroaril-S(O)ₙ-alquilo C₁₋₆, heterociclil-S(O)ₙ-alquilo C₁₋₆, en donde los últimos quince radicales mencionados están sustituidos en cada caso con s radicales del grupo compuesto por nitro, halógeno, ciano, rodano, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, cicloalquilo C₃₋₆, R³O(O)C, (R³)₂N(O)C, R³O, (R³)₂N, R⁴(O)ₙS, R³O(O)₂S, (R³)₂N(O)₂S y R³O-alquilo C₁₋₆ y en donde el heterociclilo lleva n grupos oxo; R² significa alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, halógeno-alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquinilo C₃₋₆, cicloalquilo C₃₋₆, cicloalquenilo C₃₋₆, halógeno-cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, alquil C₁₋₆-O-alquilo C₁₋₆, cicloalquil-alquil C₁₋₆-O-alquilo C₁₋₆, fenilo, fenil-alquilo C₁₋₆, heteroarilo, heteroaril-alquilo C₁₋₆, heterociclilo, heterociclil-alquilo C₁₋₆, fenil-O-alquilo C₁₋₆, heteroaril-O-alquilo C₁₋₆, heterociclil-O-alquilo C₁₋₆, fenil-N(R³)-alquilo C₁₋₆, heteroaril-N(R³)-alquilo C₁₋₆, heterociclil-N(R³)-alquilo C₁₋₆, fenil-S(O)ₙ-alquilo C₁₋₆, heteroaril-S(O)ₙ-alquilo C₁₋₆, heterociclil-S(O)ₙ-alquilo C₁₋₆, en donde los últimos quince radicales mencionados están sustituidos en cada caso con s radicales del grupo compuesto por nitro, halógeno, ciano, rodano, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, cicloalquilo C₃₋₆, R³O(O)C, (R³)₂N(O)C, R³O, (R³)₂N, R⁴(O)ₙS, R³O(O)₂S, (R³)₂N(O)₂S y R³O-alquilo C₁₋₆ y en donde el heterociclilo lleva n grupos oxo; R³ significa hidrógeno, alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆ o fenilo; R⁴ significa alquilo C₁₋₆, halógeno-alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆ o fenilo; R⁵ significa hidrógeno o alquilo C₁₋₄; R⁶ significa alquilo C₁₋₄; R’ significa acetoxi, acetamido, N-metilacetamido, benzoiloxi, benzamido, N-metilbenzamido, metoxicarbonilo, etoxicarbonilo, benzoilo, metilcarbonilo, piperidinilcarbonilo, morfolinilcarbonilo, trifluorometilocarbonilo, aminocarbonilo, metilaminocarbonilo, dimetilaminocarbonilo, cicloalquilo C₃₋₆ o heteroarilo o heterociclilo sustituidos en cada caso con s radicales del grupo compuesto por metilo, etilo, metoxi, trifluorometilo y halógeno; n significa 0, 1 ó 2; s significa 0, 1, 2 ó 3; con la condición de que se excluyan los compuestos 4-difluorometil-3-etilsulfinil-2-metil-N-(5-metil-1,3,4-oxadiazol-2-il)benzamida y 4-difluorometil-3-etilsulfonil-2-metil-N-(5-metil-1,3,4-oxadiazol-2-il)benzamida; así como sus sales de sodio.
ARP180101176A 2017-05-04 2018-05-04 4-difluorometilbenzoilamidas de acción herbicida AR111756A1 (es)

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EA202191910A1 (ru) 2019-01-14 2021-11-16 Байер Акциенгезельшафт Гербицидные замещенные n-тетразолил-арилкарбоксамиды
WO2021068816A1 (zh) * 2019-10-08 2021-04-15 沈阳中化农药化工研发有限公司 一种含烯的酰胺类化合物及其应用
CN112624989B (zh) * 2019-10-08 2024-01-26 沈阳中化农药化工研发有限公司 一种酰胺类化合物及其应用
CN113387900A (zh) * 2020-03-13 2021-09-14 沈阳中化农药化工研发有限公司 一种环烯酰胺类化合物及其应用
CN112624991A (zh) * 2019-10-08 2021-04-09 沈阳中化农药化工研发有限公司 一种肉桂酰胺类化合物及其应用
CN116803993A (zh) * 2019-10-23 2023-09-26 青岛清原化合物有限公司 一种含手性硫氧化物的芳基甲酰胺类化合物或其盐、制备方法、除草组合物和应用
AR125060A1 (es) 2021-03-12 2023-06-07 Bayer Ag N-(1,3,4-oxadiazol-2-il)fenilcarboxamidas quirales y su uso como herbicidas
CN117616016A (zh) * 2021-07-08 2024-02-27 拜耳公司 手性3-亚磺酰基苯甲酸
WO2024068473A1 (de) 2022-09-27 2024-04-04 Bayer Aktiengesellschaft Herbizid/safener-kombinationen basierend auf safenern aus der klasse der substituierten [(1,5-diphenyl1h-1,2,4-triazol-3-yl)oxy]essigsäuren sowie deren salze

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