AR111607A1 - Polimerización en solución en reactor múltiple - Google Patents
Polimerización en solución en reactor múltipleInfo
- Publication number
- AR111607A1 AR111607A1 ARP180100980A ARP180100980A AR111607A1 AR 111607 A1 AR111607 A1 AR 111607A1 AR P180100980 A ARP180100980 A AR P180100980A AR P180100980 A ARP180100980 A AR P180100980A AR 111607 A1 AR111607 A1 AR 111607A1
- Authority
- AR
- Argentina
- Prior art keywords
- reactor
- polymerization
- reactors
- solution
- multiple reactor
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1862—Stationary reactors having moving elements inside placed in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/008—Feed or outlet control devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/02—Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/08—Presence of a deactivator
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/05—Bimodal or multimodal molecular weight distribution
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Se divulga un proceso de polimerización en solución continuo en tres reactores; donde el solvente del proceso, etileno, comonómeros opcionales, hidrógeno opcional y un sistema catalizador de sitio único se inyectan en un primer y un segundo reactores configurados en paralelo entre sí; un tercer reactor recibe el efluente del primer reactor, del segundo reactor o una combinación del primer y segundo reactores; el monómero fresco se alimenta al tercer reactor para una polimerización y para obtener un producto de polietileno final.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/491,135 US9963529B1 (en) | 2017-04-19 | 2017-04-19 | Multi reactor solution polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
AR111607A1 true AR111607A1 (es) | 2019-07-31 |
Family
ID=62044773
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP180100980A AR111607A1 (es) | 2017-04-19 | 2018-04-17 | Polimerización en solución en reactor múltiple |
Country Status (12)
Country | Link |
---|---|
US (1) | US9963529B1 (es) |
EP (1) | EP3612571B1 (es) |
JP (1) | JP7090643B2 (es) |
KR (1) | KR102489928B1 (es) |
CN (1) | CN110573538B (es) |
AR (1) | AR111607A1 (es) |
AU (1) | AU2018255899A1 (es) |
CL (1) | CL2019002954A1 (es) |
ES (1) | ES2878289T3 (es) |
MX (1) | MX2019011843A (es) |
PE (1) | PE20191848A1 (es) |
WO (1) | WO2018193327A1 (es) |
Families Citing this family (26)
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US10538654B2 (en) * | 2017-04-19 | 2020-01-21 | Nova Chemicals (International) S.A. | Multi reactor solution polymerization, polyethylene and polyethylene film |
CA2978205A1 (en) * | 2017-09-01 | 2019-03-01 | Nova Chemicals Corporation | Continuous tuning of ci:mg ratio in a solution polymerization |
KR102133030B1 (ko) * | 2017-12-18 | 2020-07-10 | 주식회사 엘지화학 | 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름 |
CA2989212C (en) * | 2017-12-18 | 2024-05-14 | Nova Chemicals Corporation | Multistage process for the solution polymerization of ethylene |
WO2019133373A1 (en) | 2017-12-26 | 2019-07-04 | Dow Global Technologies Llc | Multimodal ethylene-based polymer compositions having improved toughness |
JP7326283B2 (ja) * | 2017-12-26 | 2023-08-15 | ダウ グローバル テクノロジーズ エルエルシー | マルチモーダルエチレン系ポリマーの製造のための二重反応器溶液プロセス |
US11384229B2 (en) | 2017-12-26 | 2022-07-12 | Dow Global Technologies Llc | Compositions comprising multimodal ethylene-based polymers and low density polyethylene (LDPE) |
KR102663559B1 (ko) | 2017-12-26 | 2024-05-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중모드 에틸렌계 중합체 처리 시스템 및 방법 |
BR112020012805A2 (pt) * | 2017-12-26 | 2020-11-24 | Dow Global Technologies Llc | método para produzir um polímero multimodal à base de etileno. |
CN112313254B (zh) * | 2018-06-19 | 2023-04-18 | 埃克森美孚化学专利公司 | 聚乙烯组合物和由其制备的膜 |
EP3810420A1 (en) * | 2018-06-21 | 2021-04-28 | SABIC Global Technologies B.V. | Polyethylene cast films |
CA3011030A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having retained dart impact |
CA3011031A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having outstanding properties |
CA3011038A1 (en) | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having a good permeability, stiffness and sealability |
CA3011041A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film |
CA3011050A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having high stiffness, outstanding sealability and high permeability |
US10781273B2 (en) * | 2018-12-27 | 2020-09-22 | Chevron Phillips Chemical Company Lp | Multiple reactor and multiple zone polyolefin polymerization |
WO2020178010A1 (en) * | 2019-03-04 | 2020-09-10 | Borealis Ag | Polymerization process |
KR102523121B1 (ko) * | 2020-01-31 | 2023-04-19 | 주식회사 엘지화학 | 공액디엔계 중합체의 연속 제조 시스템 |
US11643531B2 (en) * | 2020-10-01 | 2023-05-09 | Nova Chemicals (International) S.A. | Thermoformable film |
KR102395347B1 (ko) * | 2020-10-20 | 2022-05-09 | 한화토탈에너지스 주식회사 | 폴리에틸렌 수지 조성물 및 이의 제조방법 |
CN112279941B (zh) * | 2020-10-21 | 2024-04-30 | 浙江传化合成材料股份有限公司 | 三元稀土催化剂的连续陈化装置及其连续陈化工艺 |
CN116396549A (zh) | 2022-01-04 | 2023-07-07 | 韩华道达尔能源有限公司 | 聚乙烯树脂组合物、其制造方法及包含其的模制品 |
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EP2883887A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
WO2016063200A1 (en) * | 2014-10-21 | 2016-04-28 | Nova Chemicals (International) S.A. | Continuous solution polymerization process |
CA2868640C (en) * | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
-
2017
- 2017-04-19 US US15/491,135 patent/US9963529B1/en active Active
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2018
- 2018-03-28 MX MX2019011843A patent/MX2019011843A/es unknown
- 2018-03-28 PE PE2019002059A patent/PE20191848A1/es unknown
- 2018-03-28 AU AU2018255899A patent/AU2018255899A1/en not_active Abandoned
- 2018-03-28 WO PCT/IB2018/052141 patent/WO2018193327A1/en unknown
- 2018-03-28 JP JP2019556967A patent/JP7090643B2/ja active Active
- 2018-03-28 KR KR1020197030645A patent/KR102489928B1/ko active IP Right Grant
- 2018-03-28 CN CN201880025958.2A patent/CN110573538B/zh active Active
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ES2878289T3 (es) | 2021-11-18 |
US9963529B1 (en) | 2018-05-08 |
CN110573538B (zh) | 2022-09-20 |
BR112019021841A2 (pt) | 2020-05-26 |
PE20191848A1 (es) | 2019-12-31 |
KR102489928B1 (ko) | 2023-01-19 |
AU2018255899A1 (en) | 2019-10-31 |
EP3612571A1 (en) | 2020-02-26 |
JP2020517780A (ja) | 2020-06-18 |
MX2019011843A (es) | 2020-02-07 |
JP7090643B2 (ja) | 2022-06-24 |
WO2018193327A1 (en) | 2018-10-25 |
EP3612571B1 (en) | 2021-05-19 |
CL2019002954A1 (es) | 2020-05-08 |
KR20190140444A (ko) | 2019-12-19 |
CN110573538A (zh) | 2019-12-13 |
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