AR111605A1 - Polimerización en solución en múltiples reactores, polietileno y películas de polietileno - Google Patents
Polimerización en solución en múltiples reactores, polietileno y películas de polietilenoInfo
- Publication number
- AR111605A1 AR111605A1 ARP180100978A ARP180100978A AR111605A1 AR 111605 A1 AR111605 A1 AR 111605A1 AR P180100978 A ARP180100978 A AR P180100978A AR P180100978 A ARP180100978 A AR P180100978A AR 111605 A1 AR111605 A1 AR 111605A1
- Authority
- AR
- Argentina
- Prior art keywords
- polyethylene
- reactor
- polymerization
- reactors
- solution
- Prior art date
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
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- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/07—High density, i.e. > 0.95 g/cm3
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/08—Low density, i.e. < 0.91 g/cm3
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/10—Short chain branches
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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- C08L2203/16—Applications used for films
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C08L2207/00—Properties characterising the ingredient of the composition
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- C08L2207/064—VLDPE
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- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
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- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Crystallography & Structural Chemistry (AREA)
Abstract
Esta divulgación se relaciona con un proceso de polimerización en solución continuo en tres reactores. El solvente del proceso, etileno, comonómeros opcionales, hidrógeno opcional y un sistema catalizador de sitio único se inyectan en un primer y un segundo reactores configurados en paralelo entre sí. Un tercer reactor recibe el efluente del primer reactor, del segundo reactor o una combinación del primer y segundo reactores. Se alimenta el monómeros frescos al tercer reactor para una polimerización y para obtener un producto de polietileno final.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/491,213 US10538654B2 (en) | 2017-04-19 | 2017-04-19 | Multi reactor solution polymerization, polyethylene and polyethylene film |
Publications (1)
Publication Number | Publication Date |
---|---|
AR111605A1 true AR111605A1 (es) | 2019-07-31 |
Family
ID=62116913
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP180100978A AR111605A1 (es) | 2017-04-19 | 2018-04-17 | Polimerización en solución en múltiples reactores, polietileno y películas de polietileno |
Country Status (11)
Country | Link |
---|---|
US (1) | US10538654B2 (es) |
EP (1) | EP3612588B1 (es) |
JP (1) | JP7088957B2 (es) |
KR (1) | KR102512023B1 (es) |
CN (1) | CN110832014B (es) |
AR (1) | AR111605A1 (es) |
AU (1) | AU2018255900A1 (es) |
CL (1) | CL2019002963A1 (es) |
ES (1) | ES2909037T3 (es) |
PE (1) | PE20200228A1 (es) |
WO (1) | WO2018193328A1 (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11384229B2 (en) * | 2017-12-26 | 2022-07-12 | Dow Global Technologies Llc | Compositions comprising multimodal ethylene-based polymers and low density polyethylene (LDPE) |
EP3732213B1 (en) * | 2017-12-26 | 2022-01-12 | Dow Global Technologies LLC | Multimodal ethylene-based polymer compositions having improved toughness |
SG11202005777XA (en) | 2017-12-26 | 2020-07-29 | Dow Global Technologies Llc | Multimodal ethylene-based polymer processing systems and methods |
SG11202005778VA (en) * | 2017-12-26 | 2020-07-29 | Dow Global Technologies Llc | Process for the production of multimodal ethylene-based polymers |
US20200332036A1 (en) * | 2017-12-26 | 2020-10-22 | Dow Global Technologies Llc | Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures |
JP7326283B2 (ja) * | 2017-12-26 | 2023-08-15 | ダウ グローバル テクノロジーズ エルエルシー | マルチモーダルエチレン系ポリマーの製造のための二重反応器溶液プロセス |
WO2019182352A1 (ko) * | 2018-03-21 | 2019-09-26 | 주식회사 엘지화학 | 폴리올레핀계 수지 조성물 및 이를 이용한 스트레치 필름 |
US20210246235A1 (en) * | 2018-05-31 | 2021-08-12 | Dow Global Technologies Llc | Devolatilizer design |
KR102571139B1 (ko) * | 2018-06-08 | 2023-08-28 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 에틸렌 중합체 혼합물과 이의 제조방법 및 이를 이용한 성형품 |
CN113195603B (zh) * | 2018-11-13 | 2023-05-26 | 埃克森美孚化学专利公司 | 聚乙烯膜 |
KR102116476B1 (ko) * | 2019-01-18 | 2020-05-28 | 대림산업 주식회사 | 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지 |
CN110165122B (zh) * | 2019-05-15 | 2022-03-04 | 乐凯胶片股份有限公司 | 聚乙烯微孔膜及其制备方法和应用 |
CN112048115B (zh) * | 2019-06-06 | 2023-09-26 | 神华(北京)新材料科技有限公司 | 金属与聚烯烃的复合材料及其制备方法和容器 |
US11046843B2 (en) * | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
KR102525719B1 (ko) * | 2019-11-28 | 2023-04-26 | 한화솔루션 주식회사 | 올레핀계 중합체 필름 및 그 제조방법 |
JP2023508929A (ja) * | 2019-12-31 | 2023-03-06 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレン組成物 |
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JP2020517767A (ja) | 2020-06-18 |
CL2019002963A1 (es) | 2020-05-08 |
US10538654B2 (en) | 2020-01-21 |
CN110832014A (zh) | 2020-02-21 |
EP3612588A1 (en) | 2020-02-26 |
CN110832014B (zh) | 2022-07-29 |
PE20200228A1 (es) | 2020-01-31 |
KR20190136019A (ko) | 2019-12-09 |
JP7088957B2 (ja) | 2022-06-21 |
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