AR101230A1 - Amidas del ácido arilcarboxílico bicíclicas y su uso como herbicidas - Google Patents
Amidas del ácido arilcarboxílico bicíclicas y su uso como herbicidasInfo
- Publication number
- AR101230A1 AR101230A1 ARP150102275A ARP150102275A AR101230A1 AR 101230 A1 AR101230 A1 AR 101230A1 AR P150102275 A ARP150102275 A AR P150102275A AR P150102275 A ARP150102275 A AR P150102275A AR 101230 A1 AR101230 A1 AR 101230A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- cycloalkyl
- heterocyclyl
- alkoxy
- halogen
- Prior art date
Links
- 239000002253 acid Substances 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- -1 cyano, formyl Chemical group 0.000 abstract 37
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 31
- 125000000217 alkyl group Chemical group 0.000 abstract 24
- 229910052736 halogen Inorganic materials 0.000 abstract 17
- 150000002367 halogens Chemical class 0.000 abstract 17
- 229910052739 hydrogen Inorganic materials 0.000 abstract 11
- 239000001257 hydrogen Substances 0.000 abstract 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 11
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 10
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 10
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 10
- 125000000623 heterocyclic group Chemical group 0.000 abstract 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 10
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 9
- 229910052760 oxygen Inorganic materials 0.000 abstract 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 7
- 239000001301 oxygen Substances 0.000 abstract 7
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 6
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 6
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 6
- 125000001072 heteroaryl group Chemical group 0.000 abstract 6
- 125000004674 methylcarbonyl group Chemical group CC(=O)* 0.000 abstract 6
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 5
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 5
- 125000006557 (C2-C5) alkylene group Chemical group 0.000 abstract 5
- 229910052799 carbon Inorganic materials 0.000 abstract 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 4
- 125000004429 atom Chemical group 0.000 abstract 4
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 4
- 125000004043 oxo group Chemical group O=* 0.000 abstract 4
- HCUOEKSZWPGJIM-YBRHCDHNSA-N (e,2e)-2-hydroxyimino-6-methoxy-4-methyl-5-nitrohex-3-enamide Chemical compound COCC([N+]([O-])=O)\C(C)=C\C(=N/O)\C(N)=O HCUOEKSZWPGJIM-YBRHCDHNSA-N 0.000 abstract 3
- 101001109689 Homo sapiens Nuclear receptor subfamily 4 group A member 3 Proteins 0.000 abstract 3
- 101000598778 Homo sapiens Protein OSCP1 Proteins 0.000 abstract 3
- 101001067395 Mus musculus Phospholipid scramblase 1 Proteins 0.000 abstract 3
- 102100022673 Nuclear receptor subfamily 4 group A member 3 Human genes 0.000 abstract 3
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 abstract 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 3
- 125000005347 halocycloalkyl group Chemical group 0.000 abstract 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 abstract 2
- 101100496169 Arabidopsis thaliana CLH1 gene Proteins 0.000 abstract 2
- 101100044057 Mesocricetus auratus SYCP3 gene Proteins 0.000 abstract 2
- 102000003728 Peroxisome Proliferator-Activated Receptors Human genes 0.000 abstract 2
- 108090000029 Peroxisome Proliferator-Activated Receptors Proteins 0.000 abstract 2
- 101100080600 Schizosaccharomyces pombe (strain 972 / ATCC 24843) nse6 gene Proteins 0.000 abstract 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 2
- 101150111293 cor-1 gene Proteins 0.000 abstract 2
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 2
- 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 abstract 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 abstract 2
- LBQAJLBSGOBDQF-UHFFFAOYSA-N nitro azanylidynemethanesulfonate Chemical compound [O-][N+](=O)OS(=O)(=O)C#N LBQAJLBSGOBDQF-UHFFFAOYSA-N 0.000 abstract 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 abstract 1
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract 1
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 abstract 1
- 102000034570 NR1 subfamily Human genes 0.000 abstract 1
- 108020001305 NR1 subfamily Proteins 0.000 abstract 1
- MYWYJXDWQFNXIC-UHFFFAOYSA-N [1-acetamido-2-(methylamino)-2-oxoethyl] acetate Chemical compound C(C)(=O)OC(C(=O)NC)NC(C)=O MYWYJXDWQFNXIC-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000005085 alkoxycarbonylalkoxy group Chemical group 0.000 abstract 1
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000002619 bicyclic group Chemical group 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 150000001721 carbon Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- AUTLGSDDLLQALF-UHFFFAOYSA-N cyano azanylidynemethanesulfonate Chemical compound N#CS(=O)(=O)OC#N AUTLGSDDLLQALF-UHFFFAOYSA-N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000004461 halocycloalkylalkyl group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004415 heterocyclylalkyl group Chemical group 0.000 abstract 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 abstract 1
- 125000004458 methylaminocarbonyl group Chemical group [H]N(C(*)=O)C([H])([H])[H] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical compound OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
- C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D257/04—Five-membered rings
- C07D257/06—Five-membered rings with nitrogen atoms directly attached to the ring carbon atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D249/14—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
- C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D271/08—1,2,5-Oxadiazoles; Hydrogenated 1,2,5-oxadiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
- C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D271/10—1,3,4-Oxadiazoles; Hydrogenated 1,3,4-oxadiazoles
- C07D271/113—1,3,4-Oxadiazoles; Hydrogenated 1,3,4-oxadiazoles with oxygen, sulfur or nitrogen atoms, directly attached to ring carbon atoms, the nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14178795 | 2014-07-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR101230A1 true AR101230A1 (es) | 2016-11-30 |
Family
ID=51292804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP150102275A AR101230A1 (es) | 2014-07-28 | 2015-07-17 | Amidas del ácido arilcarboxílico bicíclicas y su uso como herbicidas |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9914710B2 (enExample) |
| EP (1) | EP3174871B1 (enExample) |
| JP (1) | JP6643315B2 (enExample) |
| CN (1) | CN106715403B (enExample) |
| AR (1) | AR101230A1 (enExample) |
| AU (1) | AU2015295590A1 (enExample) |
| BR (1) | BR112017001433B1 (enExample) |
| CA (1) | CA2956302A1 (enExample) |
| EA (1) | EA201790281A1 (enExample) |
| MX (1) | MX2017001320A (enExample) |
| WO (1) | WO2016016107A1 (enExample) |
| ZA (1) | ZA201700704B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3558976A1 (de) | 2016-12-22 | 2019-10-30 | Bayer CropScience Aktiengesellschaft | Substituierte azolylpyrrolone und azolylhydantoine sowie deren salze und ihre verwendung als herbizide wirkstoffe |
| JP2020518625A (ja) * | 2017-05-04 | 2020-06-25 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | キナゾリンジオン−６−カルボニル誘導体を含有する除草剤毒性緩和剤組成物 |
| WO2019166305A1 (de) * | 2018-02-28 | 2019-09-06 | Bayer Aktiengesellschaft | Herbizid wirksame bizyklische benzamide |
| EP3858818A4 (en) * | 2018-09-29 | 2022-06-15 | Shandong Cynda Chemical Co., LTD. | Triketone compound, preparation method therefor and use thereof, and herbicide |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4924073B2 (enExample) * | 1971-06-12 | 1974-06-20 | Adeka Argus Chemical Co Ltd | |
| CN1153515A (zh) * | 1994-06-10 | 1997-07-02 | 拜尔公司 | N-杂环基-杂芳氧基乙酰胺 |
| EP1101758A4 (en) * | 1998-07-28 | 2002-04-03 | Nihon Nohyaku Co Ltd | CONDENSED HETEROCYCLIC DICARBONIC ACID DIAMOND DERIVATIVES OR SALTS THEREOF, HERBICIDES AND THEIR USE |
| EA023205B9 (ru) * | 2010-09-01 | 2016-09-30 | Байер Интеллектуэль Проперти Гмбх | Амиды n-(тетразол-5-ил)- и n-(триазол-5-ил)арилкарбоновых кислот и гербицидное средство |
| KR101856998B1 (ko) * | 2011-03-15 | 2018-05-14 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | N-(1,2,5-옥사디아졸-3-일)-, n-(테트라졸-5-일)- 및 n-(트리아졸-5-일)바이사이클로아릴카복사미드 및 제초제로서의 그의 용도 |
| LT2688885T (lt) * | 2011-03-22 | 2016-09-12 | Bayer Intellectual Property Gmbh | N-(1,3,4-oksadiazol-2-il)arilkarboksamidai ir jų panaudojimas kaip herbicidų |
| EP2589598A1 (de) | 2011-11-03 | 2013-05-08 | Bayer CropScience AG | 5-Phenylsubstituierte N-(Tetrazol-5-yl)- und N-(Triazol-5-yl)arylcarbonsäureamide und ihre Verwendung als Herbizide |
| AR088886A1 (es) * | 2011-11-16 | 2014-07-16 | Basf Se | Compuestos de 1,2,5-oxadiazol sustituido y su uso como herbicidas ii |
| EP2780340A1 (en) * | 2011-11-18 | 2014-09-24 | Basf Se | Substituted 1,2,5-oxadiazole compounds and their use as herbicides iii |
| EP2793589B1 (en) * | 2011-12-21 | 2017-12-20 | Syngenta Limited | Herbicidal compounds |
| CN104395304A (zh) * | 2012-04-27 | 2015-03-04 | 巴斯夫欧洲公司 | 取代的n-(四唑-5-基)-和n-(三唑-5-基)芳基羧酰胺化合物及其作为除草剂的用途 |
| CN104768937B (zh) * | 2012-09-05 | 2016-11-23 | 拜尔农作物科学股份公司 | 除草活性的二环芳基羧酸酰胺 |
| WO2014086737A1 (de) * | 2012-12-06 | 2014-06-12 | Bayer Cropscience Ag | Kondensierte 2-pyridon-3-carboxamide und ihre verwendung als herbizide |
| US9732048B2 (en) * | 2012-12-07 | 2017-08-15 | Bayer Cropscience Ag | N-(isoxazol-3-yl)-aryl-carboxylic acid amides and use thereof as herbicides |
-
2015
- 2015-07-17 AR ARP150102275A patent/AR101230A1/es unknown
- 2015-07-24 US US15/328,253 patent/US9914710B2/en active Active
- 2015-07-24 MX MX2017001320A patent/MX2017001320A/es unknown
- 2015-07-24 CN CN201580051066.6A patent/CN106715403B/zh active Active
- 2015-07-24 AU AU2015295590A patent/AU2015295590A1/en not_active Abandoned
- 2015-07-24 CA CA2956302A patent/CA2956302A1/en not_active Abandoned
- 2015-07-24 WO PCT/EP2015/066955 patent/WO2016016107A1/de not_active Ceased
- 2015-07-24 BR BR112017001433-5A patent/BR112017001433B1/pt active IP Right Grant
- 2015-07-24 EA EA201790281A patent/EA201790281A1/ru unknown
- 2015-07-24 JP JP2017504417A patent/JP6643315B2/ja active Active
- 2015-07-24 EP EP15738948.7A patent/EP3174871B1/de active Active
-
2017
- 2017-01-27 ZA ZA2017/00704A patent/ZA201700704B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP3174871A1 (de) | 2017-06-07 |
| US20170217909A1 (en) | 2017-08-03 |
| JP6643315B2 (ja) | 2020-02-12 |
| CN106715403A (zh) | 2017-05-24 |
| EP3174871B1 (de) | 2018-11-21 |
| CN106715403B (zh) | 2020-06-02 |
| US9914710B2 (en) | 2018-03-13 |
| AU2015295590A2 (en) | 2017-03-16 |
| MX2017001320A (es) | 2017-05-09 |
| EA201790281A1 (ru) | 2017-11-30 |
| BR112017001433A2 (pt) | 2017-12-05 |
| WO2016016107A1 (de) | 2016-02-04 |
| CA2956302A1 (en) | 2016-02-04 |
| JP2017523186A (ja) | 2017-08-17 |
| AU2015295590A1 (en) | 2017-02-16 |
| ZA201700704B (en) | 2018-05-30 |
| BR112017001433B1 (pt) | 2021-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |