AR098278A1 - Eteraminas preparadas a partir de una mezcla de dos o más iniciadores de alcoholes multifuncionales, y su uso como agentes de curado intermediarios para la síntesis de polímeros - Google Patents
Eteraminas preparadas a partir de una mezcla de dos o más iniciadores de alcoholes multifuncionales, y su uso como agentes de curado intermediarios para la síntesis de polímerosInfo
- Publication number
- AR098278A1 AR098278A1 ARP140104115A ARP140104115A AR098278A1 AR 098278 A1 AR098278 A1 AR 098278A1 AR P140104115 A ARP140104115 A AR P140104115A AR P140104115 A ARP140104115 A AR P140104115A AR 098278 A1 AR098278 A1 AR 098278A1
- Authority
- AR
- Argentina
- Prior art keywords
- mixture
- alkylene
- cycloalkylene
- initiators
- eteramines
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 12
- 239000003999 initiator Substances 0.000 title abstract 7
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 229920005862 polyol Polymers 0.000 abstract 8
- 150000003077 polyols Chemical class 0.000 abstract 8
- 125000002947 alkylene group Chemical group 0.000 abstract 4
- 125000002993 cycloalkylene group Chemical group 0.000 abstract 3
- 238000002844 melting Methods 0.000 abstract 3
- 230000008018 melting Effects 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000002243 precursor Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000006268 reductive amination reaction Methods 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C217/42—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having etherified hydroxy groups and at least two amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3234—Polyamines cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
- C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
- C08G65/325—Polymers modified by chemical after-treatment with inorganic compounds containing nitrogen
- C08G65/3255—Ammonia
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/50—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing nitrogen, e.g. polyetheramines or Jeffamines(r)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Resins (AREA)
- Polyethers (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361900117P | 2013-11-05 | 2013-11-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR098278A1 true AR098278A1 (es) | 2016-05-26 |
Family
ID=53041969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP140104115A AR098278A1 (es) | 2013-11-05 | 2014-11-03 | Eteraminas preparadas a partir de una mezcla de dos o más iniciadores de alcoholes multifuncionales, y su uso como agentes de curado intermediarios para la síntesis de polímeros |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10513578B2 (https=) |
| EP (1) | EP3065546B1 (https=) |
| JP (1) | JP6492070B2 (https=) |
| KR (1) | KR102240983B1 (https=) |
| CN (2) | CN105705015A (https=) |
| AR (1) | AR098278A1 (https=) |
| BR (1) | BR112016009727B1 (https=) |
| WO (1) | WO2015069531A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102627551B1 (ko) * | 2016-01-12 | 2024-01-23 | 헌츠만 페트로케미칼 엘엘씨 | 폴리에테르아민과 알킬렌 아민의 공-제조 |
| CN107754813B (zh) | 2016-08-18 | 2019-09-20 | 万华化学集团股份有限公司 | 一种用于聚醚胺合成的负载型催化剂及其制备方法 |
| US10604453B1 (en) * | 2016-10-31 | 2020-03-31 | James Hardie Technology Limited | Coating systems and formulations for cementitious articles |
| KR102720792B1 (ko) * | 2018-03-19 | 2024-10-23 | 헌츠만 페트로케미칼 엘엘씨 | 폴리에테르 디아민을 함유하는 에테르아민 혼합물 및 이의 제조 및 사용 방법 |
| US11548847B2 (en) | 2019-02-26 | 2023-01-10 | Mitsubishi Gas Chemical Company, Inc. | Amine composition, amine compound, production method, and application thereof |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2683730A (en) | 1951-01-17 | 1954-07-13 | Goodyear Tire & Rubber | Polyisocyanates and mixtures thereof |
| US3012008A (en) | 1957-03-29 | 1961-12-05 | Ici Ltd | Polyisocyanate compositions |
| DE1071329B (de) | 1957-05-10 | 1959-12-17 | Imperial Chemical Industries Limited, London | Ver fahren zur Herstellung von Polyurethan-Schaumstoffen |
| NL134685C (https=) | 1960-06-08 | |||
| USB334162I5 (https=) | 1964-01-02 | |||
| US3362979A (en) | 1964-01-02 | 1968-01-09 | Jefferson Chem Co Inc | Mixtures of methylene-bridged polyphenyl polyisocyanates |
| US3394164A (en) | 1965-10-24 | 1968-07-23 | Upjohn Co | Stabilized methylenebis-(phenyl isocyanate) compositions |
| US3654370A (en) | 1970-08-28 | 1972-04-04 | Jefferson Chem Co Inc | Process for preparing polyoxyalkylene polyamines |
| US4152353A (en) | 1977-08-29 | 1979-05-01 | The Dow Chemical Company | Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof |
| EP0137634B1 (en) | 1983-08-11 | 1989-02-22 | Minnesota Mining And Manufacturing Company | Curable epoxy compositions and cured resins obtained therefrom |
| US4766245A (en) | 1985-03-01 | 1988-08-23 | Texaco Inc. | Process for the preparation of polyoxyalkylene polyamines |
| US4748192A (en) | 1986-03-24 | 1988-05-31 | Urylon Development, Inc. | Aliphatic polyurethane sprayable coating compositions and method of preparation |
| US4705814A (en) | 1986-11-06 | 1987-11-10 | Texaco Inc. | Reaction product of polyoxyalkylene polyamine and an aliphatic isocyanate |
| US4769438A (en) | 1987-06-29 | 1988-09-06 | Texaco Inc. | Aminated propoxylated 1,4-butanediol epoxy resin adducts as epoxy resin curatives |
| DE69126333T2 (de) | 1990-02-09 | 1997-09-18 | Huntsman Spec Chem Corp | Komponenten für das Interieur eines Personenkraftwagens |
| US5639413A (en) | 1995-03-30 | 1997-06-17 | Crivello; James Vincent | Methods and compositions related to stereolithography |
| DE59701299D1 (de) | 1996-07-29 | 2000-04-27 | Ciba Sc Holding Ag | Flüssige, strahlungshärtbare Zusammensetzung, insbesondere für die Stereolithographie |
| US5912189A (en) | 1998-05-12 | 1999-06-15 | The Lubrizol Corporation | Compositions containing reaction product of a cyclic compound containing both a nitrogen atom and a carbonyl group, an aldehyde or ketone, and an etheramine |
| US6060625A (en) | 1999-04-30 | 2000-05-09 | Huntsman Petrochemical Corporation | Process for the production of etheramine alkoxylates |
| US7550550B2 (en) * | 2002-08-30 | 2009-06-23 | Huntsman Petrochemical Corporation | Polyether polyamine agents and mixtures therefor |
| WO2009058367A1 (en) | 2007-11-01 | 2009-05-07 | Cargill, Incorporated | Natural oil-derived polyester polyols and polyurethanes made therefrom |
| GB2466501B (en) * | 2008-12-23 | 2012-11-28 | Isothane Ltd | Method for preparing a composite material |
| CA2761093C (en) * | 2009-05-19 | 2017-10-10 | Basf Se | Polyureas preparable from two polyetheramines and a prepolymer |
| EP2515643B1 (en) * | 2009-12-22 | 2019-05-15 | Huntsman Petrochemical LLC | Etheramines containing flexible and rigid segments and their use as intermediates for polymer synthesis |
| JP5680108B2 (ja) * | 2009-12-22 | 2015-03-04 | ハンツマン ペトロケミカル エルエルシーHuntsman Petrochemical LLC | エーテルアミンおよびそれらを重合体合成時に中間体として用いる使用 |
| CN102668152A (zh) * | 2009-12-23 | 2012-09-12 | 默克专利有限公司 | 包括聚合粘结剂的组合物 |
| US9139690B2 (en) | 2011-04-27 | 2015-09-22 | University Of Massachusetts Lowell | Bisphenol A (BPA) free epoxy resins |
| EP2718370A4 (en) * | 2011-06-08 | 2015-05-27 | Huntsman Adv Mat Americas Inc | HARDENER WITH A LOW RATIO BETWEEN A THIN FILM CURING TIME AND A GELING TIME |
| CA2838192A1 (en) * | 2011-06-08 | 2012-12-13 | Huntsman Advanced Materials Americas Llc | Water-based amine curing agents for curable resin systems |
-
2014
- 2014-10-30 CN CN201480060332.7A patent/CN105705015A/zh active Pending
- 2014-10-30 KR KR1020167014728A patent/KR102240983B1/ko active Active
- 2014-10-30 JP JP2016521711A patent/JP6492070B2/ja active Active
- 2014-10-30 CN CN202111632215.1A patent/CN114163628A/zh active Pending
- 2014-10-30 US US15/033,704 patent/US10513578B2/en active Active
- 2014-10-30 BR BR112016009727-0A patent/BR112016009727B1/pt not_active IP Right Cessation
- 2014-10-30 WO PCT/US2014/063054 patent/WO2015069531A1/en not_active Ceased
- 2014-10-30 EP EP14860619.7A patent/EP3065546B1/en active Active
- 2014-11-03 AR ARP140104115A patent/AR098278A1/es active IP Right Grant
-
2019
- 2019-10-30 US US16/668,006 patent/US11292873B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN114163628A (zh) | 2022-03-11 |
| EP3065546B1 (en) | 2019-02-27 |
| WO2015069531A1 (en) | 2015-05-14 |
| US20200062890A1 (en) | 2020-02-27 |
| US20160257778A1 (en) | 2016-09-08 |
| BR112016009727A2 (pt) | 2017-08-01 |
| US10513578B2 (en) | 2019-12-24 |
| KR102240983B1 (ko) | 2021-04-16 |
| US11292873B2 (en) | 2022-04-05 |
| EP3065546A1 (en) | 2016-09-14 |
| KR20160083052A (ko) | 2016-07-11 |
| JP2016536287A (ja) | 2016-11-24 |
| EP3065546A4 (en) | 2017-06-21 |
| JP6492070B2 (ja) | 2019-03-27 |
| BR112016009727B1 (pt) | 2021-07-06 |
| CN105705015A (zh) | 2016-06-22 |
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