AR080270A1 - Derivados 2-( fenilo susttuido)-ciclopentano-1,3-diona herbicidamente activos y composicion herbicida - Google Patents

Derivados 2-( fenilo susttuido)-ciclopentano-1,3-diona herbicidamente activos y composicion herbicida

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AR080270A1
AR080270A1 ARP100102581A ARP100102581A AR080270A1 AR 080270 A1 AR080270 A1 AR 080270A1 AR P100102581 A ARP100102581 A AR P100102581A AR P100102581 A ARP100102581 A AR P100102581A AR 080270 A1 AR080270 A1 AR 080270A1
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Argentina
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alkyl
haloalkyl
alkoxy
haloalkoxy
halogen
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ARP100102581A
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Syngenta Ltd
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    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C07D285/06—1,2,3-Thiadiazoles; Hydrogenated 1,2,3-thiadiazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07C251/44—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups being part of a ring other than a six-membered aromatic ring
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    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
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    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
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    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
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    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)

Abstract

Reivindicacion 1: Un compuesto de la formula (1) donde R es metilo, etilo, vinilo, etinilo o ciclopropilo; R1 es hidrogeno, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-7, alcoxi C1-6, haloalcoxi C1-6, vinilo, propenilo, etinilo, propinilo, halogeno, fenilo o fenilo sustituido con alquilo, haloalquilo, alquilsulfonilo, halogeno, nitro o ciano; R2 es metilo, etilo, vinilo, etinilo o metoxi; R3 y R4 son hidrogeno, o juntos forman un doble enlace; A es cicloalquilo C3-7, que está no sustituido o está sustituido una vez o dos veces con alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, alquilcarboniloxi C1-6, alquenilo C1-6, =O o =N-R10, donde R10 es hidroxilo, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-7, alcoxi C1-6, alcoxi C1-6-alcoxi C1-6 o haloalcoxi C1-6 o A es ciclohexilo sustituido una vez, en la posicion 4 (calculada con respecto al punto de conexion de ciclohexilo), con un sustituyente (cicloalquilo C3-6)metoxi, cicloalquiloxi C3-6, alquenil C2-5-CH2-oxi, benciloxi, (monometil- o dimetil-fenil)metoxi, (monometoxi- o dimetoxi-fenil)metoxi o (monofluor- o difluor-fenil)metoxi; o A es decahidro-1-naftilo o decahidro-2-naftilo; o A es fenilo opcionalmente sustituido; y G es hidrogeno o un metal agrícolamente aceptable, sulfonio, amonio o grupo protector; donde, cuando G es un grupo protector, el grupo protector G se selecciona de los grupos alquilo C1-8, haloalquilo C2-8, fenil-alquilo C1-8 (donde el fenilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro), heteroaril-alquilo C1-8 (donde el heteroarilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro), alquenilo C3-8, haloalquenilo C3-8, alquinilo C3-8, C(Xa)-Ra, C(Xb)-Xc-Rb, C(Xd)-N(Rc)-Rd, -SO2-Re, -P(Xe)(Rf)-Rg y CH2-Xf-Rh; donde Xa, Xb, Xc, Xd, Xe y Xf son, de modo independiente entre sí, oxígeno o azufre; y donde Ra es H, alquilo C1-18, alquenilo C2-18, alquinilo C2-18, haloalquilo C1-10, cianoalquilo C1-10, nitroalquilo C1-10, aminoalquilo C1-10, alquilamino C1-5-alquilo C1-5, dialquilamino C2-8-alquilo C1-5, cicloalquilo C3-7-alquilo C1-5, alcoxi C1-5-alquilo C1-5, alqueniloxi C3-5-alquilo C1-5, alquiltio C1-5-alquilo C1-5, alquilsulfinilo C1-5-alquilo C1-5, alquilsulfonilo C1-5-alquilo C1-C5, alquilidenoaminoxi C2-8-alquilo C1-5, alquilcarbonilo C1-5-alquilo C1-5, alcoxicarbonilo C1-5-alquilo C1-5, aminocarbonil-alquilo C1-5, alquilaminocarbonil C1-5-alquilo C1-5, dialquilaminocarbonil C2-8-alquilo C1-5, alquilcarbonilamino C1-5-alquilo C1-5, N-alquilcarbonil C1-5-N-alquilamino C1-5-alquilo C1-5, trialquilsilil C3-6-alquilo C1-5, fenil-alquilo C1-5 (donde el fenilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, heteroaril-alquilo C1-5 (donde el heteroarilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, haloalquenilo C2-5, cicloalquilo C3-8, fenilo o fenilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, o heteroarilo o heteroarilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro; Rb es alquilo C1-18, alquenilo C3-18, alquinilo C3-18, haloalquilo C2-10, cianoalquilo C1-10, nitroalquilo C1-10, aminoalquilo C2-10, alquilamino C1-5-alquilo C1-5, dialquilamino C2-8-alquilo C1-5, cicloalquilo C3-7-alquilo C1-5, alcoxi C1-5-alquilo C1-5, alqueniloxi C3-5-alquilo C1-5, alquiniloxi C3-5-alquilo C1-5, alquiltio C1-5-alquilo C1-5, alquilsulfinilo C1-5-alquilo C1-5, alquilsulfonilo C1-5-alquilo C1-5, alquilidenoaminoxi C2-8-alquilo C1-5, alquilcarbonilo C1-5-alquilo C1-5, alcoxicarbonilo C1-5-alquilo C1-5, aminocarbonil-alquilo C1-5, alquilaminocarbonil C1-5-alquilo C1-5, dialquilaminocarbonil C2-8-alquilo C1-5, alquilcarbonilamino C1-5-alquilo C1-5, N-alquilcarbonilo C1-5-N-alquilamino C1-5-alquilo C1-5, trialquilsililo C3-6-alquilo C1-5, fenil-alquilo C1-5 (donde el fenilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro), heteroaril-alquilo C1-5 (donde el heteroarilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquilo C1-3-tio, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, haloalquenilo C3-5, cicloalquilo C3-8, fenilo o fenilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, o heteroarilo o heteroarilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro; Rc y Rd son, de manera independiente entre sí, hidrogeno, alquilo C1-10, alquenilo C3-10, alquinilo C3-10, haloalquilo C2-10, cianoalquilo C1-10, nitroalquilo C1-10, aminoalquilo C1-10, alquilamino C1-5-alquilo C1-5, dialquilamino C2-8-alquilo C1-5, cicloalquilo C3-7-alquilo C1-5, alcoxi C1-5-alquilo C1-5, alqueniloxi C3-5-alquilo C1-5, alquiniloxi C3-5-alquilo C1-5, alquiltio C1-5-alquilo C1-5, alquilsulfinilo C1-5-alquilo C1-5, alquilsulfonilo C1-5-alquilo C1-5, alquilidenoaminoxi C2-8-alquilo C1-5, alquilcarbonilo C1-5-alquilo C1-5, alcoxicarbonilo C1-5-alquilo C1-5, aminocarbonil-alquilo C1-5, alquilaminocarbonil C1-5-alquilo C1-5, dialquilaminocarbonil C2-8-alquilo C1-5, alquilcarbonilamino C1-5-alquilo C1-5, N-alquilcarbonilo C1-5-N- alquilaminoalquilo C2-5, trialquilsilil C3-6-alquilo C1-5, fenil-alquilo C1-5 (donde el fenilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, heteroaril-alquilo C1-5 (donde el heteroarilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, haloalquenilo C2-5, cicloalquilo C3-8, fenilo o fenilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, heteroarilo o heteroarilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, heteroarilamino o heteroarilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, diheteroarilamino o diheteroarilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, fenilamino o fenilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, difenilamino o difenilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, o cicloalquilamino C3-7, di-cicloalquilamino C3-7 o cicloalcoxi C3-7 o Rc y Rd pueden estar unidos para formar un anillo de 3-7 miembros, que, en forma opcional, contiene un heteroátomo seleccionado de O o S; Re es alquilo C1-10, alquenilo C2-10, alquinilo C2-10, haloalquilo C1-10, cianoalquilo C1-10, nitroalquilo C1-10, aminoalquilo C1-10, alquilamino C1-5-alquilo C1-5, dialquilamino C2-8-alquilo C1-5, cicloalquilo C3-7-alquilo C1-5, alcoxi C1-5-alquilo C1-5, alqueniloxi C3-5-alquilo C1-5, alquiniloxi C3-5-aIquilo C1-5, alquiltio C1-5-alquilo C1-5, alquilsulfinilo C1-5-alquilo C1-5, alquilsulfonilo C1-5-alquilo C1-5, alquilidenoaminoxi C2-8-alquilo C1-5, alquilcarbonilo C1-5-alquilo C1-5, alcoxicarbonilo C1-5-alquilo C1-5, aminocarbonil-alquilo C1-5, alquilaminocarbonil C1-5-alquilo C1-5, dialquilaminocarbonil C2-8-alquilo C1-5, alquilcarbonilamino C1-5-alquilo C1-5, N-alquilcarbonil C1-5-N-alquilamino C1-5-alquilo C1-5, trialquilsilil C3-6-alquilo C1-5, fenil-alquilo C1-5 (donde el fenilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, heteroaril-alquilo C1-5 (donde el heteroarilo está opcionalmente sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, alquilsulfinilo C1-3, alquilsulfonilo C1-3, halogeno, ciano o nitro, haloalquenilo C2-5, cicloalquilo C3-8, fenilo o fenilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, heteroarilo o heteroarilo sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, heteroarilamino o heteroarilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, diheteroarilamino o diheteroarilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, fenilamino o fenilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, difenilamino, o difenilamino sustituido con alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, halogeno, ciano o nitro, o cicloalquilamino C3-7, di-cicloalquilamino C3-7 o cicloalcoxi C3-7, alcoxi C1-10, haloalcoxi C1-10, alquilamino C1-5 o dialquilamino C2-8; Rf y Rg son, de manera independiente entre sí, alquilo C1-10, alquenilo C2-10, alquinilo C2-10, alcoxi C1-10, haloalquilo C1-10, cianoalquilo C1-10, nitroalquilo C1-10, aminoalquilo C1-10, alquilamino C1-5-alquilo C1-5, dialquilamino C2-8-alquilo C1-5, cicloalquilo C3-7-alquilo C1-5, alcoxi C1-5-alquilo C1-5, alqueniloxi C3-5-alquilo C1-5, alquiniloxi C3-5-alquilo C1-5, alquiltio C1-5-alquilo C1-5, alquilsulfinilo C1-5-alquilo C1-5, alquilsulfonilo C1-5-alquilo C1-5, alquilidenoaminoxi C2-8-alquilo C1-5, alquilcarbonilo C1-5
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