AR073115A1 - Compuestos derivados de isoxazol como insecticidas - Google Patents
Compuestos derivados de isoxazol como insecticidasInfo
- Publication number
- AR073115A1 AR073115A1 ARP090103232A ARP090103232A AR073115A1 AR 073115 A1 AR073115 A1 AR 073115A1 AR P090103232 A ARP090103232 A AR P090103232A AR P090103232 A ARP090103232 A AR P090103232A AR 073115 A1 AR073115 A1 AR 073115A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- substituted
- haloalkyl
- independently
- formula
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/04—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P29/00—Non-central analgesic, antipyretic or antiinflammatory agents, e.g. antirheumatic agents; Non-steroidal antiinflammatory drugs [NSAID]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Tropical Medicine & Parasitology (AREA)
- Rheumatology (AREA)
- Pain & Pain Management (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invencion se relaciona con los procesos y productos intermedios para preparar compuestos de formula (1) o compuestos de formula (1'), con composiciones insecticidas, acaricidas, nematicidas y molusquicidas que comprenden los compuestos de formula (1) o compuestos de formula (1') y con los métodos de uso de los compuestos de formula (1) o de los compuestos de formula (1) para combatir y controlar plagas de insectos, ácaros, nematodos y moluscos. Reivindicacion 1: Un compuesto de formula (1) o un compuesto de formula (1') donde A1, A2, A3 y A4, o A1', A2', A3', A4', A 5' y A6', son independientemente uno de otro C-H, C-R6 o nitrogeno; G1 es oxígeno o azufre; R1 es hidrogeno, alquilo C1-8, alcoxi C1-8, alquilcarbonilo C1-8- o alcoxicarbonilo C1-8-; R2 es el grupo (z): donde L es un enlace simple o alquileno C1-6; R2a es hidrogeno o alquilo C1-8; Y1, Y2 e Y3 son independientemente uno de otro CR7aR8a, C=O, C=N-OR9a, N-R9a, O, S, SO, SO2, S=N-R9a o SO=N-R9a, con la condicion de que al menos uno de Y1, Y2 o Y3 no sea CR7aR8a; R7a y R8a son independientemente uno del otro hidrogeno, halogeno, alquilo C1-8 o haloalquilo C1-8; cada R9a es independientemente hidrogeno, ciano, nitro, alquilo C1-8, haloalquilo C1-8, alquilcarbonilo C1-8-, haloalquilcarbonilo C1-8-, alcoxicarbonilo C1-8-, haloalcoxicarbonilo C1-8-, alquilsulfonilo C1-8-, haloalquilsulfonilo C1-8, aril-alquilo C1-4- o aril-alquilo C1-4- donde cada porcion arilo está sustituida con uno a tres R11a o es heteroaril-alquilo C1-4 o heteroaril-alquilo C1-4- donde cada porcion heteroarilo está sustituida con uno a tres R11a; R11a es independientemente halogeno, ciano, nitro, alquilo C1-8, haloalquilo C1-8, alcoxi C1-8, haloalcoxi C1-8 o alcoxicarbonilo C1-8-; R3 es haloalquilo C1-8; R4 es arilo o arilo sustituido con uno a cinco R9 o heteroarilo o heteroarilo sustituido con uno a cinco R9; R5a y R5b son, independientemente uno de otro, hidrogeno, ciano, halogeno, alquiltio C1-8-, haloalquiltio C1-8-, alquilsulfinilo C1-8-, haloalquilsulfinilo C1-8-, alquilsulfonilo C1-8-, haloalquilsulfonilo C1-8-, ariltio- o ariltio- donde la porcion arilo está sustituida con uno a cinco R10, arilsulfinilo- o arilsulfinilo- donde la porcion arilo está sustituida con uno a cinco R10, arilsulfonilo- o arilsulfonilo- donde la porcion arilo está sustituida con uno a cinco R10, heterocicliltio- o heterocicliltio- donde la porcion heterociclilo está sustituida con uno a cinco R10, heterociclilsulfinilo- o heterociclilsulfinilo- donde la porcion heterociclilo está sustituida con uno a cinco R10 o heterociclilsulfonilo- o heterociclilsulfonilo- donde la porcion heterociclilo está sustituida con uno a cinco R10, alquilo C1-8, alquilo C1-8 sustituido con uno a cinco R7, alquenilo C2-8, alquinilo C2-8, haloalquilo C1-8, haloalquenilo C2-8, hidroxi, alcoxi C1-8, alqueniloxi C3-8, alquiniloxi C3-8 o haloalcoxi C1-8, con la condicion de que al menos uno de R5a y R5b no sea hidrogeno; cada R7 es independientemente halogeno, ciano, nitro, cicloalquilo C3-10, halocicloalquilo C3-10, hidroxi, alcoxi C1-8, haloalcoxi C1-8, mercapto, alquiltio C1-8-, haloalquiltio C1-8-, alquilsulfinilo C1-8-, haloalquilsulfinilo C1-8- alquilsulfonilo C1-8- o haloalquilsulfonilo C1-8- y cada R6, R9 y R10 es independientemente halogeno, ciano, nitro, alquilo C1-8, haloalquilo C1-8, cicloalquilo C3-10, halocicloalquilo C3-10, alquenilo C2-8, haloalquenilo C2-8, alquinilo C2-8, haloalquinilo C2-8, hidroxi, alcoxi C1-8, haloalcoxi C1-8, mercapto, alquiltio C1-8-, haloalquiltio C1-8-, alquilsulfinilo C1-8-, haloalquilsulfinilo C1-8-, alquilsulfonilo C1-8-, haloalquilsulfonilo C1-8-, alquilcarbonilo C1-8-, alcoxicarbonilo C1-8-, arilo o el arilo mismo sustituido con uno a cinco sustituyentes independientemente seleccionados de halogeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 o haloalcoxi C1-4 o heterociclilo o el mismo heterociclilo sustituido con uno a cinco sustituyentes independientemente seleccionados de halogeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 o haloalcoxi C1-4; o una sal o un N-oxido de los mismos.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0815437A GB0815437D0 (en) | 2008-08-22 | 2008-08-22 | Insecticidal compunds |
| GB0900561A GB0900561D0 (en) | 2009-01-14 | 2009-01-14 | Insecticidal compounds |
| GB0904868A GB0904868D0 (en) | 2009-03-20 | 2009-03-20 | Insecticidal compounds |
| GB0910771A GB0910771D0 (en) | 2009-06-22 | 2009-06-22 | Insecticidal compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR073115A1 true AR073115A1 (es) | 2010-10-13 |
Family
ID=41067604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP090103232A AR073115A1 (es) | 2008-08-22 | 2009-08-21 | Compuestos derivados de isoxazol como insecticidas |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US8822502B2 (es) |
| EP (1) | EP2331515B1 (es) |
| JP (1) | JP2012500782A (es) |
| KR (1) | KR20110044873A (es) |
| CN (2) | CN105294668A (es) |
| AR (1) | AR073115A1 (es) |
| AU (1) | AU2009284229A1 (es) |
| BR (1) | BRPI0917188A2 (es) |
| CA (1) | CA2733160A1 (es) |
| CO (1) | CO6341524A2 (es) |
| EA (1) | EA201100356A1 (es) |
| MA (1) | MA32574B1 (es) |
| MX (1) | MX2011001851A (es) |
| NZ (1) | NZ590755A (es) |
| TW (1) | TW201021707A (es) |
| UY (1) | UY32070A (es) |
| WO (1) | WO2010020521A1 (es) |
| ZA (1) | ZA201100804B (es) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5316808B2 (ja) | 2007-06-29 | 2013-10-16 | 日産化学工業株式会社 | 置換イソキサゾリン又はエノンオキシム化合物および有害生物防除剤 |
| TWI411395B (zh) * | 2007-12-24 | 2013-10-11 | Syngenta Participations Ag | 殺蟲化合物 |
| BRPI0915665B1 (pt) | 2008-07-09 | 2018-01-02 | Basf Se | Misturas pesticidas, métodos para proteger plantas do ataque ou infestação por insetos, acarídeos ou nematódeos, para controlar insetos, aracnídeos ou nematódeos, uso de uma mistura, e, composição pesticida ou parasiticida |
| KR20110028538A (ko) | 2008-07-09 | 2011-03-18 | 바스프 에스이 | 이속사졸린 화합물 ⅱ를 포함하는 살충 혼합물 |
| US20110269804A1 (en) | 2008-08-22 | 2011-11-03 | Syngenta Crop Protection Llc | Insecticidal compounds |
| US8822502B2 (en) | 2008-08-22 | 2014-09-02 | Syngenta Crop Protection Llc | Insecticidal compounds |
| WO2010025998A1 (en) | 2008-09-04 | 2010-03-11 | Syngenta Participations Ag | Insecticidal compounds |
| EA020318B1 (ru) | 2008-12-23 | 2014-10-30 | Басф Се | Иминные соединения для борьбы с беспозвоночными вредителями |
| US8633134B2 (en) | 2008-12-23 | 2014-01-21 | Basf Se | Substituted amidine compounds for combating animal pests |
| CN102300864A (zh) * | 2009-01-29 | 2011-12-28 | 先正达参股股份有限公司 | 杀虫化合物 |
| CN102369199A (zh) * | 2009-04-01 | 2012-03-07 | 巴斯夫欧洲公司 | 用于防治无脊椎动物害虫的异*唑啉化合物 |
| TWI487486B (zh) | 2009-12-01 | 2015-06-11 | Syngenta Participations Ag | 以異唑啉衍生物為主之殺蟲化合物 |
| HUE029006T2 (en) | 2009-12-17 | 2017-02-28 | Merial Inc | Anti-parasitic dihydrazoazole compounds and compositions containing them |
| EP2531493B1 (en) | 2010-02-01 | 2015-07-22 | Basf Se | Substituted ketonic isoxazoline compounds and derivatives for combating animal pests |
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| JP2012017289A (ja) | 2010-07-08 | 2012-01-26 | Bayer Cropscience Ag | 殺虫性ピロリン誘導体 |
| KR101508862B1 (ko) | 2010-08-05 | 2015-04-07 | 조에티스 엘엘씨 | 구충제로서 이속사졸린 유도체 |
| WO2012049327A2 (en) | 2010-10-15 | 2012-04-19 | Syngenta Participations Ag | Pesticidal mixtures |
| JP2014028758A (ja) | 2010-11-19 | 2014-02-13 | Nissan Chem Ind Ltd | 寄生虫及び衛生害虫防除剤 |
| UY33887A (es) | 2011-02-03 | 2012-09-28 | Syngenta Ltd | Métodos de control de plagas en la soja |
| US20140005235A1 (en) * | 2011-03-22 | 2014-01-02 | Syngenta Participations Ag | Insecticidal compounds |
| UY34104A (es) * | 2011-05-31 | 2013-01-03 | Syngenta Participations Ag | ?compuestos derivados benzamídicos heterocíclicos, procesos e intermedios para su preparación, composiciones y métodos para su uso?. |
| TWI555471B (zh) * | 2011-05-31 | 2016-11-01 | 先正達合夥公司 | 包含異唑啉衍生物之殺有害生物混合物 |
| KR101959930B1 (ko) * | 2011-05-31 | 2019-03-19 | 신젠타 파티서페이션즈 아게 | 이속사졸린 유도체를 포함하는 살충 혼합물 |
| BR112014003971A2 (pt) | 2011-08-25 | 2017-03-21 | Syngenta Participations Ag | métodos para o controle de cupins e formigas |
| JP6061934B2 (ja) * | 2011-08-25 | 2017-01-18 | シンジェンタ パーティシペーションズ アーゲー | 殺虫化合物としてのイソオキサゾリン誘導体 |
| WO2013026695A1 (en) * | 2011-08-25 | 2013-02-28 | Syngenta Participations Ag | Isoxazoline derivatives as insecticidal compounds |
| BR112014003730A2 (pt) | 2011-08-25 | 2017-03-14 | Syngenta Participations Ag | processo para a preparação de derivados de tietano |
| CN103781356A (zh) * | 2011-08-25 | 2014-05-07 | 先正达参股股份有限公司 | 作为杀虫化合物的异噁唑啉衍生物 |
| CA2858766A1 (en) | 2011-12-23 | 2013-06-27 | Basf Se | Isothiazoline compounds for combating invertebrate pests |
| BR112015001908A2 (pt) | 2012-07-31 | 2017-07-04 | Syngenta Participations Ag | métodos de controle de pragas em soja |
| CN104519739A (zh) | 2012-08-03 | 2015-04-15 | 先正达参股股份有限公司 | 大豆有害生物控制的方法 |
| US20150152070A1 (en) | 2012-08-03 | 2015-06-04 | Syngenta Paricipations Ag | Methods of pest control in soybean |
| WO2014019951A1 (en) | 2012-08-03 | 2014-02-06 | Syngenta Participations Ag | Methods of controlling insects |
| WO2014024752A1 (ja) * | 2012-08-07 | 2014-02-13 | 国立大学法人名古屋工業大学 | ５－トリフルオロメチル－４－トリフルオロメチルスルホニル－２－イソキサゾリン誘導体およびその製造方法 |
| BR112015003630A2 (pt) | 2012-08-24 | 2017-07-04 | Syngenta Participations Ag | métodos de controle de insetos |
| CA2879794C (en) | 2012-08-24 | 2022-01-11 | Syngenta Participations Ag | Methods of soil pest control |
| EP2887809B1 (en) | 2012-08-24 | 2018-11-21 | Syngenta Participations AG | Methods of controlling insects |
| ES2905848T3 (es) | 2013-11-01 | 2022-04-12 | Boehringer Ingelheim Animal Health Usa Inc | Compuestos de isoxazolina antiparasitarios y plaguicidas |
| WO2018166855A1 (en) | 2017-03-16 | 2018-09-20 | Basf Se | Heterobicyclic substituted dihydroisoxazoles |
| CN111491926B (zh) * | 2017-12-15 | 2022-07-15 | 组合化学工业株式会社 | 5,5-二取代-4,5-二氢异噁唑的新型制造方法 |
| TWI812673B (zh) * | 2018-02-12 | 2023-08-21 | 美商富曼西公司 | 用於防治無脊椎害蟲之萘異噁唑啉化合物 |
| CN111909143B (zh) * | 2020-07-30 | 2021-10-29 | 山东省联合农药工业有限公司 | 一种异噁唑啉取代的苯甲酰胺类衍生物及其制备方法与用途 |
| AU2022380979A1 (en) | 2021-11-02 | 2024-06-06 | Flare Therapeutics Inc. | Pparg inverse agonists and uses thereof |
| WO2024029638A1 (ko) * | 2022-08-01 | 2024-02-08 | 한국과학기술연구원 | 신규한 헤테로사이클릴-페닐-메틸아민 유도체, 이의 제조방법 및 이의 다발성 경화증 예방, 개선, 또는 치료 용도 |
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| AU2009270255B2 (en) | 2008-07-09 | 2013-12-12 | Nissan Chemical Corporation | Process for production of isoxazoline-substituted benzoic acid amide compound |
| KR20110028538A (ko) | 2008-07-09 | 2011-03-18 | 바스프 에스이 | 이속사졸린 화합물 ⅱ를 포함하는 살충 혼합물 |
| BRPI0915665B1 (pt) | 2008-07-09 | 2018-01-02 | Basf Se | Misturas pesticidas, métodos para proteger plantas do ataque ou infestação por insetos, acarídeos ou nematódeos, para controlar insetos, aracnídeos ou nematódeos, uso de uma mistura, e, composição pesticida ou parasiticida |
| US8822502B2 (en) | 2008-08-22 | 2014-09-02 | Syngenta Crop Protection Llc | Insecticidal compounds |
| US20110269804A1 (en) | 2008-08-22 | 2011-11-03 | Syngenta Crop Protection Llc | Insecticidal compounds |
| WO2010025998A1 (en) | 2008-09-04 | 2010-03-11 | Syngenta Participations Ag | Insecticidal compounds |
| JP2010083883A (ja) | 2008-09-08 | 2010-04-15 | Nissan Chem Ind Ltd | イソキサゾリン置換ベンズアミド化合物及び有害生物防除剤 |
| EP2379544B1 (en) | 2008-12-18 | 2013-10-16 | Novartis AG | Isoxazolines derivatives and their use as pesticide |
| JP2010168367A (ja) | 2008-12-25 | 2010-08-05 | Nissan Chem Ind Ltd | 置換イソキサゾリン化合物又は置換エノンオキシム化合物及び有害生物防除剤 |
| CN102292331A (zh) | 2009-01-22 | 2011-12-21 | 先正达参股股份有限公司 | 杀虫化合物 |
| CN102300864A (zh) | 2009-01-29 | 2011-12-28 | 先正达参股股份有限公司 | 杀虫化合物 |
| CN102365278B (zh) * | 2009-03-26 | 2015-05-06 | 先正达参股股份有限公司 | 杀虫化合物 |
| JP2012525353A (ja) | 2009-04-30 | 2012-10-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 置換型イソオキサゾリン化合物およびその前駆体の調製方法 |
| WO2010149506A1 (en) | 2009-06-22 | 2010-12-29 | Syngenta Participations Ag | Insecticidal compounds |
-
2009
- 2009-07-24 US US13/060,218 patent/US8822502B2/en active Active
- 2009-07-24 AU AU2009284229A patent/AU2009284229A1/en not_active Abandoned
- 2009-07-24 CA CA2733160A patent/CA2733160A1/en not_active Abandoned
- 2009-07-24 BR BRPI0917188-6A patent/BRPI0917188A2/pt active Search and Examination
- 2009-07-24 CN CN201510685828.XA patent/CN105294668A/zh active Pending
- 2009-07-24 WO PCT/EP2009/059562 patent/WO2010020521A1/en active Application Filing
- 2009-07-24 MX MX2011001851A patent/MX2011001851A/es not_active Application Discontinuation
- 2009-07-24 CN CN2009801325027A patent/CN102131789A/zh active Pending
- 2009-07-24 EA EA201100356A patent/EA201100356A1/ru unknown
- 2009-07-24 JP JP2011523377A patent/JP2012500782A/ja active Pending
- 2009-07-24 KR KR1020117003869A patent/KR20110044873A/ko not_active Application Discontinuation
- 2009-07-24 EP EP09781036.0A patent/EP2331515B1/en active Active
- 2009-07-24 NZ NZ590755A patent/NZ590755A/xx not_active IP Right Cessation
- 2009-08-21 UY UY0001032070A patent/UY32070A/es unknown
- 2009-08-21 AR ARP090103232A patent/AR073115A1/es not_active Application Discontinuation
- 2009-08-21 TW TW098128132A patent/TW201021707A/zh unknown
-
2011
- 2011-01-31 ZA ZA2011/00804A patent/ZA201100804B/en unknown
- 2011-02-18 MA MA33629A patent/MA32574B1/fr unknown
- 2011-02-21 CO CO11020661A patent/CO6341524A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2733160A1 (en) | 2010-02-25 |
| JP2012500782A (ja) | 2012-01-12 |
| TW201021707A (en) | 2010-06-16 |
| EP2331515A1 (en) | 2011-06-15 |
| ZA201100804B (en) | 2013-07-31 |
| NZ590755A (en) | 2012-11-30 |
| EA201100356A1 (ru) | 2011-10-31 |
| CN102131789A (zh) | 2011-07-20 |
| US20110166184A1 (en) | 2011-07-07 |
| AU2009284229A1 (en) | 2010-02-25 |
| MA32574B1 (fr) | 2011-08-01 |
| EP2331515B1 (en) | 2013-07-10 |
| CN105294668A (zh) | 2016-02-03 |
| KR20110044873A (ko) | 2011-05-02 |
| MX2011001851A (es) | 2011-03-21 |
| BRPI0917188A2 (pt) | 2015-08-18 |
| US8822502B2 (en) | 2014-09-02 |
| UY32070A (es) | 2010-03-26 |
| WO2010020521A1 (en) | 2010-02-25 |
| CO6341524A2 (es) | 2011-11-21 |
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