AR072884A1 - Aditivo con sistema multiple de zeolitas para unidades de craqueo catalitico fluido y metodo de preparacion - Google Patents

Aditivo con sistema multiple de zeolitas para unidades de craqueo catalitico fluido y metodo de preparacion

Info

Publication number
AR072884A1
AR072884A1 ARP090102893A ARP090102893A AR072884A1 AR 072884 A1 AR072884 A1 AR 072884A1 AR P090102893 A ARP090102893 A AR P090102893A AR P090102893 A ARP090102893 A AR P090102893A AR 072884 A1 AR072884 A1 AR 072884A1
Authority
AR
Argentina
Prior art keywords
additive
fluid catalytic
units
zeolites
preparation
Prior art date
Application number
ARP090102893A
Other languages
English (en)
Inventor
Rodrigues Sergio Augusto Santos
Lam Yiu Lau
Figueiredo Costa Alexandre De
Macelo Andre Torem
De Almeida Marlon Brando Bezerra
Original Assignee
Petroleo Brasileiro Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa filed Critical Petroleo Brasileiro Sa
Publication of AR072884A1 publication Critical patent/AR072884A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Se han descripto aditivos para mezclar al inventario de catalizador en unidades de proceso de craqueo catalítico fluido - FCC para maximizar la produccion de GLP y de olefinas livianas. Tales aditivos comprenden una matriz que tiene incorporados una zeolita de tipo MFI, preferiblemente zeolita ZSM-5, una zeolita de tipo Y, y una fuente de fosforo, en una unica partícula. La mezcla de aditivo en proporciones de 1,0 a 40% en masa al catalizador de equilibrio de una unidad de FCC maximiza la produccion de GLP y de olefinas livianas, principalmente propeno.
ARP090102893A 2008-09-19 2009-07-29 Aditivo con sistema multiple de zeolitas para unidades de craqueo catalitico fluido y metodo de preparacion AR072884A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0803617-9A BRPI0803617A2 (pt) 2008-09-19 2008-09-19 Aditivo com sistema múltiplo de zeólitas e método de preparo

Publications (1)

Publication Number Publication Date
AR072884A1 true AR072884A1 (es) 2010-09-29

Family

ID=41445423

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP090102893A AR072884A1 (es) 2008-09-19 2009-07-29 Aditivo con sistema multiple de zeolitas para unidades de craqueo catalitico fluido y metodo de preparacion

Country Status (7)

Country Link
US (1) US20110207984A1 (es)
EP (1) EP2350234A1 (es)
JP (2) JP5662936B2 (es)
CN (1) CN102131899B (es)
AR (1) AR072884A1 (es)
BR (1) BRPI0803617A2 (es)
WO (1) WO2010032025A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0803617A2 (pt) * 2008-09-19 2010-06-15 Petroleo Brasileiro Sa Aditivo com sistema múltiplo de zeólitas e método de preparo
KR20120029429A (ko) * 2009-05-19 2012-03-26 쉘 인터내셔날 리써취 마트샤피지 비.브이. 배합 산소화물 전환 촉매의 제조 방법, 배합 산소화물 전환 촉매 및 올레핀계 생성물의 제조 방법
EP2855012B1 (en) 2012-05-25 2019-06-26 Saudi Arabian Oil Company Catalyst for enhanced propylene in fluidized catalytic cracking
CN103447063B (zh) * 2012-06-01 2016-02-10 中国石油天然气股份有限公司 重油高效转化催化裂化催化剂及其制备方法
US8895790B2 (en) 2013-02-12 2014-11-25 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products
US9428695B2 (en) 2013-02-12 2016-08-30 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products with product recycle
US9447332B2 (en) 2013-02-12 2016-09-20 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products using temperature control
CN104096590B (zh) * 2013-04-10 2016-09-14 上海碧科清洁能源技术有限公司 混合分子筛催化剂及其制备方法和应用
CN105983400B (zh) * 2015-01-28 2018-07-13 中国石油天然气股份有限公司 一种中孔氧化铝粘结剂的制备方法及其在重油催化裂化催化剂中的应用
CN108025298B (zh) 2015-07-23 2021-07-06 雅宝公司 Fcc催化剂添加剂和粘合剂
KR20200026792A (ko) * 2017-04-10 2020-03-11 릴라이언스 인더스트리즈 리미티드 Fcc 촉매 첨가제 및 그의 제조 방법

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758403A (en) * 1970-10-06 1973-09-11 Mobil Oil Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze
AU595706B2 (en) * 1987-06-11 1990-04-05 Mobil Oil Corporation Integrated process for gasoline production
US5456821A (en) * 1991-03-12 1995-10-10 Mobil Oil Corp. Catalytic conversion with improved catalyst
JPH06313176A (ja) * 1993-03-02 1994-11-08 Nippon Oil Co Ltd 重質油の流動接触分解法
US5472594A (en) * 1994-07-18 1995-12-05 Texaco Inc. FCC process for producing enhanced yields of C4 /C5 olefins
DE69832938T2 (de) * 1997-10-15 2006-08-10 China Petro-Chemical Corp. Krackkatalysator für die Produktion von leichten Olefinen und dessen Herstellung
EP1116775A1 (en) * 2000-01-12 2001-07-18 Akzo Nobel N.V. Catalyst composition with high efficiency for the production of light olefins
ES2168208B1 (es) * 2000-03-24 2003-04-01 Univ Valencia Politecnica Catalizadores de craqueo basados en zeolitas.
US6858556B2 (en) * 2002-02-25 2005-02-22 Indian Oil Corporation Limited Stabilized dual zeolite single particle catalyst composition and a process thereof
AR052122A1 (es) * 2004-11-05 2007-03-07 Grace W R & Co Catalizadores para olefinas livianas y glp gas licuado de petroleo en unidades de craqueo catalitico fluidizado
JP5008666B2 (ja) * 2006-06-28 2012-08-22 出光興産株式会社 脱硫機能付加流動接触分解触媒及びその製造方法並びに該脱硫機能付加流動接触分解触媒を用いた低硫黄接触分解ガソリンの製造方法
BRPI0602678B1 (pt) * 2006-07-14 2015-09-01 Petroleo Brasileiro Sa Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo
US9701914B2 (en) * 2006-11-07 2017-07-11 Saudi Arabian Oil Company Advanced control of severe fluid catalytic cracking process for maximizing propylene production from petroleum feedstock
BRPI0803617A2 (pt) * 2008-09-19 2010-06-15 Petroleo Brasileiro Sa Aditivo com sistema múltiplo de zeólitas e método de preparo

Also Published As

Publication number Publication date
WO2010032025A1 (en) 2010-03-25
JP5860516B2 (ja) 2016-02-16
JP5662936B2 (ja) 2015-02-04
CN102131899B (zh) 2016-05-18
JP2012503065A (ja) 2012-02-02
US20110207984A1 (en) 2011-08-25
BRPI0803617A2 (pt) 2010-06-15
EP2350234A1 (en) 2011-08-03
JP2015063686A (ja) 2015-04-09
CN102131899A (zh) 2011-07-20

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