AR061455A1 - Acidos fosfinicos y sus derivados de azufre y metodos para su preparacion - Google Patents
Acidos fosfinicos y sus derivados de azufre y metodos para su preparacionInfo
- Publication number
- AR061455A1 AR061455A1 ARP070102602A ARP070102602A AR061455A1 AR 061455 A1 AR061455 A1 AR 061455A1 AR P070102602 A ARP070102602 A AR P070102602A AR P070102602 A ARP070102602 A AR P070102602A AR 061455 A1 AR061455 A1 AR 061455A1
- Authority
- AR
- Argentina
- Prior art keywords
- heteroalkyl
- optionally substituted
- methods
- formula
- substituted alkyl
- Prior art date
Links
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 150000003463 sulfur Chemical class 0.000 title 1
- 125000004404 heteroalkyl group Chemical group 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 125000000592 heterocycloalkyl group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/5059—Preparation; Separation; Purification; Stabilisation by addition of phosphorus compounds to alkenes or alkynes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
En el cual dicho compuesto es un líquido a temperatura ambiente. Los compuestos de la formula (1) encuentran utilidad por ejemplo, como extractantes de metales. También se proveen los métodos para hacer los compuestos de la formula (1) y sus correspondientes intermediarios de fosfina. Reivindicacion 1: Un compuesto definido por la formula (1): en la cual: R1 y R2 son diferentes y cada uno de R1 y R2 se selecciona independientemente a partir: (a) /-CH2-CHR3R4, en el cual R3 es metilo o etilo; y R4 es un alquilo o heteroalquilo opcionalmente sustituido; y (b) /-CR3 (CH2R5)R6, en el cual R3 es metilo o rtilo; y R5 es H o un alquilo o heteroalquilo opcionalmente sustituido o heteroalquilo, y R6 es un alquilo o heteroalquilo opcionalmente sustituido o heteroalquilo; o R5, R6 y el grupo etileno al cual se unen forman un anillo cicloalquilo o heterocicloalquilo opcionalmente sustituido de cinco o seis miembros; y cada uno de X e Y es independientemente O o S.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2550557A CA2550557C (en) | 2006-06-14 | 2006-06-14 | Novel phosphinic acids and their sulfur derivatives and methods for their preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR061455A1 true AR061455A1 (es) | 2008-08-27 |
Family
ID=38829313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP070102602A AR061455A1 (es) | 2006-06-14 | 2007-06-13 | Acidos fosfinicos y sus derivados de azufre y metodos para su preparacion |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US8764880B2 (es) |
| EP (1) | EP2029613B1 (es) |
| CN (1) | CN101472934B (es) |
| AP (1) | AP2496A (es) |
| AR (1) | AR061455A1 (es) |
| AU (2) | AU2007260536B2 (es) |
| BR (1) | BRPI0713640B1 (es) |
| CA (1) | CA2550557C (es) |
| CY (1) | CY1118170T1 (es) |
| ES (1) | ES2594652T3 (es) |
| IL (1) | IL195766A (es) |
| MX (2) | MX343745B (es) |
| PE (1) | PE20080307A1 (es) |
| RU (1) | RU2451021C2 (es) |
| WO (1) | WO2007143832A1 (es) |
| ZA (1) | ZA200810576B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8968698B2 (en) | 2009-07-07 | 2015-03-03 | Cytec Technology Corp. | Processes for recovering metals from aqueous solutions |
| PE20160329A1 (es) | 2009-07-07 | 2016-04-27 | Cytec Tech Corp | Procesos para recuperar metales de soluciones acuosas |
| CN101619074B (zh) * | 2009-07-27 | 2012-07-04 | 清华大学 | 不对称二硫代次膦酸的合成方法 |
| DE102011121591A1 (de) | 2011-12-16 | 2013-06-20 | Clariant International Ltd. | Gemische aus Dialkylphosphinsäuren und Alkylphosphonsäuren, ein Verfahren zu deren Herstellung und ihre Verwendung |
| DE102011121900A1 (de) * | 2011-12-21 | 2013-06-27 | Clariant International Ltd. | Gemische von mindestens einer Dialkylphosphinsäure mit mindestens einer anderen, davon unterschiedlichen Dialkylphosphinsäure, Verfahren zu deren Herstellung und ihre Verwendung |
| CN104402923A (zh) * | 2014-11-14 | 2015-03-11 | 南开大学 | 一种二烷基次膦酸混合物的一步合成法 |
| CN108517406B (zh) * | 2018-04-19 | 2020-01-03 | 中国人民解放军国防科技大学 | 选择性分离三价次锕系元素与三价镧系元素的固相萃取剂及其制备方法和应用 |
| CN109081944B (zh) * | 2018-06-28 | 2020-05-12 | 浙江大学 | 二烷基二硫代次磷酸盐阻燃剂及其应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US437480A (en) * | 1890-09-30 | Indicator | ||
| US2584112A (en) | 1950-08-30 | 1952-02-05 | Standard Oil Co | Organic phosphines |
| GB902802A (en) | 1958-12-16 | 1962-08-09 | American Cyanamid Co | Organic dithiophosphinic compounds and the preparation thereof |
| US4353883A (en) | 1980-08-28 | 1982-10-12 | American Cyanamid Company | Selective extraction of cobalt(II) from aqueous solutions with phosphinic acid extractants |
| US4348367A (en) | 1980-08-28 | 1982-09-07 | American Cyanamid Company | Selective removal of cobalt(II) from aqueous solutions with phosphinic extractants |
| MA19258A1 (fr) * | 1980-08-28 | 1982-04-01 | Canada Cyanamid | Procede de separation selective de cobalt (ii) de solutions aqueuses . |
| US4374780A (en) | 1981-05-14 | 1983-02-22 | American Cyanamid Company | Di-2,4,4'-trimethylpentylphosphinic acid and its preparation |
| US4374178A (en) | 1980-12-29 | 1983-02-15 | Union Carbide Corporation | Silanated calcium carbonate fillers |
| SU1074878A1 (ru) * | 1982-12-07 | 1984-02-23 | Московский Ордена Ленина,Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Государственный Университет Им.М.В.Ломоносова | Метиленбис ( @ -оксиалкил) фосфиновые кислоты |
| US4555368A (en) * | 1984-11-28 | 1985-11-26 | American Cyanamid Company | Process for synthesizing diorganomonothiophosphinates |
| US4721605A (en) * | 1985-07-24 | 1988-01-26 | American Cyanamid Company | Selective removal of metals from aqueous solutions with dithiophosphinic acids |
| US5028403A (en) * | 1989-05-31 | 1991-07-02 | American Cyanamid Company | Metal recovery with monothiophosphinic acids |
| JP3830986B2 (ja) * | 1995-03-07 | 2006-10-11 | 日本化学工業株式会社 | ジ（１，１，３，３−テトラメチルブチル）ホスフィン及びその製造方法 |
-
2006
- 2006-06-14 CA CA2550557A patent/CA2550557C/en not_active Expired - Fee Related
-
2007
- 2007-06-12 CN CN200780022303.1A patent/CN101472934B/zh not_active Expired - Fee Related
- 2007-06-12 AU AU2007260536A patent/AU2007260536B2/en not_active Ceased
- 2007-06-12 RU RU2009100922/04A patent/RU2451021C2/ru not_active IP Right Cessation
- 2007-06-12 EP EP07719959.4A patent/EP2029613B1/en not_active Not-in-force
- 2007-06-12 AP AP2008004681A patent/AP2496A/xx active
- 2007-06-12 ES ES07719959.4T patent/ES2594652T3/es active Active
- 2007-06-12 MX MX2014014006A patent/MX343745B/es unknown
- 2007-06-12 MX MX2008015381A patent/MX2008015381A/es active IP Right Grant
- 2007-06-12 US US12/304,484 patent/US8764880B2/en not_active Expired - Fee Related
- 2007-06-12 BR BRPI0713640A patent/BRPI0713640B1/pt not_active IP Right Cessation
- 2007-06-12 WO PCT/CA2007/001043 patent/WO2007143832A1/en active Application Filing
- 2007-06-13 AR ARP070102602A patent/AR061455A1/es not_active Application Discontinuation
- 2007-06-13 PE PE2007000743A patent/PE20080307A1/es not_active Application Discontinuation
-
2008
- 2008-12-07 IL IL195766A patent/IL195766A/en active IP Right Grant
- 2008-12-12 ZA ZA200810576A patent/ZA200810576B/xx unknown
-
2014
- 2014-05-23 US US14/286,254 patent/US9102695B2/en not_active Expired - Fee Related
- 2014-06-19 AU AU2014203337A patent/AU2014203337A1/en not_active Abandoned
-
2016
- 2016-10-19 CY CY20161101051T patent/CY1118170T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2029613B1 (en) | 2016-07-20 |
| EP2029613A4 (en) | 2011-09-14 |
| US20140275615A1 (en) | 2014-09-18 |
| PE20080307A1 (es) | 2008-04-14 |
| US20090165598A1 (en) | 2009-07-02 |
| CN101472934B (zh) | 2015-05-20 |
| CA2550557A1 (en) | 2007-12-14 |
| ES2594652T3 (es) | 2016-12-21 |
| CA2550557C (en) | 2011-03-29 |
| RU2009100922A (ru) | 2010-07-20 |
| MX343745B (es) | 2016-11-22 |
| US8764880B2 (en) | 2014-07-01 |
| IL195766A0 (en) | 2009-09-01 |
| CY1118170T1 (el) | 2017-06-28 |
| AU2007260536B2 (en) | 2014-04-03 |
| EP2029613A1 (en) | 2009-03-04 |
| AU2014203337A1 (en) | 2014-07-10 |
| RU2451021C2 (ru) | 2012-05-20 |
| CN101472934A (zh) | 2009-07-01 |
| US9102695B2 (en) | 2015-08-11 |
| ZA200810576B (en) | 2009-10-28 |
| MX2008015381A (es) | 2009-05-05 |
| AP2496A (en) | 2012-10-19 |
| WO2007143832A1 (en) | 2007-12-21 |
| BRPI0713640A2 (pt) | 2012-10-23 |
| AP2008004681A0 (en) | 2008-12-31 |
| IL195766A (en) | 2013-09-30 |
| AU2007260536A1 (en) | 2007-12-21 |
| BRPI0713640B1 (pt) | 2016-10-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration | ||
| FD | Application declared void or lapsed, e.g., due to non-payment of fee |