PE20080307A1 - Nuevos acidos fosfinicos y sus derivados de azufre y metodos para su preparacion - Google Patents
Nuevos acidos fosfinicos y sus derivados de azufre y metodos para su preparacionInfo
- Publication number
- PE20080307A1 PE20080307A1 PE2007000743A PE2007000743A PE20080307A1 PE 20080307 A1 PE20080307 A1 PE 20080307A1 PE 2007000743 A PE2007000743 A PE 2007000743A PE 2007000743 A PE2007000743 A PE 2007000743A PE 20080307 A1 PE20080307 A1 PE 20080307A1
- Authority
- PE
- Peru
- Prior art keywords
- acid
- produce
- olefin
- ethyl
- methyl
- Prior art date
Links
- 239000002253 acid Substances 0.000 title abstract 6
- 150000007513 acids Chemical class 0.000 title abstract 3
- 150000003463 sulfur Chemical class 0.000 title 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- -1 1,1,3,3-TETRAMETHYLBUTYL Chemical class 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical group C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 abstract 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/5059—Preparation; Separation; Purification; Stabilisation by addition of phosphorus compounds to alkenes or alkynes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
SIENDO LOS ACIDOS FOSFINICOS DE FORMULA (I), DONDE R1 Y R2 SON DIFERENTES Y CADA UNO SE SELECCIONA INDEPENDIENTEMENTE A PARTIR: a) /-CH2-CHR3R4, DONDE R3 ES METILO O ETILO, Y R4 ES UN ALQUILO O HETEROALQUILO OPCIONALMENTE SUSTITUIDO; Y, b) /-CR3(CH2R5)R6, DONDE R3 ES METILO O ETILO, R5 ES H O UN ALQUILO O HETEROALQUILO OPCIONALMENTE SUSTITUIDO, Y R6 ES UN ALQUILO O HETEROALQUILO OPCIONALMENTE SUSTITUIDO; O R5, R6 Y EL GRUPO ETILENO AL CUAL SE UNEN FORMAN UN ANILLO CICLOALQUILO O HETEROCICLOALQUILO OPCIONALMENTE SUSTITUIDO DE CINCO O SEIS MIEMBROS; Y CADA X E Y ES INDEPENDIENTEMENTE O o S. EL METODO INCLUYE: i) PREPARAR UNA FOSFINA SECUNDARIA DE FORMULA (II) DONDE SE DEJA REACCIONAR UNA FOSFINA PRIMARIA (R1PH2) CON: UNA OLEFINA (CH2=CR3R4) BAJO CONDICIONES DE RADICAL LIBRE, CUANDO R2 ES (a), Y EN PRESENCIA DE UN CATALIZADOR ACIDO (ACIDO METANOSULFONICO) CON UNA OLEFINA (HR5C=CR3R6), CUANDO R2 ES (b); Y, ii) DEJAR QUE LA FOSFINA SECUNDARIA REACCIONE CON: A)UN AGENTE OXIDANTE (PEROXIDO DE HIDROGENO), PARA PRODUCIR ACIDO FOSFINICO; O, B)AZUFRE, PARA PRODUCIR ACIDO DITIOFOSFINICO; O, C)UNA CANTIDAD LIMITADA DE AGENTE OXIDANTE, PARA PRODUCIR OXIDO DE FOSFINA QUE REACCIONA CON AZUFRE PARA PRODUCIR ACIDO MONOTIOFOSFINICO. LA OLEFINA ES DIISOBUTILENO. LOS COMPUESTOS PREFERIDOS SON ACIDOS FOSFINICOS DE: (2,4,4-TRIMETILPENTIL)(1,1,3,3-TETRAMETILBUTIL); (1,1,3,3-TETRAMETILBUTIL)(2-ETIL-HEXIL), (2,4,4-TRIMETILPENTIL)(2-ETILHEXIL) Y (2,4,4-TRIMETILPENTIL)(1-METIL-1-ETILPENTIL), ENTRE OTROS
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2550557A CA2550557C (en) | 2006-06-14 | 2006-06-14 | Novel phosphinic acids and their sulfur derivatives and methods for their preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20080307A1 true PE20080307A1 (es) | 2008-04-14 |
Family
ID=38829313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2007000743A PE20080307A1 (es) | 2006-06-14 | 2007-06-13 | Nuevos acidos fosfinicos y sus derivados de azufre y metodos para su preparacion |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US8764880B2 (es) |
| EP (1) | EP2029613B1 (es) |
| CN (1) | CN101472934B (es) |
| AP (1) | AP2496A (es) |
| AR (1) | AR061455A1 (es) |
| AU (2) | AU2007260536B2 (es) |
| BR (1) | BRPI0713640B1 (es) |
| CA (1) | CA2550557C (es) |
| CY (1) | CY1118170T1 (es) |
| ES (1) | ES2594652T3 (es) |
| IL (1) | IL195766A (es) |
| MX (2) | MX343745B (es) |
| PE (1) | PE20080307A1 (es) |
| RU (1) | RU2451021C2 (es) |
| WO (1) | WO2007143832A1 (es) |
| ZA (1) | ZA200810576B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2012000233A (es) * | 2009-07-07 | 2012-01-25 | Cytec Tech Corp | Procesos para recuperar metales de las soluciones acuosas. |
| US8968698B2 (en) | 2009-07-07 | 2015-03-03 | Cytec Technology Corp. | Processes for recovering metals from aqueous solutions |
| CN101619074B (zh) * | 2009-07-27 | 2012-07-04 | 清华大学 | 不对称二硫代次膦酸的合成方法 |
| DE102011121591A1 (de) | 2011-12-16 | 2013-06-20 | Clariant International Ltd. | Gemische aus Dialkylphosphinsäuren und Alkylphosphonsäuren, ein Verfahren zu deren Herstellung und ihre Verwendung |
| DE102011121900A1 (de) * | 2011-12-21 | 2013-06-27 | Clariant International Ltd. | Gemische von mindestens einer Dialkylphosphinsäure mit mindestens einer anderen, davon unterschiedlichen Dialkylphosphinsäure, Verfahren zu deren Herstellung und ihre Verwendung |
| CN104402923A (zh) * | 2014-11-14 | 2015-03-11 | 南开大学 | 一种二烷基次膦酸混合物的一步合成法 |
| CN108517406B (zh) * | 2018-04-19 | 2020-01-03 | 中国人民解放军国防科技大学 | 选择性分离三价次锕系元素与三价镧系元素的固相萃取剂及其制备方法和应用 |
| CN109081944B (zh) * | 2018-06-28 | 2020-05-12 | 浙江大学 | 二烷基二硫代次磷酸盐阻燃剂及其应用 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US437480A (en) * | 1890-09-30 | Indicator | ||
| US2584112A (en) * | 1950-08-30 | 1952-02-05 | Standard Oil Co | Organic phosphines |
| GB902802A (en) | 1958-12-16 | 1962-08-09 | American Cyanamid Co | Organic dithiophosphinic compounds and the preparation thereof |
| MA19258A1 (fr) | 1980-08-28 | 1982-04-01 | Canada Cyanamid | Procede de separation selective de cobalt (ii) de solutions aqueuses . |
| US4353883A (en) * | 1980-08-28 | 1982-10-12 | American Cyanamid Company | Selective extraction of cobalt(II) from aqueous solutions with phosphinic acid extractants |
| US4348367A (en) | 1980-08-28 | 1982-09-07 | American Cyanamid Company | Selective removal of cobalt(II) from aqueous solutions with phosphinic extractants |
| US4374780A (en) * | 1981-05-14 | 1983-02-22 | American Cyanamid Company | Di-2,4,4'-trimethylpentylphosphinic acid and its preparation |
| US4374178A (en) | 1980-12-29 | 1983-02-15 | Union Carbide Corporation | Silanated calcium carbonate fillers |
| SU1074878A1 (ru) * | 1982-12-07 | 1984-02-23 | Московский Ордена Ленина,Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Государственный Университет Им.М.В.Ломоносова | Метиленбис ( @ -оксиалкил) фосфиновые кислоты |
| US4555368A (en) * | 1984-11-28 | 1985-11-26 | American Cyanamid Company | Process for synthesizing diorganomonothiophosphinates |
| US4721605A (en) | 1985-07-24 | 1988-01-26 | American Cyanamid Company | Selective removal of metals from aqueous solutions with dithiophosphinic acids |
| US5028403A (en) | 1989-05-31 | 1991-07-02 | American Cyanamid Company | Metal recovery with monothiophosphinic acids |
| JP3830986B2 (ja) * | 1995-03-07 | 2006-10-11 | 日本化学工業株式会社 | ジ（１，１，３，３−テトラメチルブチル）ホスフィン及びその製造方法 |
-
2006
- 2006-06-14 CA CA2550557A patent/CA2550557C/en not_active Expired - Fee Related
-
2007
- 2007-06-12 RU RU2009100922/04A patent/RU2451021C2/ru not_active IP Right Cessation
- 2007-06-12 EP EP07719959.4A patent/EP2029613B1/en not_active Not-in-force
- 2007-06-12 AP AP2008004681A patent/AP2496A/xx active
- 2007-06-12 US US12/304,484 patent/US8764880B2/en not_active Expired - Fee Related
- 2007-06-12 MX MX2014014006A patent/MX343745B/es unknown
- 2007-06-12 MX MX2008015381A patent/MX2008015381A/es active IP Right Grant
- 2007-06-12 BR BRPI0713640A patent/BRPI0713640B1/pt not_active IP Right Cessation
- 2007-06-12 ES ES07719959.4T patent/ES2594652T3/es active Active
- 2007-06-12 CN CN200780022303.1A patent/CN101472934B/zh not_active Expired - Fee Related
- 2007-06-12 AU AU2007260536A patent/AU2007260536B2/en not_active Ceased
- 2007-06-12 WO PCT/CA2007/001043 patent/WO2007143832A1/en active Application Filing
- 2007-06-13 PE PE2007000743A patent/PE20080307A1/es not_active Application Discontinuation
- 2007-06-13 AR ARP070102602A patent/AR061455A1/es not_active Application Discontinuation
-
2008
- 2008-12-07 IL IL195766A patent/IL195766A/en active IP Right Grant
- 2008-12-12 ZA ZA200810576A patent/ZA200810576B/xx unknown
-
2014
- 2014-05-23 US US14/286,254 patent/US9102695B2/en not_active Expired - Fee Related
- 2014-06-19 AU AU2014203337A patent/AU2014203337A1/en not_active Abandoned
-
2016
- 2016-10-19 CY CY20161101051T patent/CY1118170T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CY1118170T1 (el) | 2017-06-28 |
| AP2496A (en) | 2012-10-19 |
| EP2029613A4 (en) | 2011-09-14 |
| AR061455A1 (es) | 2008-08-27 |
| ES2594652T3 (es) | 2016-12-21 |
| ZA200810576B (en) | 2009-10-28 |
| MX343745B (es) | 2016-11-22 |
| WO2007143832A1 (en) | 2007-12-21 |
| CN101472934A (zh) | 2009-07-01 |
| US20090165598A1 (en) | 2009-07-02 |
| AP2008004681A0 (en) | 2008-12-31 |
| IL195766A0 (en) | 2009-09-01 |
| US9102695B2 (en) | 2015-08-11 |
| EP2029613B1 (en) | 2016-07-20 |
| RU2009100922A (ru) | 2010-07-20 |
| CA2550557A1 (en) | 2007-12-14 |
| US20140275615A1 (en) | 2014-09-18 |
| AU2007260536B2 (en) | 2014-04-03 |
| US8764880B2 (en) | 2014-07-01 |
| RU2451021C2 (ru) | 2012-05-20 |
| MX2008015381A (es) | 2009-05-05 |
| AU2014203337A1 (en) | 2014-07-10 |
| BRPI0713640B1 (pt) | 2016-10-25 |
| CN101472934B (zh) | 2015-05-20 |
| BRPI0713640A2 (pt) | 2012-10-23 |
| IL195766A (en) | 2013-09-30 |
| CA2550557C (en) | 2011-03-29 |
| EP2029613A1 (en) | 2009-03-04 |
| AU2007260536A1 (en) | 2007-12-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration | ||
| FD | Application declared void or lapsed |