AR060804A1 - Sintesis del alcohol mixto con uso mejorado del valor del carbono - Google Patents
Sintesis del alcohol mixto con uso mejorado del valor del carbonoInfo
- Publication number
- AR060804A1 AR060804A1 ARP070101555A ARP070101555A AR060804A1 AR 060804 A1 AR060804 A1 AR 060804A1 AR P070101555 A ARP070101555 A AR P070101555A AR P070101555 A ARP070101555 A AR P070101555A AR 060804 A1 AR060804 A1 AR 060804A1
- Authority
- AR
- Argentina
- Prior art keywords
- mixed
- alcohol
- synthesis
- product
- ethanol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/08—Ethanol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente proporciona un método para simplificar la fabricacion de un producto de alcohol mixto u oxigenado mixto desde el gas de síntesis. El producto de alcohol mixto u oxigenado mixto contiene etanol y otros oxigenados con dos o más átomos de carbono por molécula. El método incluye depurar una porcion de dioxido de carbono y los gases inertes contenidos en un producto de reaccion de síntesis de alcohol mixto utilizando una corriente que contiene metanol, tal como una producida como parte del método, como un medio para absorber dicho dioxido de carbono y los gases inertes y de los productos de reciclaje livianos y de los productos pesados para una o más generaciones de gas de síntesis, síntesis del alcohol mixto y separacion del alcohol mixto deseado o los productos oxigenados mixtos de otros componentes de una corriente de síntesis del alcohol. La presente también proporciona un procesamiento corriente abajo del producto de alcohol mixto o del producto oxigenado mixto sometiendo el producto a un paso de deshidratacion para convertir a menos el etanol preferiblemente al menos etanol y propanol, a sus correspondientes olefinas (por ejemplo etileno y propileno)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79176306P | 2006-04-13 | 2006-04-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR060804A1 true AR060804A1 (es) | 2008-07-16 |
Family
ID=39186749
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP070101555A AR060804A1 (es) | 2006-04-13 | 2007-04-12 | Sintesis del alcohol mixto con uso mejorado del valor del carbono |
Country Status (11)
Country | Link |
---|---|
US (1) | US8129436B2 (es) |
EP (1) | EP2024304B1 (es) |
JP (1) | JP2009533431A (es) |
KR (1) | KR20080109924A (es) |
CN (1) | CN101535217B (es) |
AR (1) | AR060804A1 (es) |
AU (1) | AU2007313481A1 (es) |
BR (1) | BRPI0709499B1 (es) |
CA (1) | CA2648630A1 (es) |
MX (1) | MX2008013571A (es) |
WO (1) | WO2008048364A2 (es) |
Families Citing this family (69)
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EP2024304B1 (en) | 2006-04-13 | 2017-09-27 | Dow Global Technologies LLC | Mixed alcohol synthesis with enhanced carbon value use |
EP1862443A1 (en) * | 2006-06-01 | 2007-12-05 | BP Chemicals Limited | Process for the conversion of synthesis gas to oxygenates |
US7923405B2 (en) | 2007-09-07 | 2011-04-12 | Range Fuels, Inc. | Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas |
US8026290B2 (en) * | 2007-12-11 | 2011-09-27 | Range Fuels, Inc. | Methods and apparatus for continuous removal of carbon dioxide from a mixture of reacting gases |
CA2729477A1 (en) * | 2008-07-03 | 2010-01-07 | Synthenol Energy Corporation | Bimetallic mo/co catalyst for producing of alcohols from hydrogen and carbon monoxide containing gas |
US20100030002A1 (en) * | 2008-07-31 | 2010-02-04 | Johnston Victor J | Ethylene production from acetic acid utilizing dual reaction zone process |
US20100030001A1 (en) * | 2008-07-31 | 2010-02-04 | Laiyuan Chen | Process for catalytically producing ethylene directly from acetic acid in a single reaction zone |
US8354357B2 (en) | 2008-09-04 | 2013-01-15 | Albemarle Corporation | Cobalt-molybdenum sulfide catalyst materials and methods for stable alcohol production from syngas |
US8586801B2 (en) | 2008-09-04 | 2013-11-19 | Albemarle Corporation | Cobalt-molybdenum sulfide catalyst materials and methods for stable alcohol production from syngas |
US7855303B2 (en) * | 2008-11-14 | 2010-12-21 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
US8178715B2 (en) * | 2008-12-31 | 2012-05-15 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde |
JP2013521103A (ja) * | 2009-03-06 | 2013-06-10 | アルベマール・ユーロプ・エスピーアールエル | 塊状硫化混合金属触媒ならびに合成ガスからアルコールへの変換におけるその製造および使用のための方法 |
US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
US8858659B2 (en) * | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
US8859827B2 (en) | 2011-11-18 | 2014-10-14 | Celanese International Corporation | Esterifying acetic acid to produce ester feed for hydrogenolysis |
US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
US9073816B2 (en) | 2011-04-26 | 2015-07-07 | Celanese International Corporation | Reducing ethyl acetate concentration in recycle streams for ethanol production processes |
CN103080053B (zh) | 2011-04-26 | 2015-08-12 | 国际人造丝公司 | 使用叠置床反应器生产乙醇的方法 |
US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
US8748675B2 (en) | 2011-06-16 | 2014-06-10 | Celanese International Corporation | Extractive distillation of crude alcohol product |
US8592635B2 (en) | 2011-04-26 | 2013-11-26 | Celanese International Corporation | Integrated ethanol production by extracting halides from acetic acid |
US8704012B2 (en) | 2011-06-16 | 2014-04-22 | Celanese International Corporation | Distillation of crude alcohol product using entrainer |
US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
DK2748136T3 (en) * | 2011-08-22 | 2018-06-18 | Albemarle Corp | Methods and apparatus for sulfur control in catalytic mixed alcohol synthesis. |
US8721995B2 (en) * | 2011-11-03 | 2014-05-13 | Fluor Technologies Corporation | Conversion of organosulfur compounds to hydrogen sulfide in mixed alcohol synthesis reactor effluent |
CN102503769B (zh) * | 2011-11-10 | 2013-11-20 | 北京化工大学 | 一种合成气合成混合醇的方法 |
US8748673B2 (en) | 2011-11-18 | 2014-06-10 | Celanese International Corporation | Process of recovery of ethanol from hydrogenolysis process |
CA2855563A1 (en) * | 2011-11-18 | 2013-05-23 | Haldor Topsoe A/S | Process for the preparation of higher alcohols |
US8829251B2 (en) | 2011-11-18 | 2014-09-09 | Celanese International Corporation | Liquid esterification method to produce ester feed for hydrogenolysis |
US8853468B2 (en) | 2011-11-18 | 2014-10-07 | Celanese International Corporation | Vapor esterification method to produce ester feed for hydrogenolysis |
US9024089B2 (en) | 2011-11-18 | 2015-05-05 | Celanese International Corporation | Esterification process using extractive separation to produce feed for hydrogenolysis |
US8829249B2 (en) | 2011-11-18 | 2014-09-09 | Celanese International Corporation | Integrated esterification and hydrogenolysis process for producing ethanol |
US8802901B2 (en) | 2011-11-18 | 2014-08-12 | Celanese International Corporation | Continuous ethyl acetate production and hydrogenolysis thereof |
WO2013078207A1 (en) | 2011-11-22 | 2013-05-30 | Celanese International Corporation | Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis |
WO2013089990A1 (en) | 2011-12-14 | 2013-06-20 | Celanese International Corporation | Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol |
US8927790B2 (en) | 2011-12-15 | 2015-01-06 | Celanese International Corporation | Multiple vapor feeds for hydrogenation process to produce alcohol |
US8907139B2 (en) | 2011-12-28 | 2014-12-09 | Celanese International Corporation | Process for acetal removal in the purification of a crude ethanol product |
US9024086B2 (en) | 2012-01-06 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts with acidic sites |
WO2013103395A1 (en) | 2012-01-06 | 2013-07-11 | Celanese International Corporation | Precious metal, active metal and modified support - containing hydrogenation catalysts and acetic acid hydrogenation process using the same |
US8921431B2 (en) | 2012-02-29 | 2014-12-30 | Standard Alcohol Company Of America, Inc. | Methods for improving higher alcohol yields from syngas by altering flow regimes within a reactor |
CN102633597B (zh) * | 2012-03-22 | 2013-11-13 | 河北工业大学 | 一种从多元醇-水混合物中回收乙醇、正丙醇和异丁醇的工艺 |
ES2532888B1 (es) * | 2012-05-31 | 2016-04-21 | Abengoa Bioenergía Nuevas Tecnologías, S.A. | Procedimiento catalítico de obtención de etanol a partir de gas de síntesis |
US8957262B2 (en) | 2012-11-20 | 2015-02-17 | Celanese International Corporation | Olefin hydration for hydrogenation processes |
US9988330B2 (en) | 2012-12-20 | 2018-06-05 | Haldor Topsoe A/S | Process and apparatus for the production of higher alcohols |
US9000237B2 (en) | 2012-12-20 | 2015-04-07 | Celanese International Corporation | Ethanol refining process using intermediate reboiler |
US8975451B2 (en) | 2013-03-15 | 2015-03-10 | Celanese International Corporation | Single phase ester feed for hydrogenolysis |
US8926718B2 (en) | 2013-03-15 | 2015-01-06 | Celanese International Corporation | Thermochemically produced ethanol compositions |
CN107810253A (zh) | 2015-05-08 | 2018-03-16 | 赛贝克环球科技公司 | 与合成气到烯烃生产相关的系统和方法 |
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US10540855B2 (en) | 2016-09-21 | 2020-01-21 | Igt | Gaming system and method for redistributing funds amongst players of skill games |
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CN108380216B (zh) * | 2018-02-10 | 2020-07-17 | 浙江大学 | 用于催化二氧化碳制乙醇的钴基催化剂的制备方法及应用 |
CN110292946B (zh) * | 2018-03-21 | 2021-11-16 | 中国石油化工股份有限公司 | 一种由合成气制低碳烯烃的催化剂及其制备方法和应用 |
CN110292945B (zh) * | 2018-03-21 | 2021-11-16 | 中国石油化工股份有限公司 | 一种含分子筛与金属改性硫化钼的催化剂及其制备方法和应用 |
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EP4112169A1 (en) | 2021-07-03 | 2023-01-04 | Studiengesellschaft Kohle mbH | Process for converting synthesis gas to higher alcohols |
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-
2007
- 2007-03-21 EP EP07861269.4A patent/EP2024304B1/en active Active
- 2007-03-21 JP JP2009505372A patent/JP2009533431A/ja not_active Withdrawn
- 2007-03-21 US US12/296,961 patent/US8129436B2/en active Active
- 2007-03-21 BR BRPI0709499A patent/BRPI0709499B1/pt active IP Right Grant
- 2007-03-21 CA CA002648630A patent/CA2648630A1/en not_active Abandoned
- 2007-03-21 MX MX2008013571A patent/MX2008013571A/es not_active Application Discontinuation
- 2007-03-21 AU AU2007313481A patent/AU2007313481A1/en not_active Abandoned
- 2007-03-21 WO PCT/US2007/006967 patent/WO2008048364A2/en active Application Filing
- 2007-03-21 CN CN200780021786.3A patent/CN101535217B/zh active Active
- 2007-03-21 KR KR1020087027663A patent/KR20080109924A/ko not_active Application Discontinuation
- 2007-04-12 AR ARP070101555A patent/AR060804A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
AU2007313481A1 (en) | 2008-04-24 |
US20100069515A1 (en) | 2010-03-18 |
BRPI0709499B1 (pt) | 2017-04-11 |
EP2024304B1 (en) | 2017-09-27 |
US8129436B2 (en) | 2012-03-06 |
JP2009533431A (ja) | 2009-09-17 |
EP2024304A2 (en) | 2009-02-18 |
CN101535217B (zh) | 2014-08-27 |
CN101535217A (zh) | 2009-09-16 |
BRPI0709499A2 (pt) | 2011-07-19 |
MX2008013571A (es) | 2008-12-12 |
KR20080109924A (ko) | 2008-12-17 |
WO2008048364A3 (en) | 2008-12-24 |
WO2008048364A2 (en) | 2008-04-24 |
CA2648630A1 (en) | 2008-04-24 |
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