AP220A - Novel fungicidal imidazole complexes. - Google Patents
Novel fungicidal imidazole complexes. Download PDFInfo
- Publication number
- AP220A AP220A APAP/P/1991/000263A AP9100263A AP220A AP 220 A AP220 A AP 220A AP 9100263 A AP9100263 A AP 9100263A AP 220 A AP220 A AP 220A
- Authority
- AP
- ARIPO
- Prior art keywords
- prochloraz
- complex
- accordance
- metal complex
- plant
- Prior art date
Links
- 230000000855 fungicidal effect Effects 0.000 title claims description 15
- 150000002460 imidazoles Chemical class 0.000 title 1
- 239000005820 Prochloraz Substances 0.000 claims description 50
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 40
- 241000196324 Embryophyta Species 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 239000011701 zinc Substances 0.000 claims description 15
- 201000010099 disease Diseases 0.000 claims description 14
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 241000233866 Fungi Species 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000004563 wettable powder Substances 0.000 claims description 10
- 241000221785 Erysiphales Species 0.000 claims description 9
- 150000004696 coordination complex Chemical class 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 241001284615 Frangula californica Species 0.000 claims description 6
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 description 24
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 238000009472 formulation Methods 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical class [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 8
- 239000011592 zinc chloride Chemical class 0.000 description 8
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical class [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000417 fungicide Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 235000007319 Avena orientalis Nutrition 0.000 description 3
- 244000075850 Avena orientalis Species 0.000 description 3
- 240000008067 Cucumis sativus Species 0.000 description 3
- 240000005979 Hordeum vulgare Species 0.000 description 3
- 235000007340 Hordeum vulgare Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000004464 cereal grain Substances 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 235000009849 Cucumis sativus Nutrition 0.000 description 2
- 239000005789 Folpet Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 150000004700 cobalt complex Chemical class 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000004487 negative regulation of sporulation resulting in formation of a cellular spore Effects 0.000 description 2
- 231100000208 phytotoxic Toxicity 0.000 description 2
- 230000000885 phytotoxic effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 235000000832 Ayote Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 241000579741 Sphaerotheca <fungi> Species 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000028070 sporulation Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000011135 tin Chemical group 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL9363690A IL93636A (en) | 1990-03-05 | 1990-03-05 | Crystalline zinc or tin complexes of prochloraz and compositions containing them |
| IL97181A IL97181A0 (en) | 1991-02-07 | 1991-02-07 | Novel fungicidal imidazole complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AP9100263A0 AP9100263A0 (en) | 1991-07-31 |
| AP220A true AP220A (en) | 1992-10-21 |
Family
ID=26322061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| APAP/P/1991/000263A AP220A (en) | 1990-03-05 | 1991-02-25 | Novel fungicidal imidazole complexes. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5206232A (da) |
| EP (1) | EP0445656B1 (da) |
| AP (1) | AP220A (da) |
| AR (1) | AR246737A1 (da) |
| AT (1) | ATE115950T1 (da) |
| BR (1) | BR9100916A (da) |
| DE (1) | DE69106015T2 (da) |
| DK (1) | DK0445656T3 (da) |
| ES (1) | ES2066245T3 (da) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022053116A1 (en) * | 2020-09-11 | 2022-03-17 | Alfa Smart Agro | Metal prochloraz complexes and the production of them in water based suspension concentrates |
| CN115684321B (zh) * | 2022-10-13 | 2025-10-03 | 桂林理工大学 | 一种基于苯丙氨酸-咪鲜胺的分子印迹传感器及制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2604847A1 (de) * | 1975-02-21 | 1976-09-02 | Polva Nederland Bv | Verfahren und vorrichtung zum herstellen eines kunststoffteiles mit widerstandselement |
| GB1567521A (en) * | 1977-03-26 | 1980-05-14 | Boots Co Ltd | Funigicidal complexes of metal salts with imidazoles |
| DE3210009A1 (de) * | 1981-03-20 | 1982-10-14 | Hokko Chemical Industry Co. Ltd., Tokyo | Imidazolderivate und diese enthaltende fungizide zusammensetzung |
| EP0290204A1 (en) * | 1987-05-08 | 1988-11-09 | Schering Agrochemicals Limited | Fungicidal mixtures with prochloraz |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3789122A (en) * | 1969-03-05 | 1974-01-29 | Du Pont | Fungicidal compositions of transition metal complexes of substituted 2-benzimidazolecarbamic acid, alkyl esters |
| HU171736B (hu) * | 1974-12-11 | 1978-03-28 | Eszakmagyar Vegyimuevek | Fungicid soderzhahhij 8-oksikhinolin v kachestve aktivnogo vehhestva i sposob poluchenija aktivnogo vehhestva |
-
1991
- 1991-02-25 AP APAP/P/1991/000263A patent/AP220A/en active
- 1991-02-28 EP EP91103024A patent/EP0445656B1/en not_active Expired - Lifetime
- 1991-02-28 DK DK91103024.5T patent/DK0445656T3/da active
- 1991-02-28 ES ES91103024T patent/ES2066245T3/es not_active Expired - Lifetime
- 1991-02-28 DE DE69106015T patent/DE69106015T2/de not_active Expired - Fee Related
- 1991-02-28 AT AT91103024T patent/ATE115950T1/de not_active IP Right Cessation
- 1991-03-01 US US07/662,650 patent/US5206232A/en not_active Expired - Lifetime
- 1991-03-01 AR AR91319143A patent/AR246737A1/es active
- 1991-03-04 BR BR919100916A patent/BR9100916A/pt not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2604847A1 (de) * | 1975-02-21 | 1976-09-02 | Polva Nederland Bv | Verfahren und vorrichtung zum herstellen eines kunststoffteiles mit widerstandselement |
| GB1567521A (en) * | 1977-03-26 | 1980-05-14 | Boots Co Ltd | Funigicidal complexes of metal salts with imidazoles |
| DE3210009A1 (de) * | 1981-03-20 | 1982-10-14 | Hokko Chemical Industry Co. Ltd., Tokyo | Imidazolderivate und diese enthaltende fungizide zusammensetzung |
| EP0290204A1 (en) * | 1987-05-08 | 1988-11-09 | Schering Agrochemicals Limited | Fungicidal mixtures with prochloraz |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE115950T1 (de) | 1995-01-15 |
| BR9100916A (pt) | 1991-11-05 |
| AR246737A1 (es) | 1994-09-30 |
| EP0445656B1 (en) | 1994-12-21 |
| AP9100263A0 (en) | 1991-07-31 |
| DK0445656T3 (da) | 1995-02-20 |
| EP0445656A1 (en) | 1991-09-11 |
| US5206232A (en) | 1993-04-27 |
| ES2066245T3 (es) | 1995-03-01 |
| DE69106015D1 (de) | 1995-02-02 |
| DE69106015T2 (de) | 1995-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2530590B2 (ja) | 殺菌・殺カビ剤 | |
| US4940720A (en) | Microbicidal compositions | |
| US4975429A (en) | Fungicidal compositions | |
| CA1228538A (en) | Fungicidal agents | |
| CS236864B2 (en) | Fungicide agent and processing of active component | |
| DE3238306C2 (da) | ||
| US4250179A (en) | Metal complex imidazole fungicides, and methods of controlling fungi with them | |
| AP220A (en) | Novel fungicidal imidazole complexes. | |
| EP0072156B1 (en) | Fungicidal composition containing prochloraz | |
| EP0106558B1 (en) | Fungicidal mixtures | |
| EP0280431B1 (en) | Fungicidal mixtures with prochloraz | |
| JPH0764688B2 (ja) | 農園芸用殺菌組成物 | |
| HU209690B (en) | Synergic fungicidal composition and process for combating of fungicidal infections of plants and vegetable matters and for protection of plants | |
| IL93636A (en) | Crystalline zinc or tin complexes of prochloraz and compositions containing them | |
| JP3086741B2 (ja) | 農園芸用殺菌剤組成物 | |
| JPS5973504A (ja) | 植物生病原菌撲滅剤 | |
| US4346098A (en) | Fungicidal compositions and methods | |
| AT393589B (de) | Fungizide mittel | |
| US4196284A (en) | 5-Substituted-thio-3-chloro-4H-1,2,6-thiadiazin-4-ones | |
| JPS6081106A (ja) | 殺菌・殺カビ剤 | |
| JP3614903B2 (ja) | 安全な殺菌組成物 | |
| JPS5978108A (ja) | 農園芸用殺菌剤組成物 | |
| EP0572085A1 (en) | Fungicidal compositions | |
| JPH03193763A (ja) | ピリジルメチルアミン誘導体および農園芸用殺菌剤 | |
| EP0290204A1 (en) | Fungicidal mixtures with prochloraz |