CN106221629A - A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application - Google Patents
A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application Download PDFInfo
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- CN106221629A CN106221629A CN201610668724.2A CN201610668724A CN106221629A CN 106221629 A CN106221629 A CN 106221629A CN 201610668724 A CN201610668724 A CN 201610668724A CN 106221629 A CN106221629 A CN 106221629A
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- sensitive adhesive
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- retardant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/046—Presence of homo or copolymers of ethene in the substrate
Abstract
The present invention relates to a kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof, this pressure sensitive adhesive is the product for waterproofing industry exploitation, the flame-retardant hot-melt pressure sensitive adhesive of the present invention, weight percentage, the composition of raw materials of this pressure sensitive adhesive includes: thermoplastic elastomer (TPE) 20～35%, amorphous polyolefin 0～5%, polyisobutylene 5～the 10%, first tackifying resin 25～the 40%, second tackifying resin 5～10%, plasticizer 10～20%, coupling agent 0.1～1%, UV absorbent 0.1～1%, antioxidant 0.1～1%, fire retardant 5～10%.The flame-retardant hot-melt pressure sensitive adhesive that the present invention provides not only has the ultraviolet aging resistance of excellence, heat-resistant aging, low temperature resistant bending is good, has suitable cohesiveness, peeling force, initial bonding strength, and has anti-flammability, perfect can solve the defect that traditional pre-laying water-proof coiled material can only be constructed more than 0 DEG C.
Description
Technical field
The present invention relates to a kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application.
Background technology
Along with the acceleration of urbanization process, limited land resource is difficult to accommodate more population and construction, exploitation are lived
Dynamic.Then, development and utilization Underground Space Resource becomes the inevitable choice of the most numerous urban development.Underground is empty at present
Between utilize and have been directed to: underground commerce facility, underground parking station, groundwater reservoir, subway, pipe gallery etc..But, underground is prevented
Channeling water seepage and settlement influence in Hydraulic Projects remain the waterproof expert of puzzlement and a great problem of user.It how to be structure coagulation
It is extremely challenging that soil offer directly completely glues waterproofing protection.
At present pre-installed and inverted adhered waterproof roll substantially be modified pitch class adhesive, such as CN101694114A,
CN1900207, CN202023264U, CN2892857Y etc..What modified pitch adhesive was made overlays waterproof roll following lacking
Point:
1, it is known that Colophonium itself is a kind of hot-fluid cold-short material, therefore modified pitch class adhesive is high temperature resistant and low temperature
Poor performance, this made troubles for summer and construction in winter；
2, the surface of coiled material is without processing, and viscous foot, workman cannot be in coiled material surface assembling reinforcement；
3, coiled material surface unprotect layer, as because of working-day claims, under the effect of ultraviolet and wind and rain, loses bonding effect
And cause product rejection；
4, the bonding peel strength of modified pitch class adhesive is relatively low；
5, non-antiflaming property.
In recent years, market being proposed a kind of polymer membranes being firmly bonded with structural concrete, it is by preventing
Adhesion coating, melt pressure sensitive glue-line, high-density polyethylene layer form, and when using construction, melt pressure sensitive glue-line can avoid waterproof volume
Bonding gap between material and structural concrete so that it is permanent the fullest viscous, this product technology performance and construction effect are the most very
Good.Minstry of Housing and Urban-Rural Development of People Republic of China (MOHURD) is listed in " first popularization catalogue of building cause Eleventh Five-Year Plan popularization and application use technology ", and quilt
List in up-to-date 2010 year " 10 new techniques of building industry " and widely popularize application.It may be said that waterproof coiled material effect quality and hot melt
Pressure-sensitive adhesive layer has vital relation.
Pressure-sensitive adhesive agent recent two decades is developed rapidly, and it is applied throughout the every field of national economy,
And come into huge numbers of families, but, in terms of the applied basic research and technological development of pressure sensitive adhesive goods, China still with prosperity
There is bigger gap in country.Can apply to pressure sensitive adhesive high/low temperature to be possessed, UV resistant and the resistance to immersion of waterproofing industry, and
Preferable adhesive property is had with sheet material and Cement Concrete.
But existing hot-fusible pressure-sensitive adhesive has the disadvantage that 1, most common be exactly that high-and low-temperature resistance is inadequate, resistance to immersion
Difference, substandard products are many；2, the cohesive force of PUR is unstable, and sooner or later being changed by temperature in working environment and humidity is affected, it is impossible to protect
Card firmness；3, low temperature can make hot-fusible pressure-sensitive adhesive bonding force substantially reduce, and coiled material cannot be constructed；4, weatherability is inadequate, resistance to purple
Outside line is also an important indicator, and coiled material needs the catabiosis produced in view of the sunlight when construction；5 and existing
Technology does not the most have the hot-fusible pressure-sensitive adhesive of fire resistance.
Summary of the invention
The technical problem to be solved is to overcome the deficiencies in the prior art, it is provided that a kind of flame-retardant hot-melt pressure sensitive adhesive and
Its preparation method, it is good that this flame-retardant hot-melt pressure sensitive adhesive has high-and low-temperature resistance performance, and resistance to ag(e)ing is good, and peel strength is high, and has resistance
Combustion property, construction temperature is wide.
For solving above technical problem, the present invention adopts the following technical scheme that
A kind of flame-retardant hot-melt pressure sensitive adhesive, weight percentage, the composition of raw materials of described hot-fusible pressure-sensitive adhesive includes:
Wherein, during described first tackifying resin is C5 Petropols, C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin
Kind or multiple combination；
Described second tackifying resin includes rosin resin, pentalyn, rosin glyceride, terpene resin, phenolic aldehyde
The combination of one or more in resin.
Preferably, described first tackifying resin is C5 hydrogenated petroleum resin.
Preferably, described second tackifying resin is the combination of the one or both in rosin glyceride, phenolic resin.
In the present invention, described thermoplastic elastomer (TPE) be s-B-S (SBS), styrene-isoprene-
In styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene ethylene-propylene-styrene (SEPS) one
Kind or multiple combination.
Preferably, described thermoplastic elastomer (TPE) is styrene-isoprene-phenylethene (SIS).
It is further preferred that the mass content of polystyrene is 13-18% in described SIS elastomer, polystyrene-poly is different
The mass content of pentadiene diblock is 0%～80%.
In the present invention, described amorphous polyolefin is APAO.
In the present invention, described polyisobutene molecular weight is less than 2000, and pour point is 3 DEG C～-30 DEG C.
In the present invention, described plasticizer is the combination of one or more in naphthenic oil, white oil, DOP, chlorinated paraffin.
Preferably, the combination of the one or both during described plasticizer is naphthenic oil, chlorinated paraffin.It is highly preferred that it is described
Plasticizer is chlorinated paraffin.
In the present invention, described coupling agent is silane coupling agent.
In the present invention, described UV absorbent is one or more in triazines, benzotriazole, hindered amines
Combination.Described UV absorbent includes but not limited to one or more in UV-P, UV234, UV328, UV944, UV292
Combination.The combination of the one or both being preferably in UV-P, UV234.
In the present invention, described antioxidant, include but not limited to 1010,168,1076,264 one or more.
In the present invention, described fire retardant is environment friendly halogen-free fireproof agent.Preferably, described fire retardant is phosphorus-nitrogen containing flame retardant.
In the present invention, the most described raw material all can prepare by being purchased and/or take known means, does not has
When being illustrated, it is satisfied by standardization chemical product requirement.
The another technical scheme that the present invention takes is: the preparation method of a kind of above-mentioned flame-retardant hot-melt pressure sensitive adhesive, described preparation
Method is: by formula, by described thermoplastic elastomer (TPE), amorphous polyolefin, polyisobutylene, the first tackifying resin, the second thickening
Resin, plasticizer, coupling agent, UV absorbent, antioxidant, fire retardant at a temperature of 150 DEG C～180 DEG C mix and blend until
Material dissolution, both described flame-retardant hot-melt pressure sensitive adhesive.
What the present invention taked another solution is that a kind of above-mentioned flame-retardant hot-melt pressure sensitive adhesive answering in waterproof roll
With.The particularly application in non-bituminous based high molecular self-adhesion glued membrane waterproof roll.
Due to the enforcement of technique scheme, the present invention compared with prior art has the advantage that
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has the high-and low-temperature resistance performance of excellence, ageing-resistant performance.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention enriches pressure sensitive adhesive construction application temperature range greatly.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has fire resistance, improves the range of pressure sensitive adhesive.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has preferable resistance to water, solves traditional asphalt base and overlays coiled material and market is general
Logical Macromolecular self-adhesive membrane waterproof roll channeling water, leakage problems.
The flame-retardant hot-melt pressure sensitive adhesive of the present invention in the preparation by add in thermoplastic elastomer (TPE) the first tackifying resin, the
The compositions such as two tackifying resins, plasticizer, prepared hot-fusible pressure-sensitive adhesive has certain needle penetration, it is possible to improve its with after water coagulation
The peel strength of soil.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described in detail, but the present invention is not limited to following enforcement
Example.
Embodiment 1
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, and the raw material of employing and consumption see table 1, wherein:
Thermoplastic elastomer (TPE) is SIS, and purchased from Ke Teng Polymer Company of the U.S., the trade mark is D1163.
Amorphous polyolefin is APAO, and purchased from Ying Chuan company, the trade mark is Vestoplast 408.
First tackifying resin is C5 hydrogenated petroleum resin
Second tackifying resin is made up of rosin glyceride, phenolic resin 1:1 in mass ratio, and wherein, rosin glyceride is purchased from
Song Chuan chemical company, the trade mark is RE85, and phenolic resin is purchased from Shanghai three even industrial corporation, and the trade mark is 2402.
Plasticizer is made up of naphthenic oil and chlorinated paraffin 2:1 in mass ratio, and wherein, naphthenic oil is extraordinary purchased from Suzhou Sai Pahan
Oil product company limited, the trade mark is KN4010, and chlorinated paraffin is purchased from Suzhou Sai Pahan specialty oil company limited, and the trade mark is 52#.
Coupling agent joins chemistry of silicones company limited purchased from Nanjing, and the trade mark is KH560.
UV absorbent is UV-P and UV234 1:1 in mass ratio composition.
Antioxidant is antioxidant 1010, purchased from BASF AG.
Fire retardant is phosphorus-nitrogen containing flame retardant, and purchased from Suzhou An Hongtai new material company limited, the trade mark is FR563.
The preparation method of flame-retardant hot-melt pressure sensitive adhesive is as follows: by the formula of embodiment 1, by thermoplastic elastomer (TPE), amorphous poly-
Alkene, polyisobutylene, the first tackifying resin, the second tackifying resin, plasticizer, coupling agent, UV absorbent, antioxidant, resistance
Combustion agent adds in hermetic container, high-speed stirred under the conditions of 170 DEG C, and discharging after material dissolution obtains described flame-retardant hot-melt pressure
Quick glue.
Embodiment 2
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, and the raw material of employing and consumption see table 1, heat extraction Plastic resilient
Raw material outside body, the first tackifying resin, the second tackifying resin, plasticizer is the most same as in Example 1, wherein:
Thermoplastic elastomer (TPE) is SBS and SIS 1:2 in mass ratio composition, and SBS is purchased from Yueyang petro-chemical corporation, and the trade mark is 792.
First tackifying resin is that C5 Petropols and C9 hydrogenated petroleum resin form for 2:1 in mass ratio, C5 Petropols
Purchased from Lanzhou Petrochemical Company, the trade mark is that LH-100, C9 hydrotreated petroleum tree is purchased from Exxon Mobil Corporation, and the trade mark is 5400.
Second tackifying resin is terpene resin, and purchased from Shanghai three even industrial corporation, the trade mark is T80.
Plasticizer is DOP, and purchased from Shanghai Sen Di chemical company, the trade mark is JSSD-DOP.
Preparation method is with embodiment 1.
Embodiment 3
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, and the raw material of employing and consumption see table 1, except antioxidant, plasticising
Raw material outside agent is the most same as in Example 1, wherein:
Antioxidant is irgasfos 168 and antioxidant 1076 1:1 in mass ratio composition.
Plasticizer is chlorinated paraffin.
Preparation method is with embodiment 1.
Embodiment 4
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, and the raw material of employing and consumption see table 1, except the second thickening tree
Raw material outside fat, UV absorbent is the most same as in Example 1.
Second tackifying resin is rosin glyceride.
UV absorbent is UV328.
Preparation method is with embodiment 1.
Comparative example 1
This comparative example provides a kind of hot-fusible pressure-sensitive adhesive, and the raw material of employing and consumption see table 1, in the formula of this comparative example not
Add fire retardant.
Table 1 is embodiment 1～4 and the raw material composition of comparative example 1
By embodiment 1～4 and the flame-retardant hot-melt pressure sensitive adhesive of comparative example 1 carry out performance test, method is as follows: by this hot melt pressure
Quick glue coats to macromolecule HDPE sheet material, cools down stand-by, is then torn by isolating membrane, uniformly sprinkles antiseized on glue-line
Grain, makes Macromolecular self-adhesive membrane waterproof roll, overlays Y in wet-laying waterproof roll standard according to GB GB/T 23457-2009
P class carries out performance Indexs measure, and fire resistance is carried out according to GB GB8624-2012 construction material and product burns grading performance
Detection, test result sees table 2.
Table 2 is embodiment 1～4 and the performance of hot-fusible pressure-sensitive adhesive of comparative example 1
Above the present invention is described in detail, its object is to allow the personage being familiar with this art will appreciate that this
Invention content and be carried out, can not limit the scope of the invention with this, and the invention is not restricted to above-mentioned enforcement
Example, all equivalence changes made according to the spirit of the present invention or modification, all should contain within protection scope of the present invention.
Claims (10)
1. a flame-retardant hot-melt pressure sensitive adhesive, it is characterised in that: weight percentage, the composition of raw materials of described hot-fusible pressure-sensitive adhesive
Including:
Thermoplastic elastomer (TPE) 20～35%
Amorphous polyolefin 0～5%
Polyisobutylene 5～10%
First tackifying resin 25～40%
Second tackifying resin 5～10%
Plasticizer 10～20%
Coupling agent 0.1～1%
UV absorbent 0.1～1%
Antioxidant 0.1～1%
Fire retardant 5～10%；
Wherein, one during described first tackifying resin is C5 Petropols, C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin or
Multiple combination；
Described second tackifying resin includes rosin resin, pentalyn, rosin glyceride, terpene resin, phenolic resin
In the combination of one or more.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described thermoplastic elastomer (TPE) is SBS, SIS,
The combination of one or more of SEBS, SEPS.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described amorphous polyolefin is APAO.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described polyisobutene molecular weight is less than
2000, pour point is 3 DEG C～-30 DEG C.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described plasticizer be naphthenic oil, white oil,
The combination of one or more in DOP, chlorinated paraffin.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described coupling agent is silane coupling agent.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described UV absorbent be triazines,
The combination of one or more in benzotriazole, hindered amines.
Flame-retardant hot-melt pressure sensitive adhesive the most according to claim 1, it is characterised in that: described fire retardant is environment friendly halogen-free fireproof
Agent.
9. a preparation method for the flame-retardant hot-melt pressure sensitive adhesive as described in claim any one of claim 1 ~ 8, its feature
It is: described preparation method is: by formula, by described thermoplastic elastomer (TPE), amorphous polyolefin, polyisobutylene, the first thickening
Resin, the second tackifying resin, plasticizer, coupling agent, UV absorbent, antioxidant, fire retardant are at a temperature of 150 DEG C ~ 180 DEG C
Mix and blend until material dissolution, both described flame-retardant hot-melt pressure sensitive adhesive.
10. the answering in waterproof roll of the flame-retardant hot-melt pressure sensitive adhesive as described in a claim any one of claim 1 ~ 8
With.
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| CN201610668724.2A CN106221629B (en) | 2016-08-15 | 2016-08-15 | A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application |
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| CN201610668724.2A CN106221629B (en) | 2016-08-15 | 2016-08-15 | A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application |
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| CN106753235A (en) * | 2016-12-19 | 2017-05-31 | 钦州市钦南区科学技术情报研究所 | A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof |
| CN108178998A (en) * | 2018-02-01 | 2018-06-19 | 四川鑫桂湖防水保温节能科技有限公司 | A kind of resistant to heat aging hot-fusible pressure-sensitive adhesive and preparation process |
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| CN111662664A (en) * | 2020-05-29 | 2020-09-15 | 四川省宏源防水工程有限公司 | Flame-retardant self-adhesive for composite gas isolation plate and preparation method thereof |
| CN112048266A (en) * | 2019-06-06 | 2020-12-08 | 沈阳万合胶业股份有限公司 | Pressure-sensitive adhesive for liquid crystal display and preparation method thereof |
| CN112457806A (en) * | 2020-11-26 | 2021-03-09 | 苏州凯伦高分子新材料科技有限公司 | High-temperature-resistant hot-melt pressure-sensitive adhesive and preparation method and application thereof |
| CN113382864A (en) * | 2019-01-31 | 2021-09-10 | 伊士曼化工公司 | Process for preparing low volatility tackifier compositions |
| CN113429921A (en) * | 2021-07-21 | 2021-09-24 | 渭南科顺新型材料有限公司 | Hot-melt pressure-sensitive adhesive and pre-paved waterproof coiled material applying same |
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| US11661531B2 (en) | 2019-01-31 | 2023-05-30 | Synthomer Adhesives Technology LLC | Hygiene adhesives comprising low volatile tackifier compositions |
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| WO2023062534A1 (en) | 2021-10-15 | 2023-04-20 | Colquímica-Indústria Nacional De Colas, S.A | Flame retardant hot melt adhesive |
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